Article
Chemistry, Multidisciplinary
Wei-Hai Fang, Todd J. Martinez, Lihong Liu
Summary: Light-driven molecular motors, such as the chiral N-alkyl imines reported by Greb and Lehn, show promising potential in material and biological systems. However, the mechanism of unidirectional rotation in these motors is not fully understood. Through computational study, we find that the location and energetics of conical intersections alone cannot explain the motor's mechanism, and dynamic effects and out-of-plane distortions play a crucial role. Our results provide insights on how to improve the efficiency of photoisomerization in this class of molecular motors.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Xuehan Zhou, Yan Liang, Huixia Fu, Ruixue Zhu, Jingyue Wang, Xuzhong Cong, Congwei Tan, Congcong Zhang, Yichi Zhang, Yani Wang, Qijia Xu, Peng Gao, Hailin Peng
Summary: The researchers proposed a step-climbing epitaxy growth strategy, which can achieve molecular beam epitaxy growth of 2D layered crystals on stepped substrates with a large lattice mismatch, and obtain high-quality large-area epitaxial films. Controllable thickness 2D Bi2O2Se single-crystal films can be synthesized using this strategy, and the films exhibit higher Hall mobility compared to other materials with similar thickness.
ADVANCED MATERIALS
(2022)
Article
Materials Science, Ceramics
Jothi Ramalingam Rajabathar, Prabhakarn Arunachalam, Hamad A. AL-Lohedan, Radhika Thankappan, Jimmy Nelson Appaturi, Thiruchelvi Pulingam, Wasmiah Mohammed Dahan
Summary: By utilizing Triton-X-100 polymer assisted precipitation process, silver nanoparticles were decorated on nanotubes morphology of Bismuth doped manganese oxide (Bi-MnOx), while Ag nanoparticles with very fine particle size and graphene nanoparticles were deposited using high power ultra-sonication method. The synthesized Bi-MnOx with silver nanoparticles could be utilized for non-enzymatic detection of hydrogen peroxide sensor application. The material has potential applications in visible light photo-catalysis and antimicrobial applications.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Physical
Y. Gerasymchuk, A. Kedziora, A. Wedzynska, L. Tahershamsi, V Chernii, I Tretyakova, S. Chernii, V Pekhnyo, I Korona-Glowniak, A. Malm, Barbara Rajtar, T. Bachanek, D. Piatek, G. Bugla-Ploskonska, A. Lukowiak
Summary: The synthesis of a group of photoactive materials based on zirconium(IV) phthalocyanine out-of-plane substituted with two fragments of L-arginine was described in this work. The materials, including Pc complex, complex immobilized on graphite oxide flakes, GO-Pc composite with silver nanoparticles, and GO-Pc in dental filling cement, showed photocatalytic activity under red light exposure. The bioactivity against bacteria strains was highest for S. aureus, with GO-Pc showing the lowest cytotoxicity among different Pc complexes.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Z. Csaszar, G. Farkas, A. Benyei, G. Lendvay, I. Toth, J. Bakos
DALTON TRANSACTIONS
(2015)
Article
Chemistry, Physical
Anna Busch, Nuria Gonzalez-Garcia, Gyoergy Lendvay, Matthias Olzmann
JOURNAL OF PHYSICAL CHEMISTRY A
(2015)
Article
Chemistry, Physical
Peter Szabo, Gyoergy Lendvay
JOURNAL OF PHYSICAL CHEMISTRY A
(2015)
Article
Chemistry, Physical
Peter Szabo, Gyoergy Lendvay
JOURNAL OF PHYSICAL CHEMISTRY A
(2015)
Article
Chemistry, Physical
Tibor Nagy, Anna Vikar, Gyoegy Lendvay
JOURNAL OF CHEMICAL PHYSICS
(2016)
Article
Chemistry, Physical
Sridhar A. Lahankar, Jianming Zhang, Timothy K. Minton, Hua Guo, Gyorgy Lendvay
JOURNAL OF PHYSICAL CHEMISTRY A
(2016)
Article
Chemistry, Physical
Anna Vikar, Tibor Nagy, Gyorgy Lendvay
JOURNAL OF PHYSICAL CHEMISTRY A
(2016)
Article
Chemistry, Inorganic & Nuclear
Csaba Feher, Mate Papp, Agnes Gomory, Livia Nagy, Johan Wouters, Gyorgy Lendvay, Rita Skoda-Foldes
Article
Chemistry, Physical
Tibor Nagy, Gyorgy Lendvay
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2017)
Article
Chemistry, Physical
Attila Tajti, Gyorgy Lendvay, Peter G. Szalay
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2017)
Article
Energy & Fuels
Szabolcs Goger, Peter Szabo, Gabor Czako, Gyorgy Lendyay
Article
Chemistry, Physical
Tibor Nagy, Anna Vikar, Gyoergy Lendvay
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2018)
