Article
Chemistry, Multidisciplinary
H. Hemanth, Sairam S. Mallajosyula
Summary: This study used polarizable molecular dynamics simulation to investigate the self-assembly of nucleobases on a graphene sheet. The introduction of polarization led to significant changes in interaction patterns, including the stacking probability in guanine-rich systems and the formation of hydrogen-bonded structures on the graphene sheet, highlighting the importance of DNA sequence and composition.
Article
Chemistry, Multidisciplinary
R. Guerrero-Aviles, M. Pelc, F. R. Geisenhof, R. T. Weitz, A. Ayuela
Summary: Stackings in graphene play a pivotal role in its properties, including the recently discovered superconductivity of twisted bilayer graphene. Rhombohedral stacking in multilayer graphene has interesting flat bands near the Fermi level, but its stability has been debated. We conducted a detailed investigation of trilayer graphene stackings and found that rhombohedral and Bernal stackings have similar energies, and switching between stable stackings can be induced by shear deformation and symmetry breaking.
Article
Chemistry, Analytical
Octavian-Gabriel Simionescu, Andrei Avram, Bianca Adiaconita, Petruta Preda, Catalin Parvulescu, Florin Nastase, Eugen Chiriac, Marioara Avram
Summary: The progress of advanced materials has led to increasing interest in novel biosensing applications, particularly in the use of field-effect transistors (FETs) due to their material variability and self-amplifying electrical signals. Graphene and other graphene-derived materials (GDMs) have emerged as promising materials for biosensors, offering exceptional properties such as thermal and electrical conductivity, mechanical strength, and high surface area for receptor immobilization. This comparative experimental study presents FETs with channels fabricated from three different graphenic materials: single-layer graphene (SLG), graphene/graphite nanowalls (GNW), and bulk nanocrystalline graphite (bulk-NCG). The study explores the conductivity and sensitivity of these FETs through SEM, Raman spectroscopy, and I-V measurements, with bulk-NCG-based FETs demonstrating the highest electrical conductance and enhanced sensitivity with Au nanoparticle functionalization.
Article
Chemistry, Multidisciplinary
Adil Rehman, Juan Antonio Delgado Notario, Juan Salvador Sanchez, Yahya Moubarak Meziani, Grzegorz Cywinski, Wojciech Knap, Alexander A. Balandin, Michael Levinshtein, Sergey Rumyantsev
Summary: This study demonstrates that mobility fluctuations are the dominant mechanism of low-frequency electronic noise in high-quality graphene, providing important insights for its applications in electronics and understanding the origin of 1/f noise in any electronic device.
Article
Chemistry, Multidisciplinary
Zhi-Bin Jian, Jie Bie, Shuang Chen
Summary: Confined ammonia molecules form a stable new rhomboidal phase in graphene oxide/graphene nanosheets, showing liquid-like behavior at room temperature and high stability requiring significant strain to destroy. These rhomboidal NH3 monolayers offer diverse hydrogen-bonded networks and potential piezoelectricity for future device applications.
Article
Chemistry, Physical
Matthew J. Mason, Bryan J. Coleman, Sanjit Saha, Mazin M. Mustafa, Micah J. Green
Summary: A bulk, rapid testing methodology is demonstrated to distinguish graphene from graphite based on the frequency-dependent heating response, which can match a given graphene sample with a reference graphene grade.
Article
Chemistry, Multidisciplinary
Kaidi Zhang, Yun Yu, Stephen Carr, Mohammad Babar, Ziyan Zhu, Bryan Junsuh Kim, Catherine Groschner, Nikta Khaloo, Takashi Taniguchi, Kenji Watanabe, Venkatasubramanian Viswanathan, D. Kwabena Bediako
Summary: By controlling interlayer twists in trilayer graphene moiré, we demonstrate that interfacial electron-transfer rates depend strongly on electronic localization in each atomic layer, rather than the overall electronic density of states. The high tunability of moiré electrodes leads to local electron-transfer kinetics that vary over three orders of magnitude across different constructions of only three atomic layers, even surpassing rates observed in bulk metals. Our findings highlight the critical role of electronic localization in facilitating interfacial electron transfer, with implications for understanding the high interfacial reactivity of defects at electrode-electrolyte interfaces.
