4.6 Article

Effect of dosage strategy on Al-humic flocs growth and re-growth

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.colsurfa.2012.04.033

Keywords

Flocs breakage; Re-growth; One time dosage; Continuous dosage; Surface activity

Funding

  1. National Natural Science Foundation of China [51108444, 51138008]
  2. Creative Research Groups of China [50921064]
  3. National High-Tech Research and Development Program (863) of China [2009AA06Z303]

Ask authors/readers for more resources

The ability of flocs growth has a significant effect on the efficiency of solid/liquid separation during coagulation process. The growth and re-growth of flocs by one time or continuous dosage were explored at neutral pH, including one time and continuous additional dosage strategy after flocs breakage. The size of flocs formed by continuous dosage before breakage was much larger than the one formed by one time dosage. There was significant irreversibility of floc breakage when no additional coagulant was added. For the one with one time initial dosage strategy, the size of re-grown flocs by one time additional dosage was nearly the same as that before breakage. The re-grown flocs formed by continuous additional dosage were a little smaller than that formed by one time additional dosage. It definitely showed that the growth or connection of flocs was probably not determined by the flocs size distribution and fractal dimension, but by the surface activity of flocs. Additional dosage could improve flocs re-grown ability because the surface activity of broken flocs was repaired by adding new alum. (C) 2012 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Environmental

Insights into the properties of surface waters and their associated nanofiltration membrane fouling: The importance of biopolymers and high molecular weight humics

Long Tian, Peng Zhou, Zhaoyang Su, Ting Liu, Nigel Graham, Tom Bond, Wenzheng Yu

Summary: This study investigated the impact of water quality parameters on nanofiltration membrane fouling and found that hydrophobic NOM, biopolymer content, and high molecular weight components play important roles in NF membrane fouling.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Environmental Sciences

Engineering of 3D graphene hydrogel-supported MnO2-FeOOH nanoparticles with synergistic effect of oxidation and adsorption toward highly efficient removal of arsenic

Kai Zhang, Fengchen Guo, Nigel Graham, Wenzheng Yu

Summary: In this study, an active Fe(III) oxyhydroxide-Mn(IV) oxide/3D graphene oxide (GO) gel composite was successfully fabricated through a simple hydrothermal reaction. The optimized Fe-Mn/GO composites showed superior performance with removal efficiencies of over 90% for As(III) at pH 7.0 and close to 97% for As(V) at pH 5.0. After stable and continuous operation for 20 days, the effluent concentration of arsenic could be reduced to below 10 μg/l. This research is of great significance for addressing the challenges of nanoparticle aggregation, metal leaching, and insufficient removal efficiency in practical applications.

ENVIRONMENTAL POLLUTION (2023)

Article Green & Sustainable Science & Technology

Ultra-low concentrations of detection for fluoride and trivalent chromium ions by multiple biomimetic nanochannels in a PET membrane

Jinqiang Wang, Nigel Graham, Kai Sun, Liping Wen, Wenzheng Yu

Summary: The development of a PET membrane with multiple biomimetic nanochannels for the detection of fluoride and chromium (III) ions is described. The membrane was created using an asymmetric chemical etching technique and was modified with specific recognition compounds for F- and Cr3+. The method showed excellent linear relationships between current values and ion concentrations, with low detection limits of 4.10 nM for Cr3+ and 0.46 nM for F-. The accuracy and reliability of the method were compared to conventional ICP-MS analysis and showed good agreement, demonstrating its potential application for detecting a wide range of ionic contaminants.

JOURNAL OF CLEANER PRODUCTION (2023)

Article Engineering, Environmental

Efficient electrochemical generation of active chlorine to mediate urea and ammonia oxidation in a hierarchically porous-Ru/RuO2-based flow reactor

Kai Zhang, Yuanxiao Duan, Nigel Graham, Wenzheng Yu

Summary: The electrochemical chlorination of urea to CO2 and N-2 end-products, via active-chlorine-mediated oxidation under nearly neutral conditions, is an effective treatment for medium-concentrated urea-containing wastewater. A novel flow reactor integrated with three-dimensional hierarchically porous Ru/RuO2 architectures anchored on a Ti mesh was designed. The hierarchically macroporous electrode can create sufficient exposure of catalytically active sites and facilitate the microscopic mass transport and diffusion inside the active layer, thereby contributing to the increased removal efficiency of urea-N and ammonia-N.

