1,n-Hydrogen-Atom Transfer (HAT) Reactions in Whichn≠5: An Updated Inventory

Chemoselective Amination of Propargylic C(sp3)H Bonds by Cobalt(II)-Based Metalloradical Catalysis

(2014) Hongjian Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thiyl Radicals in Organic Synthesis

(2014) Fabrice Dénès et al.   CHEMICAL REVIEWS

Intramolecular 1,2- and 1,3-Hydrogen Transfer Reactions of Thiyl Radicals

(2014) Christian Schöneich et al.   ISRAEL JOURNAL OF CHEMISTRY

sp3 C–H oxidation by remote H-radical shift with oxygen- and nitrogen-radicals: a recent update

(2014) Shunsuke Chiba et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Tin-Free Regioselective Radical De-O-benzylation by an Intramolecular Hydrogen Atom Transfer on Carbohydrate Templates

(2013) Angie Attouche et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[RuIV(F20-TPP)Cl2] efficiently catalysed inter- and intra-molecular nitrene insertion into sp3 C–H bonds of hydrocarbons using phosphoryl azides as nitrene sources

(2013) Wenbo Xiao et al.   CHEMICAL COMMUNICATIONS

Finding the right path: Baldwin “Rules for Ring Closure” and stereoelectronic control of cyclizations

(2013) Igor V. Alabugin et al.   CHEMICAL COMMUNICATIONS

Concerted Reactions That Produce Diradicals and Zwitterions: Electronic, Steric, Conformational, and Kinetic Control of Cycloaromatization Processes

(2013) Rana K. Mohamed et al.   CHEMICAL REVIEWS

Axial-to-central chirality transfer in cyclization processes

(2013) Damien Campolo et al.   CHEMICAL SOCIETY REVIEWS

Stabilization of long-chain intermediates in solution. Octyl radicals and cations

(2013) Aleksandar V. Teodorović et al.   JOURNAL OF MOLECULAR STRUCTURE

The use of the methods of radiolysis to explore the mechanisms of free radical modifications in proteins

(2013) Chantal Houée-Levin et al.   Journal of Proteomics

DNA Double Strand Cleavage via Interstrand Hydrogen Atom Abstraction

(2013) Marisa L. Taverna Porro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An aminated reaction

(2013) Tom G. Driver   Nature Chemistry

Synthetic use of the primary kinetic isotope effect in hydrogen atom transfer 2: generation of captodatively stabilised radicals

(2013) Mark E. Wood et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Tetraalkylammonium-Templated Stereoselective Norrish–Yang Cyclization

(2013) Shinji Yamada et al.   ORGANIC LETTERS

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

Benzophenone Photosensitized DNA Damage

(2012) M. Consuelo Cuquerella et al.   ACCOUNTS OF CHEMICAL RESEARCH

Copper Carbenoid, Reactant and Catalyst for One-Pot Diazo Ester Coupling Cascade Rearrangement of Enediynes: Formation of Two Contiguous Tetrasubstituted Stereocenters

(2012) Shovan Mondal et al.   ADVANCED SYNTHESIS & CATALYSIS

Carbon-Centered Radicals Can Transfer Hydrogen Atoms between Amino Acid Side Chains

(2012) Quentin Raffy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Carbocycles and Heterocycles by Radical/Polar and Polar/Radical Cascades

(2012) Shovan Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Hydrogen Atom Transfer (HAT) for Sustainable and Diastereoselective Radical Reduction

(2012) Andreas Gansäuer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-pot Crabbé homologation-radical cascade cyclisation with memory of chirality

(2012) Shovan Mondal et al.   CHEMICAL COMMUNICATIONS

Intramolecular Hydrogen Transfer Reactions of Thiyl Radicals from Glutathione: Formation of Carbon-Centered Radical at Glu, Cys, and Gly

(2012) Olivier Mozziconacci et al.   CHEMICAL RESEARCH IN TOXICOLOGY

Reactions of Vinylidenecyclopropanes with Diphenyl Diselenide in the Presence of AIBN and Thermally-Induced Further Transformations

(2012) Wei Yuan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6- or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines

(2012) Damien Campolo et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Oxaziridine-Mediated Oxidation of C–H Bonds

(2012) Hashim F. Motiwala et al.   JOURNAL OF ORGANIC CHEMISTRY

Inter- and Intramolecular Mechanisms for Chlorine Rearrangements in Trimethyl-Substituted N-Chlorohydantoins