ACS CENTRAL SCIENCE
(2023)
Article
Chemistry, Physical
Alexander J. Auty, Negar Mansouriboroujeni, Thiba Nagaraja, Dimitri Chekulaev, Christopher M. Sorensen, Suprem R. Das, Natalia Martsinovich, Adrien A. P. Chauvet
Summary: The electronic properties of inkjet-printed aerosol gel graphene (AG) films and inkjet-printed graphene (G) films were compared. AG films have a higher oxygen content and a complex 3D morphology compared to graphene. The similarity in the carrier-optical phonon scatter rates suggests a comparable lattice defect density between AG and G films. Interestingly, AG films exhibit lower recovery of the transient signal, indicating the presence of long-lived electronic states.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Physical
Alexander J. Marsden, Mark Skilbeck, Matthew Healey, Helen R. Thomas, Marc Walker, Rachel S. Edwards, Natalya A. Garcia, Filip Vukovic, Hicham Jabraoui, Tiffany R. Walsh, Jonathan P. Rourke, Neil R. Wilson
Summary: This article investigates the structural traits of graphene oxide (GO) and their impact on properties. Through experimental approaches and molecular simulations, it is found that extended topological defects are common in GO and greatly influence its properties. The presence of these defects plays a crucial role in the retention of oxygen functional groups after reduction, and GO displays lower strength and stiffness compared to graphene.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Multidisciplinary Sciences
Katarzyna Z. Donato, Hui Li Tan, Valeria S. Marangoni, Marcos V. S. Martins, Pei Rou Ng, Mariana C. F. Costa, Purvi Jain, Sarah J. Lee, Gavin K. W. Koon, Ricardo K. Donato, A. H. Castro Neto
Summary: Given the increasing industrial use of graphene-related materials, it is necessary to classify and standardize them. Graphene oxide (GO) is one of the most used and difficult to classify materials. However, inconsistent definitions of GO are found in the literature and industrial brochures, which creates confusion. This lack of regulation and standardization leads to trust issues and hinders industrial development. This study critically assesses commercially available GOs and establishes correlations between their physicochemical properties and applications, providing a rationale for their classification.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Multidisciplinary
Ayelet Zalic, Takashi Taniguchi, Kenji Watanabe, Snir Gazit, Hadar Steinberg
Summary: In this work, a novel atomically thin, all van der Waals SQUID is constructed, in which current flows between NbSe2 contacts through parallel graphene weak links. The 2D planar SQUID remains stable at high in-plane fields, enabling the tracing of critical current interference patterns and the observation of a field-driven transition. The asymmetric SQUID geometry is further suggested for directly probing current density in the absence of phase information.
Article
Physics, Multidisciplinary
Masahiro Kamada, Weijun Zeng, Antti Laitinen, Jayanta Sarkar, Sheng-Shiuan Yeh, Kirsi Tappura, Heikki Seppa, Pertti Hakonen
Summary: The authors investigate the sources of 1/f noise using a suspended graphene Corbino device and provide evidence that mobility fluctuations are an essential contributing factor. The work shows that the noise can be suppressed in a high-mobility graphene Corbino disk, indicating potential technological benefits for low noise 2D devices. The results suggest that the 1/f noise is induced by scattering of carriers on mobile impurities forming clusters.
COMMUNICATIONS PHYSICS
(2023)
Article
Physics, Applied
Yong Han, James W. Evans, Michael C. Tringides
Summary: The study investigates the kinetic process of foreign guest atom intercalation into graphene layers and provides numerical values for the critical energy barriers through theoretical calculations.
APPLIED PHYSICS LETTERS
(2021)
Article
Materials Science, Multidisciplinary
Andrew McEllistrim, Aitor Garcia-Ruiz, Zachary A. H. Goodwin, Vladimir I. Fal'ko
Summary: Tetralayer graphene, a new member of few-layer graphenes, demonstrates versatile electronic properties. Spectroscopic characteristics, such as angle-resolved photoemission spectroscopy, dynamical optical conductivity, and Raman spectra, can be used to identify the stacking order of tetralayer graphene films in a noninvasive manner.
