4.7 Article

Study on the supramolecular systems of two basic violets with cyclodextrins by MWNTs/Nafion modified glassy carbon electrode

Journal

CHINESE CHEMICAL LETTERS
Volume 20, Issue 8, Pages 981-984

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2009.03.018

Keywords

Basic violet; Carbon nanotubes; Modified electrode; Inclusion complexes

Funding

  1. National Natural Science Foundation of China [90813018]
  2. Natural Science Foundation of Shanxi Province of China [2007011023]

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The electrochemical properties of two basic violets (methyl violet and ethyl violet) at the MWNTs/Nafion modified glassy carbon electrode were investigated. The redox of the basic violets is two-electron and two-proton process, and methyl violet presents stronger electron transfer capacity than ethyl violet. Meanwhile, the inclusion constants of the two basic violets with five CDs were determined by differential pulse voltammetry (DPV). The two basic violets and CDs can form 1:1 complexes. The inclusion capacities of the two basic violets follow the same order: CM-beta-CD > HP-beta-CD > TM-beta-CD > DM-beta-CD > beta-CD. (C) 2009 Yu Jing Guo. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

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