4.7 Article

Crystalline morphology and properties of multi-walled carbon nanotube filled isotactic polypropylene nanocomposites: Influence of filler size and loading

Journal

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2013.05.011

Keywords

Polymer-matrix composites (PMCs); Nano-structures; Mechanical properties; Surface properties; Compression moulding

Funding

  1. Bangladesh University of Engineering and Technology (BUET)

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Isotactic polypropylene (PP) nanocomposites with multi-walled carbon nanotubes (MWCNTs) of various diameters (10-50 nm) were fabricated by extrusion and compression-molding techniques and characterized by X-ray diffraction measurements, differential scanning calorimetry, scanning electron microscopy, mechanical test and differential thermal analyses. The pure PP exhibits both the a- and b-axes oriented alpha-crystal, whereas the MWCNTs induce the b-axis orientation of the alpha-crystal along with the formation of minor gamma-phase crystal in nanocomposites. Crystallinity, long period of lamellae, tensile strength, tensile modulus (TM) and microhardness (H) of PP considerably change by different loading and sizes of MWCNTs. The estimated values H/TM= 0.09-0.10 for all samples approach the predicted value of 0.10 for polymers. The increase in crystallinity has been demonstrated by both XRD and DSC studies. Mathematical models have been invoked to explain the changes in mechanical properties. An increase in thermal stability of polymer matrix occurs with increasing MWCNTs size and loading. (C) 2013 Elsevier Ltd. All rights reserved.

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