4.7 Article

An Fe-based MOF constructed from paddle-wheel and rod-shaped SBUs involved in situ generated acetate

Journal

CRYSTENGCOMM
Volume 13, Issue 20, Pages 6002-6006

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce05470h

Keywords

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Funding

  1. 973 Program of China [2007CB815305]
  2. NNSF of China [21031002, 20801029]
  3. Natural Science Fund of Tianjin, China [10JCZDJC22100]

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An Fe-based MOF has been constructed from a paddle-wheel-like dimeric Fe-cluster and a rod-shaped sinusoidal-like Fe-chain as two distinct secondary building units. Topological analyses indicate that this compound is a tetranodal (3,3,4,8)-connected net, which represents a new structural topology in MOFs. Moreover, the magnetic properties of 1 have been thoroughly investigated.

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