Activation Parameters as Mechanistic Probes in the TAML Iron(V)-Oxo Oxidations of Hydrocarbons

Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(v)–oxo complex

(2014) Eunji Kwon et al.   CHEMICAL COMMUNICATIONS

Formation of a Room Temperature Stable FeV(O) Complex: Reactivity Toward Unactivated C–H Bonds

(2014) Munmun Ghosh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen-Bonding Effects on the Reactivity of [X–FeIII–O–FeIV═O] (X = OH, F) Complexes toward C–H Bond Cleavage

(2013) Genqiang Xue et al.   INORGANIC CHEMISTRY

Dichotomous Hydrogen Atom Transfer vs Proton-Coupled Electron Transfer During Activation of X–H Bonds (X = C, N, O) by Nonheme Iron–Oxo Complexes of Variable Basicity

(2013) Dandamudi Usharani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Theoretical Evidence for Multiple FeIV Reactive Intermediates in TAML-Activator Catalysis: Rationalizing a Counterintuitive Reactivity Order

(2012) Soumen Kundu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Detection and Kinetic Characterization of a Highly Reactive Heme–Thiolate Peroxygenase Compound I

(2012) Xiaoshi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A High-Valent Iron–Oxo Corrolazine Activates C–H Bonds via Hydrogen-Atom Transfer

(2012) Kevin Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic insight from thermal activation parameters for oxygenation reactions of different substrates with biomimetic iron porphyrin models for compounds I and II

(2011) Christoph Fertinger et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

On the Reactivity of Mononuclear Iron(V)oxo Complexes

(2011) Soumen Kundu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox Potential and C−H Bond Cleaving Properties of a Nonheme FeIV═O Complex in Aqueous Solution

(2010) Dong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Million-fold activation of the [Fe2(µ-O)2] diamond core for C–H bond cleavage

(2010) Genqiang Xue et al.   Nature Chemistry

A Two-State Reactivity Model Explains Unusual Kinetic Isotope Effect Patterns in CH Bond Cleavage by Nonheme Oxoiron(IV) Complexes

(2009) Eric J. Klinker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Bond Cleavage with Reductants: Re-Investigating the Reactivity of Monomeric MnIII/IV−Oxo Complexes and the Role of Oxo Ligand Basicity

(2009) Trenton H. Parsell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(TAML)FeIVO Complex in Aqueous Solution: Synthesis and Spectroscopic and Computational Characterization

(2008) Arani Chanda et al.   INORGANIC CHEMISTRY

Catalase−Peroxidase Activity of Iron(III)−TAML Activators of Hydrogen Peroxide

(2008) Anindya Ghosh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY