4.7 Article

Cycloaddition reactions of benzyne with olefins

Journal

CHINESE CHEMICAL LETTERS
Volume 25, Issue 12, Pages 1535-1539

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2014.09.013

Keywords

Cycloaddition; Benzyne; Olefins; Benzocyclobutenes; Biaryl; 9,10-Dihydrophenanthrene

Funding

  1. National Natural Science Foundation of China [20931006, 21072070, 21072071, 21272088]
  2. Program for Academic Leader in Wuhan Municipality [201271130441]

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Some novel cycloaddition reactions based on benzyne and olefins have been developed. These reactions were performed in the absence of a transition metal catalyst, and they displayed good yields. These cycloaddition reactions of benzyne with olefins provide effective routes for synthesizing benzocyclobutenes, biaryl compounds and 9,10-dihydrophenanthrene derivatives. (C) 2014 Guang-Ao Yu and Sheng-Hua Liu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

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