Journal
CURRENT ORGANIC SYNTHESIS
Volume 9, Issue 6, Pages 764-778Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157017912803901655
Keywords
Aryleneethynylenes; conjugated oligomers; conjugated polymers; cross-coupling; Sonogashira reaction; triple C-C bonds; chiral polymers; biopolymers; organic electronics; thiol; molecular wires; self-assembly; molecular electronics; anthraquinone; norbornadiene; photoisomerization
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Funding
- Ministero dell'Istruzione, dell'Universita e della Ricerca (MIUR), Progetto PRIN [prot. 2009PRAM8L]
- Universita degli Studi di Bari
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In this article we discuss synthetic routes to organic conjugated oligomers and polymers bearing triple C-C bonds that have been recently developed in our laboratories, based on Pd-catalyzed Csp-Csp(2) coupling reactions. Experimental protocols have been tuned to face synthetic challenges such as the presence in the main conjugated backbone of multifunctional substituents or uncommon conjugated units. The relevance of the obtained products in terms of properties and applications is also shortly mentioned.
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