Molecular Assembly of an Achiral Phosphine and a Chiral Primary Amine: A Highly Efficient Supramolecular Catalyst for the EnantioselectiveMichael Reaction of Aldehydes with Maleimides

Cinchona-based Primary Amine Catalysis in the Asymmetric Functionalization of Carbonyl Compounds

(2012) Paolo Melchiorre   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A general stereoselective enamine mediated alkylation of α-substituted aldehydes

(2012) Andrea Gualandi et al.   CHEMICAL COMMUNICATIONS

Noncovalent Bifunctional Organocatalysts: Powerful Tools for Contiguous Quaternary-Tertiary Stereogenic Carbon Formation, Scope, and Origin of Enantioselectivity

(2012) Thomas C. Nugent et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrophobic Substituent Effects on Proline Catalysis of Aldol Reactions in Water

(2012) Qingquan Zhao et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective organocatalytic aldol reaction using small organic molecules

(2012) Vishnumaya Bisai et al.   TETRAHEDRON

α-Heterosubstituted β-Alkylacroleins as Useful Multisubstituted Dienophiles for Enantioselective Diels-Alder Reactions

(2012) Akira Sakakura et al.   Asian Journal of Organic Chemistry

Organocatalytic Highly Enantioselective Synthesis of β-Formyl-α-hydroxyphosphonates

(2011) Sandun Perera et al.   ADVANCED SYNTHESIS & CATALYSIS

Dual Hydrogen-Bond/Enamine Catalysis Enables a Direct Enantioselective Three-Component Domino Reaction

(2011) Hasibur Rahaman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dynamic One-Pot Three-Component Catalytic Asymmetric Transformation by Combination of Hydrogen-Bond-Donating and Amine Catalysts

(2011) Shuangzheng Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Controlled Assembly of Chiral Tetraaminophosphonium Aryloxide-Arylhydroxide(s) in Solution

(2011) Daisuke Uraguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Catalytic Asymmetric Knoevenagel Condensation

(2011) Anna Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Primary Amine Catalyzed Enantioselective Protonation via an Enamine Intermediate

(2011) Niankai Fu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective organocatalytic formal allylation of α-branched aldehydes

(2011) Eduardo Rodrigo et al.   CHEMICAL COMMUNICATIONS

Organocatalytic Diels-Alder Reactions Catalysed by Supramolecular Self-Assemblies Formed from Chiral Amines and Poly(alkene glycol)s

(2011) Ai-Bao Xia et al.   CHEMISTRY-A EUROPEAN JOURNAL

In Situ Formed Bifunctional Primary Amine-Imine Catalyst for Asymmetric Aldol Reactions of α-Keto Esters

(2011) Xi Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective One-Pot Synthesis of α-Amino Esters by a Phosphine-Catalyzed [3+2]-Cycloaddition Reaction

(2011) Marianne Steurer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ar-BINMOLs with Axial and sp3 Central Chirality - Characterization, Chiroptical Properties, and Application in Asymmetric Catalysis

(2011) Guang Gao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recyclable Tertiary Amine Modified Diarylprolinol Ether as Aminocatalyst for the Sequential Asymmetric Synthesis of Functionalized Cyclohexanes and Chromenes

(2011) Hao Shen et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective Michael Additions of Isobutyraldehyde to Nitroalkenes Promoted by Amphiphilic Bifunctional Primary Amine-Thioureas in Organic or Aqueous Medium

(2011) Zhi-Wei Ma et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Dual Secondary Amine/N-Heterocyclic Carbene Catalysis in the Asymmetric Michael/Cross-Benzoin Cascade Reaction of β-Oxo Sulfones with Enals

(2011) Dieter Enders et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Kinetic Resolution of Cyclic Secondary Amines

(2011) Michael Binanzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Dual-Catalysis Approach to the Asymmetric Steglich Rearrangement and Catalytic Enantioselective Addition ofO-Acylated Azlactones to Isoquinolines

