Journal
CURRENT ORGANIC CHEMISTRY
Volume 13, Issue 9, Pages 896-913Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/138527209788452117
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Funding
- Ministry of Science and Higher Education [3 T09A 147 29]
- European Social Fund
- Foundation for Polish Science
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A comprehensive review of the reports in the literature concerning conjugation of polyunsaturated acid and their esters (vegetable oils such as: linseed oil, sunflower oils, rape oil, soybean oil; linoleic acid, methyl linoleate etc.) catalyzed by supported transition metals and their complexes is presented. The following issues are analyzed: chemo-, regio, and stereoselectivity of the double bond migration in polyenes, mechanism of conjugation and accompanying isomerization process, hydrogenation and E-Z isomerization, stability of homo- and heterogenous catalysts, removal of catalysts from the post-reaction mixture, and possibility of catalysts' recycling.
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