Article
Chemistry, Inorganic & Nuclear
Xue-Jun Zhang, Lei Wang, Xiu-Du Zhang, Yue Zhao
Summary: Coordination cages have gained significant attention due to their well-defined cavities and diverse potential applications. In this study, a new symmetrical tripodal oxazoline-based ligand was synthesized and used to form coordination cage compounds. A novel M3L2-type crystalline coordination cage complex was obtained through the reaction between the ligand and AgPF6, which exhibited three-dimensional supramolecular networks formed by noncovalent interactions. Furthermore, the obtained cage complex showed excellent catalytic performance in the cyclopropanation reaction.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Crystallography
Huarui Wang, Jianhua Qin
Summary: Three Cd(II) coordination complexes with unique structures and topologies have been successfully synthesized and characterized. The structural and dimensional diversity of these complexes highlights the important roles of the flexible ligand and aromatic polycarboxylates in constructing the frameworks. Furthermore, the different photoluminescence behaviors of the complexes in the solid state have been studied.
Article
Chemistry, Multidisciplinary
Chih-Chieh Wang, Yu-Chen Chung, Chuan-Yien Liu, Gene-Hsiang Lee, Su-Ying Chien, Bo-Hao Chen, Yu-Chun Chuang
Summary: Two solvent-dependent 3D supramolecular architectures with doubly-interpenetrating and triply-interpenetrating networks were successfully synthesized and characterized. The structures exhibited different metal coordination environments and connection modes. The solvent vapor ad-/desorption behaviors were investigated, providing insights into their properties and potential applications.
Article
Chemistry, Multidisciplinary
Taoyuan Xiu, Simei Zhang, Peng Ren, Siyan Liu, Shuai Wang, Hamza Shehzad, Jingyang Wang, Meng Zhang, Guoan Ye, Caishan Jiao, Qunyan Wu, Liyong Yuan, Zhifang Chai, Weiqun Shi
Summary: In this study, four phenanthroline diamide ligands were synthesized and evaluated for the separation of U(VI) from Mo(VI) through extraction and stripping experiments under different conditions. The results showed that the solubility of the ligands and the separation effect of U(VI) over Mo(VI) increased with the growth of alkyl chain. The chemical stoichiometry of U(VI) complexes with ligands was determined as 1:1.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Ye-Ping Li, Shi-Fen Li, Xiao Geng, Rui-Dong Wang, Lian-Cheng He, Shu-Yu Wang, Lin Du, Qi-Hua Zhao
Summary: A two-dimensional luminescent metal-organic framework and a three-dimensional framework were synthesized using a flexible trinitrogen ligand tptb, with one compound showing potential as a multi-functional luminescent sensing material for different ions. The compound exhibited good pH stability, water stability, interference immunity, and regeneration ability, making it a promising ultra-sensitive fluorescent sensor in detection applications.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Damien Bechu, Nathalie Kyritsakas, Mir Wais Hosseini, Stephane A. Baudron
Summary: A TTF derivative with four peripheral 4-picolylthio units was synthesized and used to form coordination assemblies with divalent metal salts, showing its flexibility and adaptability. Different 1D arrangements of TTF cores were observed depending on the nature of the anions, with halide salts forming stacks and thiocyanate system forming dimers.
Article
Chemistry, Multidisciplinary
Valentyna D. Slyusarchuk, Chris S. Hawes
Summary: The first examination of Fecht's acid as a non-aromatic terephthalic acid isostere revealed the potential for greater steric bulk and control of interpenetration in MOFs. The structures of two new MOFs showed promising results in terms of pore chemistry and thermal stability, suggesting the use of non-aromatic backbones as a means to disfavor deleterious inter-framework contacts.
Article
Chemistry, Inorganic & Nuclear
Sibo Wang, Bo Sun, Zhongmin Su, Guohui Hong, Xiao Li, Yanling Liu, Qingqing Pan, Jing Sun
Summary: In this study, five isostructural lanthanide metal-organic frameworks were synthesized and shown to have excellent processability and multifunctional luminescent characteristics. One of the compounds also demonstrated excellent temperature sensing performance. Additionally, two of the compounds were found to be fluorescent sensors for detecting multiple substances.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Multidisciplinary
Yijun Zhang, Chunfang Wen, Xuefeng Wu, Peng Fei Liu, Hua Gui Yang
Summary: In this study, a modification method using ligand exchange was applied to enhance the photocatalytic performance of MOFs for water splitting under visible-light irradiation. This work broadens the field of ligand modifications of MOFs.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Meenal Batra, Sarvjeet Kaur, Shruti, Manoj K. Nayak, Shih-Sheng Sun, Ashutosh S. Singh
Summary: A new methodology for the formation of 2D coordination polymers by in situ amide bond cleavage and ligand coupling has been reported. The coordination polymers were formed under mild conditions at room temperature and characterized by various techniques.
