4.7 Article

An unprecedented 3D/3D hetero-interpenetrated MOF built from two different nodes, chemical composition, and topology of networks

Journal

CRYSTENGCOMM
Volume 14, Issue 18, Pages 5720-5722

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce25739d

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Funding

  1. NSFC [21171093, 20971068]
  2. State Key Laboratory of Materials-oriented Chemical Engineering [KL11-03]

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An exceptional acentric MOF material with two-fold hetero-interpenetrated nets consisting of a 3D diamond network (mononuclear Cd(CO2)(4) node) and a 3D CsCl framework (trinuclear Cd-3(CO2)(8) node) has been constructed, which contains 6-, 7-, 8-coordinated Cd2+ ions and shows a high thermal stability (>420 degrees C) and SHG activity.

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