Article
Chemistry, Physical
Ruitao Jin, Filip Vukovic, Tiffany R. Walsh
Summary: This study investigates the key steps of graphene exfoliation and recombination in aqueous media through molecular simulations. The results show that peptide P1 can increase the energy barrier for graphene exfoliation, but also raise the barrier for sheet recombination, contributing to stable graphene dispersion in water.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Physics, Applied
M. J. Grzybowski, C. F. Schippers, M. E. Bal, K. Rubi, U. Zeitler, M. Foltyn, B. Koopmans, H. J. M. Swagten
Summary: One of the key challenges in antiferromagnetic spintronics is the detection of the Neel vector state. High current densities used in electrical switching experiments make it difficult to differentiate between magnetic and thermal origins of electrical signals. To address this, a study of temperature dependence in the switching experiment with CoO | Pt devices is presented. It is shown that a pattern of spin Hall magnetoresistance, indicative of the magnetic origin of the signal, can be extracted for current pulses below the Neel temperature. These findings are confirmed by additional experiments in an external magnetic field.
APPLIED PHYSICS LETTERS
(2022)
Article
Instruments & Instrumentation
A. Apponi, M. G. Betti, M. Borghesi, N. Canci, G. Cavoto, C. Chang, W. Chung, A. G. Cocco, A. P. Colijn, N. D'Ambrosio, N. de Groot, M. Faverzani, A. Ferella, E. Ferri, L. Ficcadenti, S. Gariazzo, F. Gatti, C. Gentile, A. Giachero, Y. Hochberg, Y. Kahn, A. Kievsky, M. Lisanti, G. Mangano, L. E. Marcucci, C. Mariani, M. Messina, E. Monticone, A. Nucciotti, D. Orlandi, F. Pandolfi, S. Parlati, C. Perez de los Heros, O. Pisanti, A. D. Polosa, A. Puiu, I Rago, Y. Raitses, M. Rajteri, N. Rossi, K. Rozwadowska, A. Ruocco, C. F. Strid, A. Tan, C. G. Tully, M. Viviani, U. Zeitler, F. Zhao
Summary: The paper presents the implementation and optimization methods of the PTOLEMY transverse drift filter for precise analysis of the energy spectrum of electrons near the tritium beta-decay endpoint. Simulation results show that low-energy electrons with an initial kinetic energy of 18.6 keV can be drained to < 10 eV using a 1 T iron core (or 3 T superconducting) starting field under low field operation conditions.
JOURNAL OF INSTRUMENTATION
(2022)
Article
Chemistry, Multidisciplinary
Jan Wyzula, Ivan Mohelsky, Diana Vaclaykoya, Piotr Kapuscinski, Martin Veis, Clement Faugeras, Marek Potemski, Mike E. Zhitomirsky, Milan Orlita
Summary: We report on magneto-optical studies of the quasi-two-dimensional van der Waals antiferromagnet FePS3. Our measurements reveal an unusual antiferromagnetic resonance excitation with a four-times larger Zeeman splitting in an applied magnetic field. We attribute this excitation to the condensation of multipolar magnons, which can produce new exotic states in large-spin materials with a strong magnetic anisotropy.
Article
Optics
S. Gebert, C. Consejo, S. S. Krishtopenko, S. Ruffenach, M. Szola, J. Torres, C. Bray, B. Jouault, M. Orlita, X. Baudry, P. Ballet, S. V. Morozov, V. I. Gavrilenko, N. N. Mikhailov, S. A. Dvoretskii, F. Teppe
Summary: Since the emergence of graphene, proposals for tunable Landau lasers in the terahertz frequency range have been made. Despite the non-equidistance of the Landau levels, a non-radiative process still persists in Landau-quantized graphene. This work demonstrates Landau emission from Dirac fermions in HgTe quantum wells, which can be tuned by both magnetic field and carrier concentration.
Article
Multidisciplinary Sciences
Daniel Vaquero, Vito Clerico, Michael Schmitz, Juan Antonio Delgado-Notario, Adrian Martin-Ramos, Juan Salvador-Sanchez, Claudius S. A. Mueller, Km Rubi, Kenji Watanabe, Takashi Taniguchi, Bernd Beschoten, Christoph Stampfer, Enrique Diez, Mikhail I. Katsnelson, Uli Zeitler, Steffen Wiedmann, Sergio Pezzini
Summary: The researchers demonstrate a novel transport regime in which dissipation in the quantum Hall phase is predominantly governed by electron-phonon scattering in graphene encapsulated in hexagonal boron nitride.
