Article
Chemistry, Multidisciplinary
Yi-Ming Di, Meng-Hua Li, Shu-Quan Zhang, Ming-Hua You, Mei-Jin Lin
Summary: Donor-acceptor hybrid crystals are a novel class of crystalline hybrid complexes that exhibit electron-transfer photochromic properties and possible room-temperature phosphorescence. These crystals are composed of POMs and NDIs, which are interconnected through anion-pi interactions. The light-induced color changes and RTP properties of these crystals depend on the matching electron energy levels of POMs and NDIs, as well as the presence of heavy atoms in POMs and coordination metal cations.
CRYSTAL GROWTH & DESIGN
(2021)
Article
Chemistry, Multidisciplinary
Na Luo, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang
Summary: The article briefly reviews the emergence and development of anion-pi interactions, emphasizing the concept of anion-pi catalysis and key progress in this area. The content is organized based on the role of anion-pi interactions in catalysis, from ground-state and transition-state stabilization to cooperative pi-face activation. A concluding remark and outlook on future development are also provided.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Na Luo, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang
Summary: Exploring the use of anion-pi interactions in catalyst design is an exciting direction for developing new and fundamental catalysis. By establishing cooperative pi-face activation, efficient transformation and excellent selectivity control can be achieved. The supramolecular pi-catalysis strategy demonstrated in this study showcases the successful harnessing of cooperative anion-pi interactions for efficient activation and outstanding selectivity control.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Sonam Chorol, Poonam Saini, Pritam Mukhopadhyay
Summary: There is a growing interest in the design and synthesis of organic redox-active systems that exist in ionic form. Material scientists face the challenge of designing complex molecular materials that can store and transfer multiple electrons at low operational potentials while remaining stable under ambient conditions. The design of efficient ionic pi-systems that can transport both electrons and ions is also crucial.
Article
Chemistry, Organic
Minghan Tan, Robert Chrostowski, Haruki Sanematsu, Masayuki Takeuchi, Atsuro Takai
Summary: The study presents a catalyst-free method for functionalizing pi-conjugated molecules with amines, which follows typical second-order kinetics. The hydroamination rates show a good linear correlation with chemical shifts, and resulting amino-functionalized pi-systems exhibit near-IR emission with reversible emission wavelength switching in response to Bronsted acid and base.
ASIAN JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Yoshifumi Sasano, Hiroki Tanaka, Yohei Haketa, Yoichi Kobayashi, Yukihide Ishibashi, Tatsuki Morimoto, Ryuma Sato, Yasuteru Shigeta, Nobuhiro Yasuda, Tsuyoshi Asahi, Hiromitsu Maeda
Summary: Charged pi-electronic species were observed to develop stacking structures based on electrostatic and dispersion forces, with the concept of (i)pi-(i)pi Interaction introduced to describe the interactions in these structures. The energy decomposition analysis revealed the importance of electrostatic and dispersion forces in stabilizing the stacking of pi-electronic ions, as observed through crystal-state absorption spectra and transient absorption spectroscopy.
Article
Chemistry, Inorganic & Nuclear
Javier Pitarch-Jarque, Ramon J. Zaragoza, Rafael Ballesteros, Belen Abarca, Enrique Garcia-Espana, Begona Verdejo, Rafael Ballesteros-Garrido
Summary: By transforming neutral heterocycles into their corresponding salts, new water-soluble fluorescent dyes have been successfully prepared, overcoming the issue of low solubility and helping to reveal the nature of anion-pi interactions in water.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Multidisciplinary
Masaaki Akamatsu, Ayumi Kimura, Koji Yamanaga, Kenichi Sakai, Hideki Sakai
Summary: The study evaluated anion-pi interactions at the solid/water interface and found that anion adsorption followed the hydration energy and the presence of conjugated systems of the anions by QCM measurements. Force curve measurements revealed that the single-molecule force of anion-pi interaction was approximately 40 pN between an NDI unit and the negatively charged surface of the cantilever. This study presented the first example of obtaining a single-molecule force for anion-pi interactions.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Aiswarya M. Parameswaran, Anto James, Adil Aboobacker, Rotti Srinivasamurthy Swathi
Summary: This study addresses the challenges of extended conjugation and design of all-carbon neutral anion receptors. Using computations on anion-pi complexes of halide ions with graphynes, the researchers reveal the functional relevance of graphynes as anion receptors and assert that anion-pi interactions are not solely dominated by electrostatic interactions. Polarization components play a crucial role in governing the binding of anions to graphynes.
