Journal
CURRENT ORGANIC CHEMISTRY
Volume 15, Issue 16, Pages 2816-2829Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/138527211796378514
Keywords
Organosilicon; transmetallation reagent; organic synthesis
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Funding
- National Natural Science Foundation of China [20972115]
- Chinese Ministry of Education [209054]
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Organosilicon compounds are important transmetallation reagents in organic synthesis. Aryltrialkoxysilane have recently emerged as an attractive alternative to traditional organometallic donors, due to their ease of handling, stability toward air/moisture, and/or low toxicity compared to some of the other organometallic reagents (Zn, Mg, Sn, etc.). In this review, the application of aryl trialkoxysilane and alkenyltrialkoxysilane as transmetallation reagent for C-C, C-N, C-S and C-O bonds formation will be disclosed.
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