NATURE COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
M. Meinero, F. Caglieris, A. Leveratto, L. Repetto, M. Fujioka, Y. Takano, U. Zeitler, I Pallecchi, M. Putti
Summary: Through temperature-dependent magnetotransport experiments, we have observed multiple features in the transport properties of the parent compound SmFeAsO of iron pnictide superconductors below the antiferromagnetic ordering temperature of Sm. These features evolve with in-plane magnetic field, suggesting the presence of rich and previously unobserved metamagnetic transitions in this compound. The findings indicate that these features originate from magnetic transitions of the Fe moments sublattice, induced by the magnetic transitions of the Sm moments sublattice. Our work demonstrates the usefulness of transport properties in investigating magnetic ordering in the parent compounds of iron pnictide superconductors, which is believed to be the origin of high-temperature superconductivity.
JOURNAL OF PHYSICS-MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Ruth Weller, Mihail Atanasov, Serhiy Demeshko, Ting-Yi Chen, Ivan Mohelsky, Eckhard Bill, Milan Orlita, Franc Meyer, Frank Neese, C. Gunnar Werncke
Summary: The magnetic properties of linear iron(I) silylamides K{crypt}[FeL2] and [KFeL2] were investigated. Slow-relaxation of magnetization, magnetic hysteresis, and magnetic blocking were observed in K{crypt}[FeL2]. In [KFeL2], with increased axial anisotropy, higher relaxation barrier and blocking temperature were observed, in agreement with field-dependent IR-spectroscopy, magnetic measurements, and theoretical analysis.
INORGANIC CHEMISTRY
(2023)
Article
Multidisciplinary Sciences
Puhua Wan, Oleksandr Zheliuk, Noah F. Q. Yuan, Xiaoli Peng, Le Zhang, Minpeng Liang, Uli Zeitler, Steffen Wiedmann, Nigel E. Hussey, Thomas T. M. Palstra, Jianting Ye
Summary: We report the discovery of an orbital FFLO state in the multilayer Ising superconductor 2H-NbSe2, which is characterized by finite-momentum Cooper pairings. Transport measurements reveal the broken translational and rotational symmetries in this state. By establishing the entire orbital FFLO phase diagram, we demonstrate the existence of this state and provide a universal mechanism for preparing orbital FFLO states in similar materials with broken inversion symmetries.
Article
Chemistry, Multidisciplinary
Amit Pawbake, Thomas Pelini, Ivan Mohelsky, Dipankar Jana, Ivan Breslavetz, Chang-Woo Cho, Milan Orlita, Marek Potemski, Marie-Aude Measson, Nathan P. Wilson, Kseniia Mosina, Aljoscha Soll, Zdenek Sofer, Benjamin A. Piot, Mike E. Zhitomirsky, Clement Faugeras
Summary: This study investigates the magnetization process of a biaxial antiferromagnet under an external magnetic field and finds that applying hydrostatic pressure can induce a metamagnetic transition, leading to a new magnetic phase.
Article
Materials Science, Multidisciplinary
Rajesh Dutta, Henrik Thoma, Andrew Sazonov, Balint Nafradi, Martin Meven, Arsen Gukasov, Vilmos Kocsis, Uli Zeitler, Alessandro Puri, Yusuke Tokunaga, Yasujiro Taguchi, Yoshinori Tokura, Sandor Bordacs, Istvan Kezsmaerki, Vladimir Hutanu
Summary: We conducted a study on a multiferroic Sr2CoSi2O7 (SCSO) single crystal using polarized and unpolarized neutron diffraction. Our measurements confirmed the existence of melilite-type tetragonal P4 over bar 21m space group as the parent structure of SCSO at 15 K, but revealed symmetry lowering with the possible orthorhombic Cmm'2' and P212'12' magnetic space groups at 2.3 K. The obtained ordered magnetic moments in both Cmm'2' and P212'12' magnetic space groups were around 2.86 and 2.94 mu B/Co2+ respectively, lying in the ab plane. Furthermore, our spin polarized flipping ratio measurements supported the presence of strong easy-plane spin anisotropy responsible for the in-plane order below TN as indicated by our bulk magnetization data.
