Article
Crystallography
Zhiqiang Lu, Yanzhi Li, Yi Ru, Shujian Yang, Chu Hao, Mengke Zuo, Rongkai Jiao, Hui Yao
Summary: Two different metal-organic frameworks (MOFs) were synthesized by reacting different metal salts with mixed ligands, resulting in a 1D chain structure for one and a 3D framework with a three-fold interpenetration topology for the other. Luminescent properties of the MOFs were also studied.
Article
Chemistry, Physical
Wen-Jing Xu, Kun-Peng Chen, Yue Zhang, Yue Ma, Quan-Wen Li, Qing-Lun Wang
Summary: Two new Co(II) complexes with different structures and properties have been synthesized in this study. One of the complexes is photochromic, while the other complex exhibits both photochromic and thermochromic properties. Moreover, these complexes also possess unique magnetic properties.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Physical
Xia Wang, Xiang Fang, Xianxian Yuan, Fei Zhang, Jing Yang, Ning Ling, Huaixia Yang
Summary: In this study, two new coordination polymers were synthesized and characterized by X-ray single crystal diffraction analysis, elemental analysis, 1H-NMR spectra, and IR spectra. The results showed that both polymers exhibited outstanding photocatalytic activities in the degradation of MB and RhB, with remarkable efficiencies.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Inorganic & Nuclear
Wenjun Du, Lirong Jiang, Shan Jin, Shuang Chen, Manzhou Zhu
Summary: In this study, a chiral superatom complex nanocluster was successfully synthesized and assembled into framework materials with different topologies. These materials exhibited various structures and properties due to strong interactions, and Ag-23-dpbz showed the largest specific surface area and the strongest luminescence signal.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Xin-Yu Li, Yi-Lin Wang, Zhe Xue, Song-De Han, Zhen-Zhen Xue, Jie Pan
Summary: A novel heterometallic-organic framework compound with bright yellow luminescence and temperature-dependent emission spectra has been successfully synthesized, showing potential applications as a molecular luminescence thermometer and sensitive sensor for Fe'. Additionally, the compound exhibits photocatalytic activity for decomposing dye pollutants.
CRYSTAL GROWTH & DESIGN
(2021)
Article
Materials Science, Multidisciplinary
Cungang Xu, Rong Luo, Chuanbin Fan, Chenze Xie, Xia Zhang, Dongmei Zhang, Yuhua Fan
Summary: Two novel Co(II) coordination polymers were synthesized and characterized. Complex 1 exhibited a 2D -> 3D supramolecular framework, while complex 2 possessed a 1D [Co(bidpe)2]n loop line and further formed a 3D supramolecular architecture. Both CPs showed efficient photocatalytic activities towards the degradation of methyl violet under low-energy irradiation, which could be attributed to their high efficiencies in generating .OH radicals. Additionally, 1 and 2 exhibited antiferromagnetic behavior between adjacent Co(II) ions according to variable-temperature magnetic analyses.
Article
Chemistry, Physical
Liliana Dobrzanska
Summary: Two Ag(I) complexes with different structures were synthesized and compared with similar complexes containing methyl substituents. The complexes showed unique structures and were distinct from the similar complexes.
Article
Chemistry, Physical
Hong-Chuan Fan, Xin Xia, Yan-Bo Zeng, Qiu-Feng Wang, Dan Chen, Shi-Chun Qin, Chun-Qiong Wang, Qiu-E Cao, Li-Yan Zheng
Summary: This study successfully constructed CPs with different spatial topologies by designing a novel ligand with unequal coordination sites. The relationship between the properties and structures of the CPs was investigated, revealing that the 3D CPs with unique chain structures exhibited higher electrical conductivity and photothermal conversion. The results provide insights into the structure-property connection of CPs and offer a roadmap for designing functional materials.
Article
Chemistry, Inorganic & Nuclear
Kai Chen, Ran Li, Yu-Ying Peng, Zhao-Qiang Zhu, Zi-Yi Hua
Summary: Two novel 3D coordination polymers were synthesized by diffusion method, one formed by Cd(II) metal connecting with ligand L to give a two-fold interpenetrating supramolecular 3D structure, while the other formed by non-covalent interaction. The fluorescence of complex 1 shows a red-shift, while complex 2 shows a blue-shift compared to the free molecule.
INORGANICA CHIMICA ACTA
(2021)
Article
Chemistry, Applied
Guang-Li Wang, Jun Wang, Luyi Zhou, Mi Zhou, Xiaoxiong Wang, Shan-He Zhou, Lu Lu, Manoj Trivedi, Abhinav Kumar
Summary: In this study, four new Zn(II)/Cd(II) coordination polymers were synthesized and showed efficient photocatalytic performances in selectively degrading methylene blue among other dyes under UV irradiation. The photocatalytic properties of these materials were investigated using LC-MS studies, band gap calculations, and Hirshfeld surface analysis.
Article
Chemistry, Inorganic & Nuclear
V. N. Serezhkin, M. S. Grigoriev, E. F. Rogaleva, S. A. Novikov, L. B. Serezhkina
Summary: Two new uranium compounds were synthesized and studied, revealing different coordination number preferences in their crystal structures depending on the oxalate:U(VI) ratio.
