4.7 Article

Effect of pH on pitting corrosion of stainless steel welds in alkaline salt water

Journal

CONSTRUCTION AND BUILDING MATERIALS
Volume 68, Issue -, Pages 709-715

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2014.06.090

Keywords

Stainless steel; Polarization; EIS; Welding; Pitting corrosion

Funding

  1. National Natural Science Foundation of China [51222106]
  2. Beijing Municipal Commission of Education [2013150301601]

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Pitting corrosion was studied in the weldment of 304L austenitic stainless steels joint with 308L austenitic stainless steels. The corrosion behavior of three different weldment zones (weld metal (WM), base metal (BM) and heat affected zone (HAZ)) in alkaline solutions with NaCl was characterized by a series of electrochemical tests. The results indicated that pH values played an important role in the corrosion behavior of the weldment. With the pH increasing, the film resistance, polarization resistance and Econ. increases, the charge carrier density N and the site of the pitting on the weldment decreases. In addition, WM showed a better corrosion resistance, followed by HAZ and BM. The pittings in BM were much bigger than that in WM and HAZ. (C) 2014 Elsevier Ltd. All rights reserved.

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