Article
Materials Science, Multidisciplinary
I. Mohelsky, J. Wyzula, B. A. Piot, G. D. Gu, Q. Li, A. Akrap, M. Orlita
Summary: Using Landau-level spectroscopy, the temperature dependence of the energy band gap in zirconium pentatelluride (ZrTe5) is determined. It is found that the band gap reaches E-g = (5 & PLUSMN; 1) meV at low temperatures and increases monotonically with the temperature. This implies that ZrTe5 is a weak topological insulator with noninverted ordering of electronic bands in the center of the Brillouin zone. Magnetotransport experiments show that the resistivity anomaly in ZrTe5 is not connected with the temperature dependence of the band gap.
Article
Materials Science, Multidisciplinary
C. F. Schippers, M. J. Grzybowski, K. Rubi, M. E. Bal, T. J. Kools, R. A. Duine, U. Zeitler, H. J. M. Swagten
Summary: Recent demonstrations have shown the electrical switching of antiferromagnets (AFs), which has greatly impacted the field of AF spintronics. However, various nonmagnetic effects make it difficult to distinguish them from actual magnetic effects. In this study, we investigated the electrical switching of NiO films in Pt/NiO devices with magnetic fields up to 15 T to quantitatively separate these magnetic and nonmagnetic effects. Our results indicate that these magnetic fields suppress the magnetic components of NiO's electrical switching while preserving the nonmagnetic components. By using a monodomainization model, we were able to separate and analyze the contributions of these effects, revealing their behaviors with respect to current density. These findings highlight the importance of combining electrical methods and strong magnetic fields in AF spintronics research.
Article
Astronomy & Astrophysics
A. Apponi, M. G. Betti, M. Borghesi, A. Boyarsky, N. Canci, G. Cavoto, C. Chang, V Cheianov, Y. Cheipesh, W. Chung, A. G. Cocco, A. P. Colijn, N. D'Ambrosio, N. de Groot, A. Esposito, M. Faverzani, A. Ferella, E. Ferri, L. Ficcadenti, T. Frederico, S. Gariazzo, F. Gatti, C. Gentile, A. Giachero, Y. Hochberg, Y. Kahn, M. Lisanti, G. Mangano, L. E. Marcucci, C. Mariani, M. Marques, G. Menichetti, M. Messina, O. Mikulenko, E. Monticone, A. Nucciotti, D. Orlandi, F. Pandolfi, S. Parlati, C. Pepe, C. Perez de los Heros, O. Pisanti, M. Polini, A. D. Polosa, A. Puiu, I Rago, Y. Raitses, M. Rajteri, N. Rossi, K. Rozwadowska, I Rucandio, A. Ruocco, C. F. Strid, A. Tan, L. K. Teles, V Tozzini, C. G. Tully, M. Viviani, U. Zeitler, F. Zhao
Summary: We discuss the consequences of quantum uncertainty on the spectrum of electrons emitted by the beta-processes of a tritium atom bound to a graphene sheet. We propose possible avenues to mitigate the effect of quantum uncertainty.
Article
Physics, Multidisciplinary
G. Krizman, B. A. Assaf, M. Orlita, G. Bauer, G. Springholz, R. Ferreira, L. A. de Vaulchier, Y. Guldner
Summary: Topological interface states in multivalley systems are studied using magnetooptical Landau level spectroscopy in topological crystalline insulator heterostructures. The properties of these states are characterized, revealing the factors affecting them in two dimensions.
PHYSICAL REVIEW RESEARCH
(2022)
Article
Physics, Multidisciplinary
Zijin Lei, Erik Cheah, Km Rubi, Maurice E. Bal, Christoph Adam, Rudiger Schott, Uli Zeitler, Werner Wegscheider, Thomas Ihn, Klaus Ensslin
Summary: In this study, transport experiments through high-mobility gate-tunable undoped InSb quantum wells were reported. The gate-defined two-dimensional electron gases in the QWs displayed increased mobility at low density. Spin-orbit interactions were characterized using magnetotransport experiments, and signatures of Ising quantum Hall ferromagnetism were found at certain conditions.
PHYSICAL REVIEW RESEARCH
(2022)