Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 8, Issue 1, Pages 121-128Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201200726
Keywords
conducting materials; electrochemistry; fullerenes; photovoltaic devices; thiophenes
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Funding
- Funding Program for Next-Generation World-Leading Researchers, MEXT, Japan [KAKENHI 22000008]
- Grants-in-Aid for Scientific Research [22000008] Funding Source: KAKEN
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The efficient nucleophilic addition of aryl Grignard reagents (aryl=4-MeOC6H4, 4-Me2NC6H4, Ph, 4-CF3C6H4, and thienyl) to C-60 in the presence of DMSO produced 1,2-arylhydro[60]fullerenes after acid treatment. The reactions of the anions of these arylhydro[60]fullerenes with either dimethylphenylsilylmethyl iodide or dimethyl(2-isopropoxyphenyl)silylmethyl iodide yielded the target compounds, 1-aryl-4-silylmethyl[60]fullerenes. The properties and structures of these 1-aryl-4-silylmethyl[60]fullerenes (aryl=4-MeOC6H4, thienyl) were examined by electrochemical studies, X-ray crystallography, flash-photolysis time-resolved microwave-conductivity (FP-TRMC) measurements, and electron-mobility measurements by using a space-charge-limit-ed current (SCLC) model. Organic photovoltaic devices with a polymer-based bulk heterojunction structure and small-molecule-based p-n and p-in heterojunction configurations were fabricated by using 1-aryl-4-silylmethyl[60]fullerenes as an electron acceptor. The most efficient device exhibited a power-conversion efficiency of 3.4% (short-circuit current density: 8.1 mA/cm(2), open-circuit voltage: 0.69 V, fill factor: 0.59).
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