4.7 Article

Fabrication, process simulation and testing of a thick CFRP component using the RTM process

Journal

COMPOSITES PART B-ENGINEERING
Volume 56, Issue -, Pages 673-680

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.compositesb.2013.08.088

Keywords

Resin Transfer Moulding (RTM); Cure; Finite element analysis (FEA); Mechanical testing

Funding

  1. Regione Emilia Romagna within the funding program Dai distretti produttivi ai distretti tecnologici DGR [1631/2009]

Ask authors/readers for more resources

The present article introduces the case of a CFRP con-rod beam, and describes many aspects regarding its production with the Resin Transfer Moulding (RTM) process. The objective was to find the best process parameters of the injection and curing stages in order to manufacture the 20 mm thick CFRP part. The results are analysed in terms of the aesthetic aspect, the porosity and the mechanical properties of the final component. For the resin injection stage, results obtained from production experiences are presented, which have been performed with different set-ups, and simulations of the resin flow are used to analyse them. The results show that the resin flow during injection could be rather unpredictable, probably because of the fibre rearrangement and race tracking effects. Improvements in terms of aesthetic aspect and porosity of the part could be achieved by a process which included final compaction of the cavity by means of compressed air. Regarding the curing stage, the article presents the simulation results of a curing cycle, and it's validation through DSC analysis of specimens obtained from the finished component. Finally, results of tensile mechanical tests are provided, performed on finished components produced by RTM and compared to others produced with the method of hand lay-up of pre-impregnated plies and curing in autoclave (Prepreg + Autoclave). The results confirm that it is possible to achieve components through RTM with comparable mechanical performance to those produced with the Prepreg + Autoclave process. (C) 2013 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Proceedings Paper Polymer Science

Production of Thermoplastic Composite Filaments for Additive Manufacturing using Recycled Carbon Fibers

Niccolo Giani, Jacopo Ortolani, Laura Mazzocchetti, Tiziana Benelli, Francesco Picchioni, Loris Giorgini

Summary: This study reports the use of recycled carbon fibers to produce a thermoplastic composite filament for additive manufacturing. Filaments with 5% and 10% recycled carbon fiber loadings were produced and analyzed after optimizing the production process. The study focused on the influence of the production process on carbon fiber length and the thermal and mechanical properties of the composite materials.

MACROMOLECULAR SYMPOSIA (2022)

Proceedings Paper Polymer Science

Optimization of Pyro-gasification of Carbon Fiber Reinforced Polymers (CFRPs)

Francesco Montorsi, Gianluca Brancolini, Laura Mazzocchetti, Tiziana Benelli, Loris Giorgini

Summary: This study focuses on optimizing the pyro-gasification process of carbon fiber reinforced polymers (CFRPs) to recover carbon fibers (CFs) for the production of sustainable composites. The thickness of the composites plays a crucial role in determining suitable pyro-gasification conditions.

MACROMOLECULAR SYMPOSIA (2022)

Article Multidisciplinary Sciences

Rubber-enhanced polyamide nanofibers for a significant improvement of CFRP interlaminar fracture toughness

Emanuele Maccaferri, Matteo Dalle Donne, Laura Mazzocchetti, Tiziana Benelli, Tommaso Maria Brugo, Andrea Zucchelli, Loris Giorgini

Summary: The study found that nanofibrous mats can effectively hinder delamination in composite laminates.The combination of Nylon 66 nanofibers and Nitrile Butadiene Rubber (NBR) can produce rubber/thermoplastic membranes that hinder delamination. The performance of Nylon 66 mats electrospun from different solvent systems was compared, and it was found that mats electrospun from formic acid/chloroform performed better. The NBR coating benefits both types of nanofibers and significantly improves interlaminar fracture toughness (G(I)). The best results were achieved by interleaving medium-thickness and lightweight mats with a high loading of rubber.