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
(2022)
Article
Biochemistry & Molecular Biology
Xiaolin Yu, Dmitry Pavlov, Alexey A. Ryadun, Andrei S. Potapov, Vladimir P. Fedin
Summary: In this study, two molecular coordination compounds, terbium(III) oxide and europium(III) oxide, were synthesized through a reaction in water. The crystal structures of these compounds were determined using single-crystal X-ray diffraction, and their properties were further characterized using various techniques. The compounds exhibited strong photoluminescence attributed to the lanthanide ions. Furthermore, the synthesis of these compounds demonstrated the potential of hexacarboxylic acid H6L as a novel linker for coordination polymers.
Article
Medicine, Research & Experimental
Maciej Nowak, Aleksandra J. Dyba, Jan Janczak, Alexander Morritt, Laszlo Fabian, Bozena Karolewicz, Yaroslav Z. Khimyak, Doris E. Braun, Karol P. Nartowski
Summary: Control over polymorphism and solvatomorphism in API is crucial for the industrial development of new drugs. In this study, cooling and suspension crystallization were applied to access polymorphs and solvates of fluconazole, and the interrelations and transformation pathways were elucidated through structural analysis and solid-state NMR.
MOLECULAR PHARMACEUTICS
(2022)
Article
Chemistry, Physical
Mirtes M. Damaceno, Carolina B. P. Ligiero, Jilder D. P. Serna, Odivaldo C. Alves, Luiz Antonio S. Costa, Daphne S. Cukierman, Nicolas A. Rey
Summary: This study investigates the reaction between HBPAMFF and CuCl2, resulting in the formation of a turquoise mono-nuclear complex (1). The analysis confirms that the phenol groups in HBPAMFF remain fully protonated upon complexation. Furthermore, the properties of the complex differ in different solvents.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Inorganic & Nuclear
Li Huang, Zi-you Ran, Xing Liu, Chun-Mei Huang, Qi-Pin Qin, Jian Zhou
Summary: In this study, a new type of organic-inorganic hybrid cadmium iodide was developed for the highly selective and sensitive detection of Cu2+, Fe3+, and Cr2O72- ions. The hybrid material not only shows promising applications as a sensor, but also potential use as a luminescent molecular thermometer.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Huiyeong Ju, Seulgi Kim, Jong Hwa Jung, Shim Sung Lee
Summary: The initial evaluation of MOF entanglements as their main limitation is changing to an opportunity since the related benefits are now known. Four divalent metal-organic frameworks (MOFs) with various entangled structures have been reported, all sharing a square net layer and further extending and interlocking in different ways based on the conformations and roles of flexible ligands and ligand-ligand or ligand-solvent interactions. The photoluminescence properties of the products were compared with those of free ligands and discussed.
Article
Chemistry, Multidisciplinary
Jun Zhang, Wataru Kosaka, Susumu Kitagawa, Masaki Takata, Hitoshi Miyasaka
CHEMISTRY-A EUROPEAN JOURNAL
(2019)
Article
Chemistry, Multidisciplinary
Gen Zhang, You-lee Hong, Yusuke Nishiyama, Songyan Bai, Susumu Kitagawa, Satoshi Horike
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2019)
Article
Multidisciplinary Sciences
Cheng Gu, Nobuhiko Hosono, Jia-Jia Zheng, Yohei Sato, Shinpei Kusaka, Shigeyoshi Sakaki, Susumu Kitagawa
Article
Nanoscience & Nanotechnology
Soumya Mukherjee, Shivani Sharma, Sujit K. Ghosh
Review
Chemistry, Multidisciplinary
Samraj Mollick, Sahel Fajal, Soumya Mukherjee, Sujit K. Ghosh
CHEMISTRY-AN ASIAN JOURNAL
(2019)
Review
Chemistry, Inorganic & Nuclear
Aamod V. Desai, Shivani Sharma, Sumanta Let, Sujit K. Ghosh
COORDINATION CHEMISTRY REVIEWS
(2019)
Article
Chemistry, Multidisciplinary
Aamod V. Desai, Shivani Sharma, Arkendu Roy, Sujit K. Ghosh
CRYSTAL GROWTH & DESIGN
(2019)
Article
Multidisciplinary Sciences
Pengyan Wu, Yang Li, Jia-Jia Zheng, Nobuhiko Hosono, Ken-ichi Otake, Jian Wang, Yanhong Liu, Lingling Xia, Min Jiang, Shigeyoshi Sakaki, Susumu Kitagawa
NATURE COMMUNICATIONS
(2019)
Article
Chemistry, Inorganic & Nuclear
Sumanta Let, Partha Samanta, Subhajit Dutta, Sujit K. Ghosh
