4.5 Article

Interfacial Tension of CO2 and Organic Liquid under High Pressure and Temperature

Journal

CHINESE JOURNAL OF CHEMICAL ENGINEERING
Volume 22, Issue 11-12, Pages 1302-1306

Publisher

CHEMICAL INDUSTRY PRESS
DOI: 10.1016/j.cjche.2014.09.042

Keywords

Carbon dioxide; Organic liquids; Interfacial tension; ADSA

Funding

  1. National Basic Research Program of China [2011CB707305]
  2. National Key Technologies RD Program [2012BAC24B00]
  3. National Nature Science Foundation of China [51304222]
  4. CNPC Innovation Foundation [2013D-5006-0204]
  5. Science Foundation of China University of Petroleum [YJRC-2013-20]

Ask authors/readers for more resources

In order to investigate the effect of organic liquid molecular structure and the intermolecular force operating with CO2 molecules and organic liquid molecules on interfacial tension (IFT) between CO2 and organic liquid at the first contact, the interfacial tension between CO2 and hexane, octane, ethanol and cyclohexane at different temperatures and pressures is measured by using the pendant drop method and the axisymmetric drop shape analysis (ADSA). The results show that the interfacial tension between CO2 and organic liquids is affected by the polarity and the structure of the organic liquid molecule obviously. The intermolecular force operating within CO2 molecules or organic liquid, and that between CO2 and organic liquids molecules play a dominate role on the interfacial tension between CO2 and the organic liquids. (C) 2014 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.

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