4.0 Article

A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance

Journal

COMPTES RENDUS GEOSCIENCE
Volume 340, Issue 12, Pages 865-871

Publisher

centre Mersenne pour ldition scientifique ouverte
DOI: 10.1016/j.crte.2008.07.015

Keywords

Cation exchange capacity; Cobaltihexamine chloride; Analytical method; Soils

Ask authors/readers for more resources

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH3)(6)(3+) ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation. To cite this article: D. Aran et al., C. R. Geoscience 340 (2008). (C) 2008 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.0
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available