Article
Chemistry, Multidisciplinary
Shinya Sugiura, Hiromitsu Maeda
Summary: A new series of pi-extended quinone derivatives with a pyrrole bridge exhibited NH/OH-type tautomerization and anion binding, along with deprotonation that induced near-infrared absorption and ion-pairing assemblies.
CHEMICAL COMMUNICATIONS
(2021)
Review
Chemistry, Multidisciplinary
Yohei Haketa, Kazuhisa Yamasumi, Hiromitsu Maeda
Summary: The pairing and ordered arrangement of charged pi-electronic systems are achieved through the synergistic effects of electrostatic and dispersion forces. Various methods, including covalent bonding and noncovalent ion complexation, are used to prepare charged pi-electronic systems. These systems exhibit diverse ion pairs and intriguing characteristics.
CHEMICAL SOCIETY REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Hao Gong, Cheng Zhang, Takuya Ogaki, Hiroyuki Inuzuka, Daisuke Hashizume, Daigo Miyajima
Summary: AC3Ts, a substructure of Tz-GCN, can capture protons as organic superbases and exhibit unique anion-pi interactions that alter their ionization potentials. These features are expected to expand the usage scope and possibilities for GCNs.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Jie Pan, Wei Lin, Fang Bao, Qinglong Qiao, Guixin Zhang, Yao Lu, Zhaochao Xu
Summary: This paper reports a cage-like molecule composed of two benzene rings and three imidazolium salts, which exhibits continuous fluorescence wavelength changes when interacting with fluoride ions. The fluorescence blue-shift is induced by the anion-pi interaction and (C-H) +middotmiddotmittotF- ionic hydrogen bonds. The subsequent formation of C-F covalent bonds leads to further blue-shift of the fluorescence wavelength, resulting in continuous multiple fluorescence changes caused by a single external stimulus. Six different fluorescence signal channels can be obtained based on the wavelength and intensity of the fluorescence, which can be encoded as six numbers from 0 to 5. This reaction process holds potential applications in quantitative anion recognition and molecular counting.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Ravindra D. Mule, Rupam Roy, Koushik Mandal, Deepak Chopra, Tanoy Dutta, Shashank P. Sancheti, Popat S. Shinde, Somsuvra Banerjee, Apurba Lal Koner, Rohit Bhowal, Beeran Senthilkumar, Nitin T. Patil
Summary: This study explores the use of anion-pi(+) interactions in the development of AIEgens and investigates their fluorescence properties and applications. Photophysical, computational, and crystallographic studies were conducted to understand the properties of these luminogens and elucidate the role of non-covalent interactions in inhibiting undesired effects.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Na Luo, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang
Summary: Researchers designed a class of water-soluble electron-deficient molecular cages and relevant aromatic slide compounds to achieve efficient catalysis through anion-pi interactions. Experimental results showed that these molecules could effectively catalyze reactions in water, demonstrating a pronounced hydrophobic amplification effect.
CHEMISTRY-AN ASIAN JOURNAL
(2021)
Article
Chemistry, Applied
Li Xing, Zhoulong Fan, Chengyu Hou, Guoping Yong, Ao Zhang
ADVANCED SYNTHESIS & CATALYSIS
(2014)
Article
Chemistry, Applied
Yumei Zhao, Guoping Yong, Xuerui Zhang, Bei Zhang
Article
Materials Science, Multidisciplinary
Bei Zhang, Yu-Mei Zhao, Guo-Ping Yong
FUNCTIONAL MATERIALS LETTERS
(2014)
Article
Materials Science, Multidisciplinary
Guoping Yong, Yiman Zhang, Wenlong She
Article
Materials Science, Multidisciplinary
Ya Feng, Guoping Yong, Yumei Zhao, Chen Shen
Article
Nanoscience & Nanotechnology
Ya Feng, Guoping Yong, Yumei Zhao
MICRO & NANO LETTERS
(2014)
Article
Materials Science, Multidisciplinary
Bei Zhang, Guoping Yong, Yumei Zhao, Xuerui Zhang
Article
Materials Science, Multidisciplinary
Yumei Zhao, Guoping Yong, Ya Feng, Chen Shen
Article
Chemistry, Physical
Wen-jing Liu, Yu-xin Liu, Xiang-yang Yan, Guo-ping Yong, Ye-ping Xu, Shao-min Liu
JOURNAL OF MATERIALS CHEMISTRY A
(2014)
Article
Materials Science, Multidisciplinary
Guo-Ping Yong, Yu-Mei Zhao, Ya Feng
JOURNAL OF MATERIALS CHEMISTRY C
(2014)
Article
Chemistry, Multidisciplinary
Jia-Ling Yin, Meng-Ru Yin, Guo-Ping Yong
Summary: Two new coordination polymers and two novel isostructural metal-organic frameworks were synthesized using a new ligand. The dimensional and structural diversities were controlled by adjusting the solvent ratio, and enhanced luminescence emission was observed in certain frameworks.
