4.7 Article

In-situ observations of flux growth of NaTaO3 crystals on tantalum substrate

Journal

CRYSTENGCOMM
Volume 15, Issue 20, Pages 4058-4061

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce40330k

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Funding

  1. Japan Science and Technology Agency
  2. Ministry of Education, Culture, Sports, Science and Technology, Japan [23.5691]
  3. Grants-in-Aid for Scientific Research [11J05691] Funding Source: KAKEN

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The growth of NaTaO3 crystals through the reaction between NaNO3 and a Ta substrate was directly observed using in-situ laser microscopy and in-situ X-ray diffraction. Voids and creases were first produced at similar to 430 degrees C and then NaTaO3 crystals grew at similar to 440 degrees C in a moment. Because the NaTaO3 crystals had formed during heating, the driving force for crystal growth was concluded to be the evaporation of NaNO3.

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