Journal
CRYSTENGCOMM
Volume 14, Issue 3, Pages 875-879Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce05686g
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Funding
- National Natural Science Foundation of China [51171139]
- Xi'an Jiaotong University
- New Century Excellent Talents in University (NCET)
- Fundamental Research Funds for the Central Universities [08142008]
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Non-branching twinned Ag nanowires have been synthesized within a three-dimensional electrochemical deposition system by using a non-supporting electrolyte and an unusually high over-potential. The branching rate of the Ag nanowires is significantly decreased under the interactions of a strong applied potential and the low concentration electrolyte, in which an ion migrational-transport controlled 3D electrochemical growth is created. Additionally, according to finite-element simulations, a high density growth of Ag nanowires originating from the high over-potential creates a planar growth front, resulting in a small probability of the branching growth.
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