Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 27, Pages 7862-7866Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201502256
Keywords
allenes; gold; homogeneous catalysis; indolines; rearrangement
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Funding
- MEXT (Japan)
- Japan Society for the Promotion of Science (JSPS) for Young Scientists
- Grants-in-Aid for Scientific Research [24689001] Funding Source: KAKEN
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Gold catalysis enables direct construction of tetracyclic fused indolines through the migration of a propargyl substituent from an aniline nitrogen atom to the C3-position of an indole from 2-alkynyl-N-propargylanilines. This reaction provides rapid access to fused three-dimensional indolines in a single operation with the formation of four bonds and three rings.
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