(2011) Chandra Kanta De et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene and Brønsted Acid Cooperative Catalysis: Asymmetric Synthesis oftrans-γ-Lactams

(2011) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Catalysis in Enantioselective Oxidopyrylium-Based [5 + 2] Cycloadditions

(2011) Noah Z. Burns et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-State Charge Stabilization through Multiple Non-covalent Interactions in the Guanidinium-Catalyzed Enantioselective Claisen Rearrangement

(2011) Christopher Uyeda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen cation–π interactions in asymmetric organocatalytic synthesis

(2011) Shinji Yamada et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Silicon-Based Lewis Acid Assisted Cinchona Alkaloid Catalysis: Highly Enantioselective Aza-Michael Reaction under Solvent-Free Conditions

(2011) Hua-Meng Yang et al.   ORGANIC LETTERS

Organocatalytic Iminium Ion/Carbene Reaction Cascade for the Formation of Optically Active 2,4-Disubstituted Cyclopentenones

(2011) Christian Borch Jacobsen et al.   ORGANIC LETTERS

Primary Amine/CSA Ion Pair: A Powerful Catalytic System for the Asymmetric Enamine Catalysis

(2011) Chen Liu et al.   ORGANIC LETTERS

Enantioselective Bromocycloetherification by Lewis Base/Chiral Brønsted Acid Cooperative Catalysis

(2011) Scott E. Denmark et al.   ORGANIC LETTERS

Asymmetric Michael additions of aldehydes to maleimides using a recyclable fluorous thiourea organocatalyst

(2011) Tsuyoshi Miura et al.   TETRAHEDRON LETTERS

Asymmetric Michael reactions of α,α-disubstituted aldehydes with maleimides using a primary amine thiourea organocatalyst

(2011) Tsuyoshi Miura et al.   TETRAHEDRON-ASYMMETRY

A highly efficient large-scale asymmetric Michael addition of isobutyraldehyde to maleimides promoted by a novel multifunctional thiourea

(2011) Zhi-wei Ma et al.   TETRAHEDRON-ASYMMETRY

Enamine/carbene cascade catalysis in the diastereo- and enantioselective synthesis of functionalized cyclopentanones

(2011) Kerem E. Ozboya et al.   Chemical Science

Recent advances in asymmetric catalysis with cinchona alkaloid-based primary amines

(2011) Lin Jiang et al.   Catalysis Science & Technology

Cooperative Organocatalysis for the Asymmetric γ Alkylation of α-Branched Enals

(2010) Giulia Bergonzini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organoammonium Salt-Catalyzed Enantioselective Cycloaddition Reactions with α-(Acyloxy)- or α-Diacylaminoacroleins

(2010) Akira Sakakura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Enantioselective Michael addition of ketones to maleimides catalyzed by bifunctional monosulfonyl DPEN salt

(2010) Feng Yu et al.   CHEMICAL COMMUNICATIONS

The uses of supramolecular chemistry in synthetic methodology development: examples of anion and neutral molecular recognition

(2010) Leo A. Joyce et al.   CHEMICAL SOCIETY REVIEWS

Combined Transition-Metal- and Organocatalysis: An Atom Economic C3 Homologation of Alkenes to Carbonyl and Carboxylic Compounds

(2010) Susanne T. Kemme et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Retro- and Transfer-Aldol Reactions Catalyzed by a Simple Chiral Primary Amine

(2010) Sanzhong Luo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Supramolecular Catalysis with Extended Aggregates and Gels: Inversion of Stereoselectivity Caused by Self-Assembly

(2010) Francisco Rodríguez-Llansola et al.   CHEMISTRY-A EUROPEAN JOURNAL

Isomeric Squaraine-Based [2]Pseudorotaxanes and [2]Rotaxanes: Synthesis, Optical Properties, and Their Tubular Structures in the Solid State

(2010) Min Xue et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diarylprolinol Silyl Ether Catalyzed Asymmetric Friedel-Crafts Alkylation of Indoles with α,β-Unsaturated Aldehydes: Enhanced Enantioselectivity and Mechanistic Investigations