JOURNAL OF HAZARDOUS MATERIALS (2023)

Article Engineering, Environmental

Bubbleless Air Shapes Biofilms and Facilitates Natural Organic Matter Transformation in Biological Activated Carbon

Mengjie Liu, Nigel J. D. Graham, Lei Xu, Kai Zhang, Wenzheng Yu

Summary: A bubbleless aerated BAC process was developed by installing a hollow fiber membrane module within a BAC filter, which improved the dissolved oxygen concentrations and enhanced the biodegradation and metabolism capacity. The ABAC system showed a higher electron transfer capacity and lower extracellular polymeric substances secretion, resulting in enhanced contaminant degradation efficiency and long-term stability. This proposed ABAC filter provides a practical example of how to shape and activate microbial community in BAC technology.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Article Engineering, Chemical

Fenton induced microdefects enable fast water transfer of graphene oxide membrane for efficient water purification

Long Tian, Nigel J. D. Graham, Xiangyu Tian, Ting Liu, Wenzheng Yu

Summary: Recent studies have found that graphene oxide (GO) has great potential as advanced separation membranes for water-related environmental applications. However, GO membranes often have low water permeability and stability issues. This study developed a novel approach involving intra-defect construction and cation cross-linking to prepare highly permeable and stable GO membranes for water purification. The membrane showed excellent water flux and selectivity, as well as long-term stability and pressure-resistance.

JOURNAL OF MEMBRANE SCIENCE (2023)

Article Engineering, Chemical

Impacts of water hardness on coagulation-UF-NF process using aluminum salts

Junling Wang, Qingguang Liu, Lei Xu, Muhammad Saboor Siddique, Wenzheng Yu

Summary: Surface water supplemented with reclaimed water can effectively alleviate water shortage. An integrated CUF-NF process was used to treat reclaimed water, and the effects of water hardness and different aluminum salts on the process were studied. Results showed that water hardness had a significant impact on the CUF-NF process, affecting membrane flux, organic matter removal, and disinfection by-product formation potential. This study provides insights into the impacts of water hardness and aluminum salts on CUF-NF processes treating surface water and contributes to the formulation of hardness standards for reclaimed water.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Nanoscience & Nanotechnology

Engineering Morphology and Electron Redistribution of a Ni/WO3 Mott-Schottky Bifunctional Electrocatalyst for Efficient Alkaline Urea Splitting

Kai Zhang, Fengchen Guo, Nigel Graham, Wenzheng Yu

Summary: Constructing desired morphology and nanointerface is an effective approach to enhance urea splitting for hydrogen generation. In this study, a nickel/tungsten oxide Mott-Schottky heterojunction electrocatalyst with a hedgehog-like structure was fabricated for alkaline urea splitting. The Mott-Schottky nanointerfaces between nickel and tungsten oxide domains were observed, which accelerated charge transfer rate. The optimal electrode exhibited outstanding catalytic activity and reduced cell voltage when coupled with urea oxidation reaction.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Engineering, Environmental

Hydrolyzed polyacrylonitrile UF-membrane for surface and TAP water treatment: Influence on DBPs formation and removal

Muhammad Saboor Siddique, Qingyun Song, Xuejun Xiong, Hasan Fareed, Nigel Graham, Wenzheng Yu

Summary: The integration of pre-treatment methods with low pressure-driven ultrafiltration has been proven effective in reducing disinfection by-products in drinking water. In this study, a low dose peroxone assisted alkaline hydrolyzed polyacrylonitrile UF-membrane system was explored for its efficiency in removing dissolved organic matter and regulated DBPs. The HPAN membrane displayed high flux recovery and comparable removal efficiency to the NF-3 membrane. Additionally, the H2O2/O3-HPAN system significantly reduced the aromatic and fluorescent content of the DOM and removed a high percentage of THMs, HAAs, and DBPs formation.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Environmental

Double positively charged polyamide nanofiltration membrane with PEI/Zr4+ for Cr3+ and trimethoprim removal

Jinqiang Wang, Zhaoyang Su, Nigel J. D. Graham, Hongkai Liu, Kai Sun, Wenzheng Yu