Article
Chemistry, Physical
Zsombor Miskolczy, Laszlo Biczok, Gyorgy Lendvay
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2018)
Article
Chemistry, Applied
Gyula Novodarszki, Hanna E. Solt, Gyorgy Lendvay, R. Magdolna Mihalyi, Anna Vikar, Ferenc Lonyi, Jeno Hancsok, Jozsef Valyon
Article
Chemistry, Physical
Gyorgy Lendvay
JOURNAL OF PHYSICAL CHEMISTRY A
(2019)
Review
Chemistry, Inorganic & Nuclear
Pegah Hajivand, Johannes Carolus Jansen, Emilio Pardo, Donatella Armentano, Teresa F. Mastropietro, Amirreza Azadmehr
Summary: VOCs in human breath can be used as biomarkers for diseases, and MOFs have been extensively studied as gas sensors for VOCs. This review provides a comprehensive summary of the latest MOF-derived composites used as VOCs biomarkers' sensors, and discusses the structural and functional characteristics of MOFs, sensing properties, and the potential of bio-MOFs in VOCs sensing.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Seoyoon Song, Deborah Lee, Lucia C. Dalle Ore, Sungjun Kwak, Lifeng Kang, Hyung Kyo Kim, Noah Malmstadt, Sun Min Kim, Tae-Joon Jeon
Summary: This paper introduces the latest advancements in photoactivable liposomes in drug delivery, highlighting their advantages in precise control over drug release and targeted delivery, as well as the fine control over release kinetics achieved through the manipulation of light-responsive components. Additionally, the paper emphasizes the design considerations of physicochemical properties and light-related constituents.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Shudi Liu, Liangwei Zhang, Heejeong Kim, Jinyu Sun, Juyoung Yoon
Summary: Chromium is a strategic and critical transition metal element with extensive applications. Efficient detection methods, such as fluorescence and colorimetry, have been developed for monitoring its concentrations. However, existing reviews on fluorescent probes for chromium lack comprehensive coverage. This review aims to consolidate information and promote the development of novel fluorescent probes for chromium detection.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Rehab H. Elattar, Samah F. El-Malla, Amira H. Kamal, Fotouh R. Mansour
Summary: Metal complexes have strong analysis potential and can be used to measure analytes lacking essential chemical properties. Their analytical methods based on different mechanisms offer superior performance.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Nem Singh, Miae Won, Yunjie Xu, Changyu Yoon, Jiyoung Yoo, Mingle Li, Heemin Kang, Jong Seung Kim
Summary: Hypoxia is a common occurrence in the tumor microenvironment and poses challenges for cancer treatment. The introduction of covalent organic frameworks (COFs) offers promising prospects for addressing hypoxia-related issues. This article explores the role of COFs in enhancing oxygen delivery, generating reactive oxygen species, optimizing drug delivery, and enabling hypoxia-specific imaging, as well as outlining their applications in various hypoxia-targeting therapeutic modalities.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Priyadarshi Roy Chowdhury, Himani Medhi, Krishna G. Bhattacharyya, Chaudhery Mustansar Hussain
Summary: This review critically analyzes the production of waste-derived layered double hydroxides (LDH) and their utility in electrochemical water splitting for the generation of green hydrogen as sustainable energy. It highlights the importance of waste-derived LDH and discusses the challenges and future directions in this field.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Rajamanickam Sivakumar, Nae Yoon Lee
Summary: This article reviews the progress in imaging reactive oxygen, nitrogen, and sulfur species (RONSS) using luminescent metal complex-based probes. This technology is selective and sensitive, which is of great significance for studying the impact of RONSS in cells and tissues and preventing diseases.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Xinyang Li, Binbin Ding, Pan Zheng, Ping'an Ma, Jun Lin