INORGANICA CHIMICA ACTA
(2020)
Article
Chemistry, Multidisciplinary
Samraj Mollick, Tarak Nath Mandal, Atanu Jana, Sahel Fajal, Sujit K. Ghosh
Article
Chemistry, Multidisciplinary
Munehiro Inukai, Yusuke Nishiyama, Kayako Honjo, Chinmoy Das, Susumu Kitagawa, Satoshi Horike
CHEMICAL COMMUNICATIONS
(2019)
Article
Chemistry, Physical
Mariana L. Diaz-Ramirez, Eli Sanchez-Gonzalez, J. Raziel Alvarez, Gerardo A. Gonzalez-Martinez, Satoshi Horike, Kentaro Kadota, Kenji Sumida, Eduardo Gonzalez-Zamora, Marie-Anne Springuel-Huet, Aida Gutierrez-Alejandre, Vojtech Jancik, Shuhei Furukawa, Susumu Kitagawa, Ilich A. Ibarra, Enrique Lima
JOURNAL OF MATERIALS CHEMISTRY A
(2019)
Article
Chemistry, Multidisciplinary
Kentaro Kadota, Nghia Tuan Duong, Yusuke Nishiyama, Easan Sivaniah, Susumu Kitagawa, Satoshi Horike
Article
Chemistry, Multidisciplinary
Sanjog S. Nagarkar, Haruna Kurasho, Nghia Tuan Duong, Yusuke Nishiyama, Susumu Kitagawa, Satoshi Horike
CHEMICAL COMMUNICATIONS
(2019)
Article
Nanoscience & Nanotechnology
Samraj Mollick, Tarak Nath Mandal, Atanu Jana, Sahel Fajal, Aamod V. Desai, Sujit K. Ghosh
ACS APPLIED NANO MATERIALS
(2019)
Article
Chemistry, Multidisciplinary
Abu Talha Aqueel Ahmed, Sankar Sekar, Shubhangi S. Khadtare, Nurul Taufiqu Rochman, Bathula Chinna, Abu Saad Ansari
Summary: In this study, MnCo2S4 nanosheet catalyst was successfully synthesized and found to exhibit superior performance in hydrogen evolution. Compared to MnCo2S4, MnCo2S4 showed low overpotentials, moderate Tafel slope, and excellent sustainability. The outstanding performance can be attributed to the increased number of electrochemically active sites and enhanced electronic conductivity on the catalyst surface.
Article
Chemistry, Multidisciplinary
Victor V. Maltsev, Elena A. Volkova, Elizaveta V. Koporulina, Diana D. Mitina, Vladimir L. Kosorukov, Anna I. Jiliaeva, Daniil A. Naprasnikov, Konstantin N. Gorbachenya, Viktor E. Kisel
Summary: The phase relationships, crystal properties and luminescence kinetics of two complex systems were studied, including unit cell parameters, segregation coefficients of impurities, and lifetimes of energy levels.
Article
Chemistry, Multidisciplinary
Xiaoman Zhang, Wangwang Xu, W. J. Meng, Andrew C. Meng
Summary: This study successfully grew high-quality single crystal AlScN nanowires through ultra-high vacuum reactive sputtering technique and characterized their structure and properties. The nanowires exhibit significantly reduced mosaic spread and predominantly single ferroelectric domains, as well as a high piezoelectric constant.
Article
Chemistry, Multidisciplinary
Tom E. de Vries, Elias Vlieg, Rene de Gelder
Summary: Networks are important for describing relationships between people, roads between cities, reactions between chemicals, and other interactions. Bipartiteness, dividing the network into two groups, can facilitate the study of the network's structure. We have developed an algorithm that can find a near-optimal bipartisation within a reasonable time frame and used it to uncover the hidden structure of the CSD cocrystal network.
Article
Chemistry, Multidisciplinary
Chuchu Han, Jing Yang, Xin Zhang, Aisen Li, Jiang Peng
Summary: An elastic crystal based on a photo-reactive acylhydrazone derivative is reported, which exhibits reversible bending behavior under UV irradiation and heating. The crystal undergoes reversible E<->Z isomerization under light and heating conditions. The crystal demonstrates excellent elastic properties and the bending can be controlled to control the output direction of red light.
Article
Chemistry, Multidisciplinary
Lingfeng Zhang, Yu Wang, Yefeng Wang, Shuai Liu, Na Zhang, Mingmin Yang, Haixia Ma, Zhaoqi Guo
Summary: This study designs and synthesizes a series of high-energy salts compounds without heavy metal ions and azide groups. The molecular structures and stability of the compounds are confirmed through single-crystal X-ray diffraction and intermolecular interaction analysis. Furthermore, the thermal stability, energetic properties, and electrical initiation properties of the compounds are investigated, suggesting their potential as primary explosives.
