4.4 Article

Synthesis and Properties of the Polymer Based on Benzoxazine with Two Perfluorohexyl Side Chains

Journal

CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 33, Issue 5, Pages 1042-1046

Publisher

SCIENCE PRESS
DOI: 10.6023/cjoc201212013

Keywords

benzoxaizne; thermal stability; dielectric constant; water absorbance; surface property

Funding

  1. Ministry of Science and Technology of China [2011ZX02703]

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A new benzoxazine with two perfluorohexyl side chains (M1) was synthesized and its homopolymerization was investigated. The results showed that the curing of M1 was occurred at near 257 degrees C, whereas the curing onset temperature can be lowered to 183 degrees C when a catalyst of 5 wt% imidazole was added. The cured M1 exhibited higher thermal stability with 5% and 10% weight loss temperatures of 337 and 382 degrees C, and a char yield of 45.9%, respectively. The cured M1 exhibited also good electrical properties with dielectric constant of 3.78 in a frequency of 1 MHz. The water absorption of the cured M1 was below 1%, and the surface free energy was 6.98 mN/m, respectively.

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