Summary: The main goal of immunotherapy is to enhance the response and cytotoxicity of tumor-specific T cells by turning cold tumors into hot tumors. However, metabolic reprogramming in the tumor microenvironment can depress the cytotoxicity of T cells and hinder the effectiveness of immunotherapy. This review discusses the role of metabolic reprogramming in the interplay between cancer cells and immune cells in the tumor microenvironment and explores the use of nanomaterials to modulate metabolic pathways and improve immunotherapy outcomes.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Kingsley Poon, Abhishek Gupta, William S. Price, Hala Zreiqat, Gurvinder Singh
Summary: Progress in the development of manganese oxide nanoparticles (MONPs) has provided an alternative for early-stage diagnosis of life-threatening diseases and therapeutic delivery of drugs and genes. The synthesis and characterization of MONPs have enabled the production of multi-functional targeted nanoparticles in various sizes and shapes. The integration of diagnosis and therapeutic capabilities within a single entity, known as nanotheranostics, is promising for real-time monitoring of disease progression and evaluating therapeutic treatment efficacy.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Reza Abedi-Firoozjah, Hadiseh Ebdali, Mahya Soltani, Parastoo Abdolahi-Fard, Mahshid Heydari, Elham Assadpour, Maryam Azizi-Lalabadi, Fuyuan Zhang, Seid Mahdi Jafari
Summary: With the increasing awareness of food safety, there is a growing demand for efficient and affordable sensing methods for the detection of pathogens and toxins in food products. Nanosensors offer promising solutions with their quick and reliable detection capabilities, although challenges remain in their fabrication and practical application.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Demei Sun, Xuesong Feng, Xinyuan Zhu, Youfu Wang, Jinghui Yang
Summary: Metal organic cages (MOCs) with precise and tunable nano structures show great potential in cancer therapy. Their diverse functions and ultrasmall size make them excellent nanoagents for different anticancer strategies, demonstrating outstanding anticancer performances.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Li Li, Yang-Tao Yu, Ning-Ning Zhang, Shu-Hao Li, Jian-Ge Zeng, Yang Hua, Hong Zhang
Summary: This article summarizes recent advances in POM-based hybrid photochromic materials (PCHPMs), including structure types, new photochromic mechanisms, and applications. It can provide valuable guidance for researchers investigating POM-based hybrid photochromic materials.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Chien Ing Yeo, Clariss Hui Peng Goh, Edward R. T. Tiekink, Jactty Chew
Summary: This review article provides an overview of the antibacterial activity of gold complexes, with a focus on gold(I) and gold(III) complexes. It also summarizes the repurposing of Auranofin for antibacterial purposes and the associated mechanism(s) of action.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Sangharaj Diyali, Nilankar Diyali, Bhaskar Biswas
Summary: This study discusses the recent progress in the design and development of catalysts, focusing on the factors influencing overpotential, catalytic rate, and stability, as well as the mechanisms of the hydrogen evolution reaction in acidic and alkaline media. Moreover, it outlines the challenges in future design of robust and active electrocatalysts.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Shaik Gouse Peera, Rahul S. Menon, Sumanta Kumar Das, Akram Alfantazi, K. Karuppasamy, Chao Liu, Akhila Kumar Sahu
Summary: Doped carbon materials, especially F-doped carbon catalysts, have gained significant attention as metal-free catalysts for oxygen reduction reactions and as corrosion-resistant supports for Pt and non-Pt nanoparticles. F-doped carbon materials possess unique properties and greatly improve the activity and durability of the ORR compared to N-doped carbon materials. The high electronegativity of F-doping can efficiently modify the electronic band structure of carbon materials, favoring the ORR. This review systematically discusses the effect of F-doping/F co-doping on the electrocatalytic reduction of O2 in acidic and alkaline conditions, the stability and durability of fuel cell catalysts, and provides guidelines for working with F-doped carbons. Future research directions on F-doped carbons are also proposed to bridge the gap between laboratory-scale assessments and commercial applications.
COORDINATION CHEMISTRY REVIEWS
(2024)