Summary: This paper focuses on the functionalization of double positively charged polyethylenimine (PEI)/Zr4+-polyamide (PA) nanofiltration (NF) membrane. The study evaluates the properties and performance of prepared PEI/Zr4+-PA NF membrane in removing aquatic contaminants and its antifouling ability. Results show that loading Zr4+ improves the hydrophilicity and removal behavior of the membrane when exposed to high concentrations of contaminants. The effectiveness of the membrane is not affected by factors such as high filtering degree and filtration cycle, and antifouling ability can be further improved by continuously loading Zr4+.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Environmental

An overlooked crystallization effect during the O3 participated coagulation improves the performance of dual-membrane process

Lei Xu, Shian Song, Nigel J. D. Graham, Wenzheng Yu

Summary: This study investigates the interaction between O3 and amorphous alum flocs formed during flocculation at neutral pH using a conventional coagulant (alum). It was found that O3 promotes the transition of the in-situ formed alum flocs from tetrahedral Al to octahedral Al structures, facilitating the crystallization process. The involvement of surface functional groups of amorphous Al flocs in O3 catalytic oxidation enhances the performance of the subsequent dual-membrane filtration process in terms of fouling alleviation and effluent quality improvement.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Chemical

Long-term operation and biofouling of graphene oxide membrane in practical water treatment: Insights from performance and biofilm characteristics

Long Tian, Peng Zhou, Nigel Graham, Guibai Li, Wenzheng Yu

Summary: The long-term performance of graphene oxide (GO) membranes in practical water treatment conditions was investigated. Two representative GO membranes (V-GO and P-GO) with different surface properties were evaluated for their filtration performance and biofilm characteristics. The results showed that both membranes achieved sustainable water purification, with V-GO forming a highly heterogeneous and porous biofilm and P-GO forming a thin but dense structure. The microbial community analysis revealed different bacteria compositions in the biofilms of the two membranes. The findings highlight the importance of considering membrane surface properties in designing membrane systems for long-term water treatment.

JOURNAL OF MEMBRANE SCIENCE (2023)

Article Engineering, Chemical

The impact of small organic molecules on Fe(II) coagulation: Facilitating vs. shielding mechanisms on charge transfer

Bingqian Yang, Sajid Rashid, Nigel Graham, Wenzheng Yu

Summary: This study investigates the impact of small organic molecules (SOM) on Fe(II) coagulation and reveals that they can significantly change the coagulation behavior by forming particles with distinct nanostructures. The study also demonstrates that SOM can directly influence the structure of flocs by controlling the oxidation rate of Fe(II) and indirectly interfere with the charge transfer between flocs and free Fe(II).

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Engineering, Environmental

Bubbleless aerated-biological activated carbon as a superior process for drinking water treatment in rural areas

Mengjie Liu, Nigel Graham, Lei Xu, Kai Zhang, Wenzheng Yu

Summary: Drinking water supply in rural areas is a challenging issue, and low-cost, efficient water treatment processes are needed to provide safe and affordable drinking water. This study proposes and evaluates a bubbleless aeration BAC (ABAC) process with a hollow fiber membrane (HFM) assembly, which improves dissolved oxygen (DO) throughout the filter and enhances DOM removal efficiency. Results show that ABAC significantly increases DOC removal and decreases disinfection byproduct formation compared to a comparable filter without aeration. The proposed ABAC treatment, with its various advantages, is well-suited for decentralized drinking water systems in rural areas.

WATER RESEARCH (2023)

Article Engineering, Environmental

Floc aging: Crystallization and improving low molecular weight organic removal in re-coagulation

Qingyun Song, Bingqian Yang, Mengjie Liu, Shian Song, Nigel Graham, Wenzheng Yu

Summary: It was found that aging resulted in increasing crystallization of the flocs, which can play a beneficial role in activating persulfate oxidant to remove the representative organics. Furthermore, acidification was also found to further improve the removal of low MW natural organics and tetracycline. These results show that aged flocs have a high potential of reuse for re-coagulation and activation of oxidants to enhance drinking water quality.

