Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 397, Issue -, Pages 1-18Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2014.10.018
Keywords
Pd catalysts; Nanoparticles; PAMAM dendrimer; Selective hydrogenation
Categories
Funding
- RFBR [14-03-3153-A]
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A novel method has been proposed for encapsulating palladium nanoparticles up to 5 nm in the matrix of polymeric support networks based on polyamidoamine dendrimers. The shape of the particle size distribution and the catalytic activity of the materials obtained during the hydrogenation of unsaturated compounds depend strongly on the support structure. High activity (TOF up to 86,000 h(-1)) has been observed during the hydrogenation of styrene. (C) 2014 Elsevier B.V. All rights reserved.
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