Cobalt-Catalyzed Hydrogenation of Esters to Alcohols: Unexpected Reactivity Trend Indicates Ester Enolate Intermediacy

Highly efficient, general hydrogenation of aldehydes catalyzed by PNP iron pincer complexes

(2015) Thomas Zell et al.   Catalysis Science & Technology

Unprecedented Iron-Catalyzed Ester Hydrogenation. Mild, Selective, and Efficient Hydrogenation of Trifluoroacetic Esters to Alcohols Catalyzed by an Iron Pincer Complex

(2014) Thomas Zell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogenation of Esters to Alcohols with a Well-Defined Iron Complex

(2014) Svenja Werkmeister et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

System with Potential Dual Modes of Metal-Ligand Cooperation: Highly Catalytically Active Pyridine-Based PNNH-Ru Pincer Complexes

(2014) Eran Fogler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Based Catalysts for the Hydrogenation of Esters to Alcohols

(2014) Sumit Chakraborty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Four-Coordinate Cobalt Pincer Complexes: Electronic Structure Studies and Ligand Modification by Homolytic and Heterolytic Pathways

(2014) Scott P. Semproni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative addition and C–H activation chemistry with a PNP pincer-ligated cobalt complex

(2014) Scott P. Semproni et al.   Chemical Science

Mild and selective hydrogenation of aromatic and aliphatic (di)nitriles with a well-defined iron pincer complex

(2014) Christoph Bornschein et al.   Nature Communications

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters

(2013) Denis Spasyuk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron Pincer Complex Catalyzed, Environmentally Benign,E-Selective Semi-Hydrogenation of Alkynes

(2013) Dipankar Srimani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Hydrogenation for the In Situ Regeneration of an NAD(P)H Model: Biomimetic Reduction of α-Keto-/α-Iminoesters

(2013) Liang-Qiu Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formal loss of an H radical by a cobalt complex via metal–ligand cooperation

(2013) Eugene Khaskin et al.   CHEMICAL COMMUNICATIONS

Catalytic Hydrogenation Activity and Electronic Structure Determination of Bis(arylimidazol-2-ylidene)pyridine Cobalt Alkyl and Hydride Complexes

(2013) Renyuan Pony Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding the Mechanisms of Cobalt-Catalyzed Hydrogenation and Dehydrogenation Reactions

(2013) Guoqi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two Iron Catalysts are Better than One: A General and Convenient Reduction of Aromatic and Aliphatic Primary Amides

(2012) Shoubhik Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Hydrogenation of α,α′-Disubstituted Cycloketones through Dynamic Kinetic Resolution: An Efficient Construction of Chiral Diols with Three Contiguous Stereocenters

(2012) Chong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts

(2012) Denis Spasyuk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and Homogeneous Cobalt-Catalyzed Hydrogenation of CC, CO, and CN Bonds

(2012) Guoqi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine-Imidazolyl Ligands for the Efficient Ruthenium-Catalyzed Hydrogenation of Carboxylic Esters

(2012) Kathrin Junge et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Mechanism of Efficient Asymmetric Transfer Hydrogenation of Acetophenone Using an Iron(II) Complex Containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 Ligand: Partial Ligand Reduction Is the Key

(2012) Alexandre A. Mikhailine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiopure C1-Symmetric Bis(imino)pyridine Cobalt Complexes for Asymmetric Alkene Hydrogenation

(2012) Sebastien Monfette et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

(2012) W. Hill Harman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Transfer Hydrogenation of Ketimines Using Well-Defined Iron(II)-Based Precatalysts Containing a PNNP Ligand

(2012) Alexandre A. Mikhailine et al.   ORGANIC LETTERS

High-Activity Iron Catalysts for the Hydrogenation of Hindered, Unfunctionalized Alkenes

(2012) Renyuan Pony Yu et al.   ACS Catalysis

Catalytic Reductive Transformations of Carboxylic and Carbonic Acid Derivatives Using Molecular Hydrogen

(2012) Pavel A. Dub et al.   ACS Catalysis

Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Low-Pressure Hydrogenation of Carbon Dioxide Catalyzed by an Iron Pincer Complex Exhibiting Noble Metal Activity

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ester hydrogenation catalyzed by Ru-CNN pincer complexes

(2011) Yunshan Sun et al.   CHEMICAL COMMUNICATIONS

Ruthenium-catalysed hydrogenation of esters using tripodal phosphine ligands

(2011) Martin J. Hanton et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Catalytic anti-Selective Asymmetric Hydrogenation of .ALPHA.-Amino-.BETA.-Keto Esters through Dynamic Kinetic Resolution

(2011) Yasumasa Hamada et al.   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer Hydrogenation and H2Hydrogenation

(2011) Taichiro Touge et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selectivity and Mechanism of Hydrogen Atom Transfer by an Isolable Imidoiron(III) Complex

(2011) Ryan E. Cowley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrogenation of Carboxamides and Esters by Well-Defined Cp*Ru Complexes Bearing a Protic Amine Ligand

(2011) Masato Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron-Rich PNP- and PNN-Type Ruthenium(II) Hydrido Borohydride Pincer Complexes. Synthesis, Structure, and Catalytic Dehydrogenation of Alcohols and Hydrogenation of Esters

(2011) Jing Zhang et al.   ORGANOMETALLICS

New CNN-Type Ruthenium Pincer NHC Complexes. Mild, Efficient Catalytic Hydrogenation of Esters

(2011) Eran Fogler et al.   ORGANOMETALLICS

N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex

(2011) M. M. Rodriguez et al.   SCIENCE

The hydrogenation of molecules with polar bonds catalyzed by a ruthenium(ii) complex bearing a chelating N-heterocyclic carbene with a primary amine donor

(2010) Wylie W. N. O et al.   CHEMICAL COMMUNICATIONS

Synthesis and Electronic Structure of Cationic, Neutral, and Anionic Bis(imino)pyridine Iron Alkyl Complexes: Evaluation of Redox Activity in Single-Component Ethylene Polymerization Catalysts

(2010) Aaron M. Tondreau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed, Hydrogen-Mediated Reductive Cyclization of 1,6-Enynes and Diynes: Evidence for Bis(imino)pyridine Ligand Participation

(2009) Kevin T. Sylvester et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Asymmetric Transfer Hydrogenation of Ketones Catalyzed by an Iron Complex Containing a P−N−N−P Tetradentate Ligand Formed by Template Synthesis

(2009) Alexandre Mikhailine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron-Catalyzed Hydrogenation of Aldehydes

(2009) Charles P. Casey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Bifunctional Addition of Lactones and Esters at Low Temperatures. The First Intermediates in Lactone/Ester Hydrogenations

(2009) Satoshi Takebayashi et al.   ORGANOMETALLICS

Carbon−Oxygen Bond Cleavage by Bis(imino)pyridine Iron Compounds: Catalyst Deactivation Pathways and Observation of Acyl C−O Bond Cleavage in Esters

(2008) Ryan J. Trovitch et al.   ORGANOMETALLICS