SCIENTIFIC REPORTS (2022)

Article Polymer Science

Self-Sensing Soft Skin Based on Piezoelectric Nanofibers

Giacomo Selleri, Francesco Mongioi, Emanuele Maccaferri, Riccardo D'Anniballe, Laura Mazzocchetti, Raffaella Carloni, Davide Fabiani, Andrea Zucchelli, Tommaso Maria Brugo

Summary: The development of electronic skins and wearable devices is rapidly growing due to their broad application fields. Tactile sensors based on piezoelectric polymers, such as PVDF-TrFE nanofibers, are widely used for their self-powering capability, flexibility, and light weight. In this work, a flexible sensor was manufactured using PVDF-TrFE nanofibers with enhanced piezoelectric properties, and carbon black-based electrodes were used to collect the piezoelectric signal. The sensor showed a sensitivity of up to 4 mV/N in a frequency range consistent with human activities, and its proposed electrical model was validated by experimental results.

POLYMERS (2023)

Article Polymer Science

Is Graphene Always Effective in Reinforcing Composites? The Case of Highly Graphene-Modified Thermoplastic Nanofibers and Their Unfortunate Application in CFRP Laminates

Emanuele Maccaferri, Laura Mazzocchetti, Tiziana Benelli, Jacopo Ortolani, Tommaso Maria Brugo, Andrea Zucchelli, Loris Giorgini

Summary: Graphene can effectively enhance the properties of polymers and polymer composites. In this study, the effect of different nanofibers (polyether, polyester, and polyamide) and graphene addition on the mechanical properties of epoxy-matrix carbon fiber reinforced polymers (CFRPs) was evaluated. The results showed that polycaprolactone and poly(ethylene oxide) improved the properties of CFRPs through matrix toughening, while Nylon 66 enhanced the properties through nanofiber bridging. However, graphene did not provide a positive contribution in this context.

POLYMERS (2022)

Article Materials Science, Multidisciplinary

Influence on Fatigue Strength of Post-Process Treatments on Thin-Walled AlSi10Mg Structures Made by Additive Manufacturing

Nicola Spignoli, Giangiacomo Minak

Summary: This study aims to investigate the fatigue behavior of thin-walled structures and the potential impact of post-process treatments. Specimens with novel geometry were produced using selective laser melting (SLM) technology and subjected to different treatments. The results showed that mechanical treatments and T6 quenching significantly improved the fatigue strength. Microscopic observations and measurement of density and porosity were performed. The study concluded that the thickness did not affect fatigue life in the cases studied.

METALS (2023)

Article Mechanics

Improving the crashworthiness of CFRP structures by rubbery nanofibrous interlayers

Maria Pia Falaschetti, Francesco Rondina, Emanuele Maccaferri, Laura Mazzocchetti, Lorenzo Donati, Andrea Zucchelli, Loris Giorgini

Summary: This study investigates the integration of rubbery nanofibers into composite laminates to improve crash performance. The results show that the nanofibers significantly increase the fracture toughness of the laminates and improve the energy absorption capacity by 8.2%.

COMPOSITE STRUCTURES (2023)

Article Chemistry, Applied

Phosphorylated poly(vinyl alcohol) surface coatings as intumescent flame inhibitor for polymer matrix composites

Stefano Scurti, Jacopo Ortolani, Alberto Ghirri, Emanuele Maccaferri, Daniele Caretti, Laura Mazzocchetti

Summary: Phosphorylated poly(vinyl alcohol) (PPVA) is synthesized and used as an intumescent flame inhibitor coating for carbon fiber reinforced polymer (CFRP) laminates. The PPVAs exhibit excellent fire resistance properties, reducing the flame time by up to 58%. In contrast, poly(vinyl alcohol) coatings worsen the overall fire behavior of the material, highlighting the crucial role of phosphorous in reducing flammability.