WATER RESEARCH (2023)

Article Chemistry, Physical

BiOCl as the role of cleaner for the fabrication of self-cleaning PES membranes based on the RTIPS method

Wenjing Tan, Chunmei Gao, Shifeng Ji, Yunqing Xing, Yi Guo, Baogui Liang

Summary: Membrane separation technology is widely used in wastewater treatment due to its cost-effectiveness and productivity. However, organic membrane fouling caused by humic acid is a major barrier to its further development. This study successfully addressed this issue through the production of composite materials and self-cleaning membranes, providing beneficial strategies and solutions for membrane contamination problems.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Low-temperature plasma-induced porous Sb2WO6 microspheres with rich oxygen vacancies to promote high-performance photocatalytic activity

Qichang Peng, Qingdong Ruan, Bin Wang, Jinyuan Liu, Chao Huang, Xingwang Zhu, Dan Li, Liangliang Liu, Yinchuan Wang, Xiaolin Zhang, Jia Yan, Paul K. Chu, Hui Xu

Summary: The escalating issue of water pollution has led to significant attention in the field of photocatalysis. In this study, OV-Sb2WO6-X photocatalyst with oxygen vacancies was synthesized, which exhibited enhanced charge separation efficiency and improved photocatalytic activity. The introduction of oxygen vacancies was successfully controlled and characterized, and the modified photocatalyst showed superior degradation efficiency for dye wastewater treatment.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Preparation and application of self-emulsifying curing agent for CO2 high-pressure corrosion-resistant resin cement

Wangcheng Zhang, Cunchuan Zheng, Hu Xie, Weichao Du

Summary: By using a specific curing agent ETB, the problem of dispersion and stability for oily epoxy resin in cement slurry system has been successfully solved. The application of the emulsified curing agent ETB in oilfield cement slurry system shows good rheological performance, resistance to high temperature and high pressure water loss, and corrosion resistance.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

New approaches for regulation of structure and adsorption properties of biochar based on freshwater sediments (sapropels)

O. I. Krivonos, A. Babenko, O. B. Belskaya

Summary: This study synthesized biochar based on sapropel and investigated the effects of chemical modification on its textural characteristics, acid-base properties, and adsorption properties. The results showed that the chemical modification increased the fraction of micropores, specific surface area, and changed the surface properties of biochar. The experiment also revealed that biochar pretreated with alkali exhibited the maximum adsorption capacity for copper ions. A conceptual model identifying the mechanisms of copper adsorption on sapropel-based biosorbent was proposed.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Detailed experimental performance of two new pyrimidine-pyrazole derivatives as corrosion inhibitors for mild steel in HCl media combined with DFT/MDs simulations of bond breaking upon adsorption

H. Lachhab, N. Benzbiria, A. Titi, S. Echihi, M. E. Belghiti, Y. Karzazi, A. Zarrouk, R. Touzani, C. Jama, F. Bentiss

Summary: The corrosion inhibitory potency of two new pyrimidine-pyrazole derivatives, PPA and PPC, was evaluated for mild steel in 1 M HCl. The results showed enhanced inhibition activities with increased concentration, reaching maximal values of 91.15% and 92.39% for PPA and PPC, respectively. However, the mitigation potency decreased with increasing temperature. SEM and XPS analysis revealed that PPA and PPC adsorbed on the mild steel surface, forming a shielding layer that prevented the dissolution of the steel in the acidic solution.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Encapsulation of essential oil to prepare environment friendly nanobio-fungicide against Fusarium oxysporum f.sp. lycopersici: An experimental and molecular dynamics approach

Shanmugapriya Sivalingam, D. Jeya Sundara Sharmila, Goutham Golla, Lakshmanan Arunachalam, Tarunendu Singh, G. Karthikeyan, A. Shanthi, Kannan Malaichamy

Summary: This study aims to develop a nano-biofungicide comprising of volatile essential oil molecules to enhance its efficacy in the field of agriculture through easily scalable green synthesis technique. The nano biofungicide was prepared through one pot hot melt ultrasonication technique with easy water dispersibility and long term stability. The physico-chemical analysis revealed that, nano bio-fungicides were amorphous sphere-shaped nanoparticles with low melting point. The encapsulation efficiency of major components of essential oil was determined, and it was found that they followed Higuchi model of release kinetics. The essential oil loaded nanostructured lipid carrier showed significantly higher mycelial growth inhibition compared to pure essential oil, indicating enhanced bio-efficacy.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Waterborne epoxy composite coating with long-term corrosion resistance through synergy of MXene nanosheets and ZnO quantum dots

Yinlong Li, Yingqing Zhan, Yiwen Chen, Hongshan Jia, Ximin Chen, Fei Zhu, Xulin Yang

Summary: In this study, ZnO quantum dots decorated MXene nanosheets were used as a functional filler for waterborne epoxy coating. The improved dispersion and synergy of ZnO QDs and MXene nanosheets enhanced the anticorrosion performance of the coating.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Alginate-based aerogel fibers with a sheath-core structure for highly efficient methylene blue adsorption via directed freezing wet-spinning

