Journal
DALTON TRANSACTIONS
Volume -, Issue 37, Pages 4965-4974Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b803510p
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [18550146, 16350090, 2006-2011, 20550145]
- The Mitsubishi Foundation
- Human Frontier Science Project (HFSP) Young Investigator's Grant
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It was recently demonstrated spectroscopically that RNA/DNA nucleobases can bind to metal cations in aqueous solution through coordination bonds and covalent bonds. Nitrogen-15 (N-15) NMR spectroscopy was employed and shown to be a powerful tool for determining the mode of metal ion binding to nitrogen atoms in RNA/DNA molecules. This review describes N-15 NMR spectroscopic characteristics in accordance with the mode of metal ion binding to nitrogen atoms. The general rules for N-15 chemical shift changes, which are applicable to the determination of the metal ion binding mode of N-metallated compounds, are also described.
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