Article
Chemistry, Multidisciplinary
Li-Juan Zhao, Bin Li, Guo-Ping Yong
Summary: Four novel isostructural lanthanide metal-organic frameworks were synthesized and characterized. One of them showed better sensitivity and selectivity towards Fe3+ ions and Cr2O72- anions. All four frameworks remained stable during the tests.
Article
Chemistry, Multidisciplinary
Meng-Ru Yin, Qing-Qing Yan, Bin Li, Guo-Ping Yong
Summary: A new three-connecting T-shaped ligand was used to construct four coordination polymers, showcasing different structures and CO2 adsorption properties, providing a promising approach for designing new ligands and tuning CO2 adsorption properties.
Article
Materials Science, Multidisciplinary
Bin Li, Qing-Qing Yan, Guo-Ping Yong
JOURNAL OF MATERIALS CHEMISTRY C
(2020)
Article
Chemistry, Multidisciplinary
Bin Li, Qing-Qing Yan, Zhi-Qiang Xu, Ying-Bo Xu, Guo-Ping Yong
Article
Chemistry, Multidisciplinary
Abu Talha Aqueel Ahmed, Sankar Sekar, Shubhangi S. Khadtare, Nurul Taufiqu Rochman, Bathula Chinna, Abu Saad Ansari
Summary: In this study, MnCo2S4 nanosheet catalyst was successfully synthesized and found to exhibit superior performance in hydrogen evolution. Compared to MnCo2S4, MnCo2S4 showed low overpotentials, moderate Tafel slope, and excellent sustainability. The outstanding performance can be attributed to the increased number of electrochemically active sites and enhanced electronic conductivity on the catalyst surface.
Article
Chemistry, Multidisciplinary
Victor V. Maltsev, Elena A. Volkova, Elizaveta V. Koporulina, Diana D. Mitina, Vladimir L. Kosorukov, Anna I. Jiliaeva, Daniil A. Naprasnikov, Konstantin N. Gorbachenya, Viktor E. Kisel
Summary: The phase relationships, crystal properties and luminescence kinetics of two complex systems were studied, including unit cell parameters, segregation coefficients of impurities, and lifetimes of energy levels.
Article
Chemistry, Multidisciplinary
Xiaoman Zhang, Wangwang Xu, W. J. Meng, Andrew C. Meng
Summary: This study successfully grew high-quality single crystal AlScN nanowires through ultra-high vacuum reactive sputtering technique and characterized their structure and properties. The nanowires exhibit significantly reduced mosaic spread and predominantly single ferroelectric domains, as well as a high piezoelectric constant.
Article
Chemistry, Multidisciplinary
Tom E. de Vries, Elias Vlieg, Rene de Gelder
Summary: Networks are important for describing relationships between people, roads between cities, reactions between chemicals, and other interactions. Bipartiteness, dividing the network into two groups, can facilitate the study of the network's structure. We have developed an algorithm that can find a near-optimal bipartisation within a reasonable time frame and used it to uncover the hidden structure of the CSD cocrystal network.
Article
Chemistry, Multidisciplinary
Chuchu Han, Jing Yang, Xin Zhang, Aisen Li, Jiang Peng
Summary: An elastic crystal based on a photo-reactive acylhydrazone derivative is reported, which exhibits reversible bending behavior under UV irradiation and heating. The crystal undergoes reversible E<->Z isomerization under light and heating conditions. The crystal demonstrates excellent elastic properties and the bending can be controlled to control the output direction of red light.
Article
Chemistry, Multidisciplinary
Lingfeng Zhang, Yu Wang, Yefeng Wang, Shuai Liu, Na Zhang, Mingmin Yang, Haixia Ma, Zhaoqi Guo
Summary: This study designs and synthesizes a series of high-energy salts compounds without heavy metal ions and azide groups. The molecular structures and stability of the compounds are confirmed through single-crystal X-ray diffraction and intermolecular interaction analysis. Furthermore, the thermal stability, energetic properties, and electrical initiation properties of the compounds are investigated, suggesting their potential as primary explosives.