Journal
CURRENT ORGANIC CHEMISTRY
Volume 16, Issue 20, Pages 2462-2481Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/138527212803520083
Keywords
Organoantimony; Hypervalent compounds; Intramolecular coordination; Organic synthesis; Structure; Reagent; Catalyst
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Funding
- Natural Science Foundation of Hunan Province [10JJ1003]
- Science Research Foundation of Higher Universities of Hunan Province [10A092]
- National Natural Science Foundation of China [20973056, 21003040]
- program for New Century Excellent Talents in Universities [NCET-10-0371]
- Fundamental Research Funds for the Central Universities
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The review article covers the hypervalent organoantimony compounds that are with intramolecular N, O, S -> Sb coordinations synthesized in the past 20 years. We describe their structures and the related coordination chemistry, highlighting a number of hypervalent stibines. These compounds have shown many applications in organic synthesis. They are useful reagents for reactions such as cross-coupling and arylation with organic halides, and addition with carbonyl compounds. They can be used as Lewis acid catalysts in organic synthesis. Furthermore, they can be utilized as catalysts or reagents for CO 2 chemical fixation. It is envisaged that more hypervalent organoantimony compounds of novel structure will be synthesized and find new applications in the near future.
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