PROGRESS IN ORGANIC COATINGS (2023)

Article Biochemistry & Molecular Biology

Water-Resistant Photo-Crosslinked PEO/PEGDA Electrospun Nanofibers for Application in Catalysis

Emanuele Maccaferri, Andrea Canciani, Laura Mazzocchetti, Tiziana Benelli, Loris Giorgini, Stefania Albonetti

Summary: Polymeric catalytic membranes made of PEO/PEGDA blends with Au/Pd catalyst were proposed for water phase and low-temperature reactions. The resulting nanofibrous mat, optimized in terms of blend solution, electrospinning process, and UV irradiation time, maintained its structure in water. The addition of Au-6/Pd-1 catalyst supported on TiO2 enabled the production of a catalytic nanofibrous membrane, which demonstrated potential usage in catalysis through the reduction of 4-NP to 4-AP.

MEMBRANES (2023)

Article Biochemistry & Molecular Biology

Valorization Strategies in CO2 Capture: A New Life for Exhausted Silica-Polyethylenimine

Irene Coralli, Demetra Giuri, Lorenzo Spada, Jacopo Ortolani, Laura Mazzocchetti, Claudia Tomasini, Lee A. Stevens, Colin E. Snape, Daniele Fabbri

Summary: The study investigates the use of three silica-polyethylenimine materials for CO2 adsorption in carbon capture and storage. The researchers found that solvent extraction and pyrolysis can recover and utilize these materials, obtaining valuable chemicals in the process.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2023)

Article Chemistry, Multidisciplinary

Novel Strategies for Recycling Poly(butylene adipate-co-terephthalate)-Starch-Based Plastics: Selective Solubilization and Depolymerization-Repolymerization Processes

Adriano Parodi, Vincenzo Arpaia, Chiara Samori, Laura Mazzocchetti, Paola Galletti

Summary: This study characterized the main components of starch-based plastics and investigated three recycling strategies. The results showed that all three methods were effective in recovering the components of starch-based plastics. Extensive characterization of the recovered PBAT demonstrated the efficiency of the processes. The environmental sustainability of the proposed approaches was preliminarily evaluated through the calculation of their environmental factor.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023)

Review Engineering, Marine

Solar Energy-Powered Boats: State of the Art and Perspectives

Giangiacomo Minak

Summary: This paper examines the primary applications and recent developments of solar energy as the main power source in the maritime sector. A comprehensive review of literature identifies three prominent areas for advancing solar energy-powered boats: maritime drones, sporting boats, and short-range touristic vessels. The paper explores specific cases and discusses potential future perspectives.

JOURNAL OF MARINE SCIENCE AND ENGINEERING (2023)

Article Ecology

A New Perspective on Hydrogen Chloride Scavenging at High Temperatures for Reducing the Smoke Acidity of PVC Cables in Fires, IV: The Impact of Acid Scavengers at High Temperatures on Flame Retardance and Smoke Emission

Iacopo Bassi, Francesca Delchiaro, Claudia Bandinelli, Laura Mazzocchetti, Elisabetta Salatelli, Gianluca Sarti

Summary: In PVC compounds, hydrogen chloride plays a fundamental role in flame retarding and promoting cross-linking. Low-smoke acidity PVC compounds have been developed to reduce HCl emission and smoke. However, acid scavengers in these compounds can neutralize the action of flame retardants and make PVC items prone to ignite.

FIRE-SWITZERLAND (2023)

Article Engineering, Multidisciplinary

The relationship between the impact position interference and CAI strength of composite sandwich structures under double impacts

Keyu Zhu, Xitao Zheng, Jing Peng, Jiaming Sun, Ruilin Huang, Leilei Yan

Summary: This paper discusses the influence of multiple impacts on the compression strength of honeycomb sandwich structures with composite face sheets. It is found that the size of the impactor affects the turning point of the compression strength. Additionally, high impact energy leads to damage in the bottom face sheet and reduces the overall compression strength.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Effect of carbonation on the corrosion behavior of steel rebar embedded in magnesium phosphate cement

Danqian Wang, Yanfei Yue, Jueshi Qian

Summary: Magnesium Potassium Phosphate Cement (MKPC) as a binder for steel rebars shows improved corrosion resistance when subjected to carbonation, due to the increase in pH and the formation of a more protective oxide film.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Mechanical properties and failure mechanisms of all-CFRP corrugated sandwich truncated cone

