Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 5, Issue 7, Pages 1692-1699Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201000063
Keywords
chromogenic probes; cyanides; environmental chemistry; heterocycles; mercury
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Funding
- Ministerio de Ciencia e Innovacion, Spain [CTQ2006-15456-004-04BQU, CTQ2009-12631-BQU]
- Junta de Castilla y Leon
- Consejeria de Educacion y Cultura y Fondo Social Europeo [BU023A09, GR170]
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The synthesis of some new polysulfur-nitrogen heterocycles by cycloaddition of an ynamine to bisdithiolothiazine ketothiones or dithiones is described and the interconversion between regioisomers is studied by DFT calculations, showing that the double bond isomerizes at room temperature. This series is a new selective and sensitive chromogenic probe for the naked-eye detection of mercury(II) cation and cyanide anion in buffered (HEPES 0.05M, pH 7.14) water/acetonitrile 1:1 mixture, with sub-micromolar sensitivity, and constitutes the first example of a new class of colorimetric chemical probes for Hg2+ and CN-.
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