SOLID STATE SCIENCES
(2021)
Article
Chemistry, Multidisciplinary
Ming-Yue Wen, Li Ren, Guang-Hua Cui
Summary: Two new Co(II) coordination compounds were synthesized and characterized, one displaying a 2D layered network while the other exhibited a dinuclear structure. Both complexes showed high pH stabilities in the range from 3 to 12, and could serve as fluorescence probes for detecting various substances with high quenching constants and low detection limits. The fluorescence sensing mechanisms of the two compounds were discussed in detail.
Article
Chemistry, Inorganic & Nuclear
Alessia Giordana, Emanuele Priola, Giacomo Gariglio, Elisabetta Bonometti, Lorenza Operti, Eliano Diana
Summary: This study investigated the impact of flexibility of tri-chelating ligands on the overall topology of CuCN derivatives. Different ligands were selected to synthesize coordination polymers and a molecular compound, revealing varying effects on the topological fragments of cyanocuprate. Vibrational analysis proved to be diagnostic of the structural patterns in these systems, particularly for cyanide stretching modes.
Article
Chemistry, Physical
Juan Pablo Leon-Gomez, Cristian Pinzon-Vanegas, Helen Paola Toledo-Jaldin, Jesus Jara-Cortes, Diego Martinez-Otero, Roberto Escudero, Maria K. Salomon-Flores, Jesus Valdes-Martinez, Alejandro Dorazco-Gonzalez
Summary: A new 1D Cu-coordination polymer and its variant were synthesized and characterized. The structures, UV-Vis absorptions, and magnetic properties of the two polymers were analyzed and compared using various techniques.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Review
Chemistry, Inorganic & Nuclear
Barbara Barszcz, Joanna Masternak, Mateusz Kowalik
Summary: Studies on coordination chemistry in the past 20 years have sparked increased interest in coordination polymers, which exhibit diverse structures and potential applications. This review mainly focuses on three main topics related to Pb(II) and Bi(III) polymers, while also exploring the impact of different ligand structures based on comprehensive literature review.
COORDINATION CHEMISTRY REVIEWS
(2021)
Article
Chemistry, Multidisciplinary
Abu Talha Aqueel Ahmed, Sankar Sekar, Shubhangi S. Khadtare, Nurul Taufiqu Rochman, Bathula Chinna, Abu Saad Ansari
Summary: In this study, MnCo2S4 nanosheet catalyst was successfully synthesized and found to exhibit superior performance in hydrogen evolution. Compared to MnCo2S4, MnCo2S4 showed low overpotentials, moderate Tafel slope, and excellent sustainability. The outstanding performance can be attributed to the increased number of electrochemically active sites and enhanced electronic conductivity on the catalyst surface.
Article
Chemistry, Multidisciplinary
Victor V. Maltsev, Elena A. Volkova, Elizaveta V. Koporulina, Diana D. Mitina, Vladimir L. Kosorukov, Anna I. Jiliaeva, Daniil A. Naprasnikov, Konstantin N. Gorbachenya, Viktor E. Kisel
Summary: The phase relationships, crystal properties and luminescence kinetics of two complex systems were studied, including unit cell parameters, segregation coefficients of impurities, and lifetimes of energy levels.
Article
Chemistry, Multidisciplinary
Xiaoman Zhang, Wangwang Xu, W. J. Meng, Andrew C. Meng
Summary: This study successfully grew high-quality single crystal AlScN nanowires through ultra-high vacuum reactive sputtering technique and characterized their structure and properties. The nanowires exhibit significantly reduced mosaic spread and predominantly single ferroelectric domains, as well as a high piezoelectric constant.
Article
Chemistry, Multidisciplinary
Tom E. de Vries, Elias Vlieg, Rene de Gelder
Summary: Networks are important for describing relationships between people, roads between cities, reactions between chemicals, and other interactions. Bipartiteness, dividing the network into two groups, can facilitate the study of the network's structure. We have developed an algorithm that can find a near-optimal bipartisation within a reasonable time frame and used it to uncover the hidden structure of the CSD cocrystal network.
Article
Chemistry, Multidisciplinary
Chuchu Han, Jing Yang, Xin Zhang, Aisen Li, Jiang Peng
Summary: An elastic crystal based on a photo-reactive acylhydrazone derivative is reported, which exhibits reversible bending behavior under UV irradiation and heating. The crystal undergoes reversible E<->Z isomerization under light and heating conditions. The crystal demonstrates excellent elastic properties and the bending can be controlled to control the output direction of red light.
Article
Chemistry, Multidisciplinary
Lingfeng Zhang, Yu Wang, Yefeng Wang, Shuai Liu, Na Zhang, Mingmin Yang, Haixia Ma, Zhaoqi Guo
Summary: This study designs and synthesizes a series of high-energy salts compounds without heavy metal ions and azide groups. The molecular structures and stability of the compounds are confirmed through single-crystal X-ray diffraction and intermolecular interaction analysis. Furthermore, the thermal stability, energetic properties, and electrical initiation properties of the compounds are investigated, suggesting their potential as primary explosives.