Zhibin Li, Wenyu Wang, Pengcheng Xue, Xingyu Wei, Jian Xiong

Summary: This work proposes a design approach and manufacturing method for carbon fiber reinforced plastic (CFRP) corrugated sandwich truncated cones (CSTC) to improve their anti-debonding ability and ensure reliability. The study establishes theoretical models for CSTCs' stiffness and failure modes, which are verified through experiments and finite element analysis (FEA). The research reveals the effect of geometric parameters on failure modes and performs an optimal design for CSTC structures. The findings have significant implications for the design and application of lightweight CSTCs in constructions, such as launch vehicle adapters.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Asymmetric wettability fibrous membranes: Preparation and biologic applications

Mingyu Zhang, Lei Chu, Jiahua Chen, Fuxun Qi, Xiaoyan Li, Xinliang Chen, Deng-Guang Yu

Summary: This review summarizes the different structures and construction methods of fibrous membranes with asymmetric wettability. It also reviews the biological applications of these membranes and suggests future challenges.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Effect of fibre concentration on the mechanical properties of welded reinforced polypropylene

E. Mofakhami, L. Gervat, B. Fayolle, G. Miquelard-Garnier, C. Ovalle, L. Laiarinandrasana

Summary: This study investigates the effects of fibre concentration on the mechanical response of welded glass-fibre-reinforced polypropylene (GF-PP). Experimental observations reveal a significant reduction in weld ratio, up to 60%, indicating a decreased strength compared to the bulk material. Increasing fibre content in the welded material results in a decrease in stress at break and strain at the maximum stress. The use of DIC technique and X-ray microtomography further confirms the localized strain amplification in the welded zone due to the significant increase in fibre density.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Interlaminar shear strength of Carbon/PEEK thermoplastic composite laminate: Effects of in-situ consolidation by automated fiber placement and autoclave re-consolidation

Emad Pourahmadi, Farjad Shadmehri, Rajamohan Ganesan

Summary: This research compares the mechanical properties of laminates manufactured using automated fiber placement and conventional autoclave curing methods. The results show that laminates manufactured using automated fiber placement have a lower interlaminar shear strength compared to laminates reconsolidated using autoclave curing. A finite element simulation method is proposed to quantitatively analyze these differences.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Bolted joint method for composite materials using a novel fiber/metal patch as hole reinforcement-Improving both static and fatigue properties

Johnny Jakobsen, Benny Endelt, Fahimeh Shakibapour

Summary: This study proposes a new bolted/pinned joining method for composite applications, which improves load transfer by introducing a patch-type reinforcement. Experimental results demonstrate significant improvements in both static and fatigue load conditions compared to existing methods. Finite element simulations highlight the advantage of this method, as it creates a more efficient load-transferring mechanism through different stress distributions.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Novel multi-crack damage approach for pultruded fiber-polymer web-flange junctions

Gisele G. Cintra, Janine D. Vieira, Daniel C. T. Cardoso, Thomas Keller

Summary: This paper proposes a novel approach to assess multi-crack behavior in layered fiber-polymer composites. The generated Compliance and R-curves provide useful insights into understanding the multiple delamination process and allow for separate evaluation of strain energy release rate (SERR) for each crack. The developed cohesive zone model successfully simulates the failure process zone of three parallel cracks, showing good agreement between the numerical model and experimental results.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Uncovering the hidden structure: A study on the feasibility of induction thermography for fiber orientation analysis in CFRP composites using 2D-FFT

Renil Thomas Kidangan, Sreedhar Unnikrishnakurup, C. Krishnamurthy, Krishnan Balasubramaniam

Summary: The induction heating process can accurately identify fiber orientation and stacking order, making it a valuable tool for large-area inspection and quality control in manufacturing fiber-reinforced composites.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Morphological characteristics of spray dried cellulose nanofibers produced using various wood pulp feedstocks and their effects on polypropylene composite properties

