Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 397, Issue -, Pages 106-113Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2014.10.029
Keywords
Magnetic; Palladium; Copper; Synergistic; Cyanation
Categories
Funding
- Institute for Advanced Studies in Basic Sciences (IASBS) Research Council
- Iran National Science Foundation (INSF) [93020713]
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In this paper, for the first time, palladium nanoparticles were supported on (3-aminopropyl) triethoxysilane-modified copper ferrite nanoparticles. The obtained catalyst was characterized using FT-IR, TEM, EDX, AAS, XRD, and TGA analyses. The prepared heterogeneous catalyst showed superior activity toward cyanation of aryl iodides and bromides with K-4[Fe(CN)(6)] compared to the Fe3O4 supported palladium nanoparticles, unfunctionalized CuFe2O4 nanoparticles, homogeneous Pd(OAc)(2), CuCl2, and CuI catalysts. The heterogeneous and low Pd loading catalyst was recycled for four consecutive runs with small drops in catalytic activity. (C) 2014 Elsevier B.V. All rights reserved.
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