Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 2, Pages 514-518Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201507083
Keywords
semiconductors; inorganic-organic hybrid composites; lead; nanotube arrays; wheel clusters
Categories
Funding
- NSF of China [51402293, 21401193, 21471149, 91222204]
- NSF of Fujian Province [2014J01065, 2014J05025]
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Crystalline nanotube array would create great opportunity for novel electrical application. Herein we report the first example of a metal halide based crystalline nanotube array which is constructed from an unprecedented giant [(Pb18I54)-I-II(I-2)(9)] wheel cluster, as determined by synchrotron X-ray diffraction. The electrical properties of the single crystal were studied and the present compound shows typical semi-conductivity and highly anisotropic conductivity.
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