Fucheng Guan, Jing Tao, Qiang Yao, Zheng Li, Yihang Zhang, Shi Feng, Jianbin Sun, Qiang Yang, Xuecui Song, Jing Guo, Yuanfa Liu

Summary: This paper presents a method for preparing adsorbent materials based on biomass that can efficiently adsorb methylene blue. The experimental results show that the material has a hierarchical structure, high adsorption capacity, and reusability.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

In-situ study on the heterocoagulation between fine coal particles and coarse glass beads by the particle vision and measurement (PVM) techniques

Pengfei Hu, Zuli Mo, Weiliang Wang, Chengzhe Li, Zhaojia Guo, Guanqing Lin, Zhimin Guo

Summary: This study developed a novel in-situ particle vision and measurement (PVM) system to investigate heterocoagulation between coarse and fine particles in mineral processing. The experimental results showed that the degree of heterocoagulation decreased with increasing pH and stirring speed. Furthermore, under certain hydrodynamic conditions, coal particles were more distributed at the rear of the glass bead.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Label-free immunosensor for detection of hepatitis C (HCV) core antigen using ternary polypyrrole-Ag doped ZnO-exfoliated graphene nanocomposite

Tanveer ul Haq Zia, Anwar ul Haq Ali Shah, Behisht Ara, Kashif Gul

Summary: A label-free immunosensor for detection of hepatitis C core antigen was fabricated using a ternary nanocomposite based on polypyrrole, silver doped zinc oxide, and exfoliated graphene. The immunosensor demonstrated low detection limit, high selectivity, and stability.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Zwitterionic polymers as high-performance coatings for hemoperfusion adsorbents and their chemisorption of protein-bound toxins through computational simulations

Xiaoyan Feng, Jiachen Li, Lijun Liang, Linli Zhu, Sa Liu, Li Ren

Summary: In this study, polystyrene divinylbenzene microspheres were surface-modified by poly(carboxybetaine methacrylate) to develop an efficient hemoperfusion adsorbent for the removal of protein-bound toxins. The modified microspheres showed increased adsorption capacity and better biocompatibility, making them promising for clinical hemoperfusion therapy.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

A flexible high-efficiency approach to preparing a durable flame-retardant cellulosic fabric as well as the research of the property

Xiaoye Bi, Dong Xue, Yunpeng Wang, Chencheng Lv, Zexiong Li, Tao Zhao

Summary: This research aimed to develop a durable and formaldehyde-free flame retardant treatment for cotton fabrics. The results demonstrated successful grafting of phosphorous acid (PA) onto cotton fabrics, leading to enhanced flame resistance while maintaining the desired fabric characteristics.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Inhibiting mechanisms and applications of novel Al-starch for ultrafine gangue minerals based on experimental and computational study

Ruolin Wang, Wenjuan Sun, Haisheng Han, Dongping Tao

Summary: This study finds that Al-starch colloidal depressants can effectively inhibit the flotation of ultrafine calcite and chlorite, and increase the grade of valuable minerals. The chemisorption of Al-starch on mineral surface changes the functional group peaks and generates new O-Al functional groups.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Tuneable functionalized biochar for simultaneous removal of pharmaceuticals from binary mixture

Wondimu K. Wakejo, Ali Maged, Beteley T. Meshesha, Joon W. Kang, Abayneh G. Demesa, Sandip Chakrabarti, Thallada Bhaskar, Ashok Kumar Gupta, Amit Bhatnagar

Summary: Simultaneously removing different pharmaceutical pollutants from wastewater is an important environmental issue, and the use of a system that can remove multiple contaminants at once is necessary. Functionalized biochar (FBC) has been found to be effective in simultaneously removing acetaminophen and ciprofloxacin and other pharmaceutical pollutants.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Full utilization of Cu single atoms on carbon nitride nanofibers for enhanced Fenton-like degradation of methylene blue

Yu Wang, Fengwen Yan, Jie Wu, Zhijun Huang, Liuting Song, Shunda Yuan

Summary: In this study, Cu single atoms are anchored on the external surface of g-C3N4 nanofibers to maximize atom utilization. This catalyst exhibits excellent Fenton-like catalytic activity and good stability due to the full utilization of Cu active sites.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)