Journal
CRYSTENGCOMM
Volume 15, Issue 44, Pages 8998-9002Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce41221k
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Funding
- National Basic Research Program of China [2010CB635108, 2011CBA00700]
- International S&T Cooperation Program, China [2012DFA-51210]
- scientific research project of Huzhou teachers college
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A cyanostilbene-based derivative with aggregation induced-emission was obtained, which exhibited multi-luminescent intensity under external stimuli. The as-prepared crystals of the desired dye showed a rather faint luminescence. Upon heating, its fluorescence could be turned on with the quantum yields of 13.3%. The quantum yields of the melted and solidified powders were further increased to 28.6%. Powder X-ray diffractometry, fluorescence spectroscopy, fluorescence lifetime experiments and single crystal XRD analyses were applied to investigate the changes of molecular packing modes. Such a transformation of fluorescence dark-bright, easily distinguished by naked eye, was related to the phase transition. The planar cyanostilbene with H-type packing and multiple mutable interactions may be the essential factor for the multi-luminescent intensity properties.
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