Sungjun Hwang, Yousoo Han, Douglas J. Gardner

Summary: Bleached Kraft pulp, unbleached Kraft pulp, and old corrugated cardboard pulp are suitable for producing cellulose nanofibril suspensions. Spray drying is a fast, simple, cost-effective, and scalable drying method. Spray-dried cellulose nanofibrils can be used as reinforcing materials in polypropylene matrices. The particle size of cellulose nanofibrils affects the material properties.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Four-dimensional printing of continuous glass fiber-reinforced thermoplastics

Mehdi Mahdavi, Abbas Zolfaghari

Summary: This study aims to improve the recovery forces of shape memory polymers (SMPs) through material extrusion additive manufacturing. By using glass fiber (GF) as reinforcement and manufacturing multi-layer composite specimens, it was found that PLA with 6.62% GF exhibited the best recovery force, which was further optimized through annealing heat treatment.

COMPOSITES PART B-ENGINEERING (2024)

Review Engineering, Multidisciplinary

Flame retardancy and fire mechanical properties for natural fiber/polymer composite: A review

Xiang Ao, Antonio Vazquez-Lopez, Davide Mocerino, Carlos Gonzalez, De-Yi Wang

Summary: The vulnerability of natural fibers to heat and fire poses a significant challenge for their substitution of traditional fiber reinforcements in composite materials. Natural fiber/polymer composites (NFCs) are regarded as potential candidates for engineering applications due to their environmental friendliness and low-impact sourcing. Thus, appropriate approaches need to be implemented to enhance the fire safety of NFCs. This review summarizes and discusses the latest understanding of flammability and thermal properties of natural fibers, with a special focus on their interaction with polymer matrix in fire behavior. Additionally, the latest developments in flame-retardant approaches for NFCs are reviewed, covering both flame retardancy and fire structural integrity. Finally, future prospects and perspectives on fire safety of NFCs are proposed, providing insights into further advancements of NFCs.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Construction of an epoxidized, phosphorus-based poly(styrene butadiene styrene) and its application in high-performance epoxy resin

Cheng Wang, Siqi Huo, Guofeng Ye, Bingtao Wang, Zhenghong Guo, Qi Zhang, Pingan Song, Hao Wang, Zhitian Liu

Summary: The demand for multifunctional, transparent epoxy resin with superior dielectric, mechanical, and fire-safety performances is increasing in modern industries. Researchers have developed an epoxidized, phosphaphenanthrene-containing poly(styrene butadiene styrene) (ESD) for advanced fire-safe epoxy resin, which maintains high transparency and improves UV-blocking property. The addition of 10 wt% ESD results in improved mechanical properties, decreased dielectric constant and loss, and outperformance compared to other fire-safe epoxy resins. This research provides an effective method for developing multifunctional flame-retardant epoxy resin.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Inner superhydrophobic materials based on waste fly ash: Microstructural morphology of microetching effects

Bo Pang, Heping Zheng, Zuquan Jin, Dongshuai Hou, Yunsheng Zhang, Xiaoyun Song, Yanan Sun, Zhiyong Liu, Wei She, Lin Yang, Mengyuan Li

Summary: This study develops an internal superhydrophobic material (ISM) using waste denitrification fly ash, which maintains stable hydrophobicity under harsh conditions of use and does not rely on expensive fluor-based surface modifications. The synthesized ISM has excellent matrix strength, strong waterproof properties, and retains superhydrophobicity even at damaged or friction interfaces.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Directional eddy current probe configuration for in-line detection of out-of-plane wrinkles

Meirbek Mussatayev, Qiuji Yi, Mark Fitzgerald, Vincent K. Maes, Paul Wilcox, Robert Hughes

Summary: Real-time monitoring of carbon fibre composites during Automated Fibre Placement (AFP) manufacturing remains a challenge for non-destructive evaluation (NDE) techniques. This study designed a directional eddy-current (EC) probe to evaluate the detectability of out-of-plane wrinkles. Experimental evaluations and finite element modeling were conducted to better understand the relationship between eddy-current density and defect detection. The findings suggest that the probe configuration with an asymmetric driver coil and differential pickup coils shows the best capability for wrinkle detection.

COMPOSITES PART B-ENGINEERING (2024)