Journal
CRYSTENGCOMM
Volume 15, Issue 15, Pages 3031-3039Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce00058c
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Funding
- UGC
- Institucio Catalana de Recerca I Estudis Avancats (ICREA)
- Spanish Ministerio de Economia y Competitividad (MINECO) [CTQ2011-27929-C02-01, CTQ2011-27512/BQU, CSD2010-00065]
- FEDER funds
- Direccio General de Recerca i Innovacio del Govern Balear
- ICREA Funding Source: Custom
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Reaction of manganese(II) with the electron-deficient ligand 3,6-bis(4-pyridyl)-1,2,4,5-tetrazine (pbptz) leads to distinct coordination networks whose topologies are influenced by the nature of the anions used. As anticipated, the linear ditopic ligand pbptz is involved in various types of supramolecular pi interactions, i.e. pi center dot center dot center dot pi, lone pair center dot center dot center dot pi and C-H center dot center dot center dot pi interactions, which clearly play a role in the formation of the different solid-state architectures obtained, as shown by DFT calculations.
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