4.7 Article

Pre-strain enhances film rupture to promote SCC of brass in Mattsson's solution - A proposal for a film-rupture-induced SCC mechanism

Journal

CORROSION SCIENCE
Volume 69, Issue -, Pages 302-310

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2012.11.043

Keywords

Brass; SEM; Stress corrosion

Funding

  1. National Nature Science Foundation of China [51071028, 51171024, 50901010]

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The stress corrosion cracking (SCC) behaviour of H62 brass with various levels of pre-strains in Mattsson's solution was investigated using electrochemical and SCC tests. The results revealed that the corrosion current densities increased and the work function decreased when the pre-strains increased, which facilitate anodic dissolution, thereby resulting in an increase of the film growth rate and the film-induced stress, ultimately resulting in the enhancement of film rupture and SCC susceptibility. Based on the obtained results, a film-rupture-induced SCC mechanism of brass in Mattsson's solutions was proposed. (C) 2012 Elsevier Ltd. All rights reserved.

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