4.7 Article

In situ characterization by localized electrochemical impedance spectroscopy of the electrochemical activity of microscopic inclusions in an X100 steel

Journal

CORROSION SCIENCE
Volume 53, Issue 2, Pages 850-853

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2010.11.026

Keywords

Steel; EIS; SEM; Inclusion

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A localized electrochemical impedance spectroscopy (LEIS) technique was used to characterize in situ the micro-electrochemical activity of inclusions contained in an American Petroleum Institute (API) X100 steel in a near-neutral pH solution. It is found that there exists an electrochemical heterogeneity between inclusions and the adjacent steel matrix. Consequently, a galvanic couple is formed to result in the locally preferential dissolution. The local electrochemical activity of the inclusion depends on its composition. A Si-enriched inclusion is associated with a high electrochemical activity, and the preferential dissolution of the inclusion generates a local microvoid. whose further dissolution initiates a corrosion pit. An aluminum oxide-enriched inclusion is more stable than the adjacent steel matrix. The preferential dissolution would occur on the steel, causing the drop-off of the inclusion and generating a corrosion pit. (C) 2010 Elsevier Ltd. All rights reserved.

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