(2010) Zi-Hui Shi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Chiral Primary Amine Catalyzed Asymmetric Epoxidation of α-Substituted Acroleins

(2010) Jiuyuan Li et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cooperative and Enantioselective NbCl5/Primary Amine Catalyzed Biginelli Reaction

(2010) Yong-Feng Cai et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Chiral Primary−Tertiary Diamine−Brønsted Acid Salt Catalyzed Syn-Selective Cross-Aldol Reaction of Aldehydes

(2010) Jiuyuan Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Supramolecular catalysis beyond enzyme mimics

(2010) Jurjen Meeuwissen et al.   Nature Chemistry

A highly efficient asymmetric Michael addition of α,α-disubstituted aldehydes to maleimides catalyzed by primary amine thiourea salt

(2010) Feng Yu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Attractive noncovalent interactions in asymmetric catalysis: Links between enzymes and small molecule catalysts

(2010) R. R. Knowles et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Chiral primary amine thiourea promoted highly enantioselective Michael reactions of isobutylaldehyde with maleimides

(2010) Jian-Fei Bai et al.   TETRAHEDRON

Highly enantioselective synthesis of warfarin and its analogs by means of cooperative LiClO4/DPEN-catalyzed Michael reaction: enantioselectivity enhancement and mechanism

(2010) Hua-Meng Yang et al.   TETRAHEDRON

Iron-catalyzed Michael reactions revisited: a synthetically useful process for the preparation of tri-carbonyl compounds and chiral warfarin

(2010) Hua-Meng Yang et al.   TETRAHEDRON LETTERS

Recent Progress in Asymmetric Bifunctional Catalysis Using Multimetallic Systems

(2009) Masakatsu Shibasaki et al.   ACCOUNTS OF CHEMICAL RESEARCH

Trends in Organocatalytic Conjugate Addition to Enones: An Efficient Approach to Optically Active Alkynyl, Alkenyl, and Ketone Products

(2009) Márcio Weber Paixão et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric catalysis with chiral primary amine-based organocatalysts

(2009) Li-Wen Xu et al.   CHEMICAL COMMUNICATIONS

Dual Organocatalysis: Asymmetric Allylic-Allylic Alkylation of α,α-Dicyanoalkenes and Morita-Baylis-Hillman Carbonates

(2009) Hai-Lei Cui et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Synthesis of Functionalized Cyclopentanones via a Multicatalytic Secondary Amine/N-Heterocyclic Carbene Catalyzed Cascade Sequence

(2009) Stephen P. Lathrop et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rational design of dynamic ammonium salt catalysts towards more flexible and selective function

(2009) Kazuaki ISHIHARA   PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES

Advances in asymmetric organocatalytic reactions catalyzed by chiral primary amines

(2008) Fangzhi Peng et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Pyridinium 1,1′-Binaphthyl-2,2′-disulfonates as Highly Effective Chiral Brønsted Acid−Base Combined Salt Catalysts for Enantioselective Mannich-Type Reaction

(2008) Manabu Hatano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The advent and development of organocatalysis

(2008) David W. C. MacMillan   NATURE

Primary amino acids: privileged catalysts in enantioselective organocatalysis

(2008) Li-Wen Xu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Organocatalytic Asymmetric Tandem Michael−Henry Reactions: A Highly Stereoselective Synthesis of Multifunctionalized Cyclohexanes with Two Quaternary Stereocenters

(2008) Bin Tan et al.   ORGANIC LETTERS

The Development of Asymmetric Primary Amine Catalysts Based on Cinchona Alkaloids

(2008) Ying-Chun Chen   SYNLETT

Noyori’s Ts-DPEN ligand: an efficient bifunctional primary amine-based organocatalyst in enantio- and diastereoselective Michael addition of 1,3-dicarbonyl indane compounds to nitroolefins

(2008) Ya-Dong Ju et al.   TETRAHEDRON LETTERS