(2012) Billy W. McCann et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Copper-Catalyzed Aerobic Aliphatic C–H Oxygenation Directed by an Amidine Moiety

(2012) Yi-Feng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hybrids of amino acids and acetylenic DNA-photocleavers: optimising efficiency and selectivity for cancer phototherapy

(2012) Boris Breiner et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Aliphatic C–H Amination with an Amidine Moiety

(2012) Hui Chen et al.   ORGANIC LETTERS

Photoinduced CC-coupling Reactions of Rigid Diastereomeric Benzophenone-Methionine Dyads

(2012) Anna Lewandowska-Andralojc et al.   PHOTOCHEMISTRY AND PHOTOBIOLOGY

Intramolecular hydrogen atom migration along the backbone of cationic and neutral radical tripeptides and subsequent radical-induced dissociations

(2012) Junfang Zhao et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Photochemical Reactions as Key Steps in Natural Product Synthesis

(2011) Thorsten Bach et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An efficient and recyclable hybrid nanocatalyst to promote enantioselective radical cascade rearrangements of enediynes

(2011) Malek Nechab et al.   CHEMICAL COMMUNICATIONS

Non-Cp titanium alkoxide-based homolytic ring-opening of epoxides by an intramolecular hydrogen abstraction in β-titanoxy radical intermediates

(2011) Tsuyoshi Kawaji et al.   CHEMICAL COMMUNICATIONS

Purine 5′,8-cyclonucleoside lesions: chemistry and biology

(2011) Chryssostomos Chatgilialoglu et al.   CHEMICAL SOCIETY REVIEWS

1,8-Hydrogen Atom Transfer Promoted by N-Radicals in (1→4)-O-Disaccharide Models

(2011) Elisa I. León et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Translocation versus cyclisation in radicals derived from N-3-alkenyl trichloroacetamides

(2011) M. Luisa Marin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Radical carbonylation of ω-alkynylamines leading to α-methylene lactams. Synthetic scope and the mechanistic insights

(2011) Ilhyong Ryu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of the Asperparaline Core by a Radical Cascade

(2011) Peter J. Crick et al.   ORGANIC LETTERS

Discovery of Hypoiodite-Mediated Aminyl Radical Cyclization Lacking a Nitrogen Radical-Stabilizing Group: Application to Synthesis of an Oxazaspiroketal-Containing Cephalostatin Analog

(2011) Myong Koag et al.   ORGANIC LETTERS

Selective Intramolecular CH Amination through the Metalloradical Activation of Azides: Synthesis of 1,3-Diamines under Neutral and Nonoxidative Conditions

(2010) Hongjian Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Photocyclizations of N-(ω-Hydroxyalkyl)tetrachlorophthalimide with Alkenes Leading to Medium- and Large-Ring Heterocycles-Reaction Modes and Regio- and Stereoselectivity of the 1,n-Biradicals

(2010) Yong-Miao Shen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen Atom Transfer Experiments Provide Chemical Evidence for the Conformational Differences between C- and O-Disaccharides

(2010) Elisa I. León et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Memory of Chirality in Cascade Rearrangements of Enediynes

(2010) Malek Nechab et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral discrimination in the hydrogen-atom transfer between tyrosine and benzophenone in rigid peptides

(2009) Anna Lewandowska et al.   CHEMICAL PHYSICS LETTERS

Stereoselectivity of the Hydrogen-Atom Transfer in Benzophenone-Tyrosine Dyads: An Intramolecular Kinetic Solvent Effect

(2009) Gerald Hörner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Competitive Reaction Pathways foro-Anilide Aryl Radicals: 1,5- or 1,6-Hydrogen Transfer versus Nucleophilic Coupling Reactions. A Novel Rearrangement to Afford an Amidyl Radical

(2009) Valentina Rey et al.   JOURNAL OF ORGANIC CHEMISTRY

The Photochemical C2−C6Cyclization of Enyne−Allenes: Interception of the Fulvene Diradical with a Radical Clock Ring Opening

(2009) Götz Bucher et al.   JOURNAL OF ORGANIC CHEMISTRY

Solvent Effects on the Intramolecular Hydrogen-Atom Transfer between Tyrosine and Benzophenone. Diverting Reaction Mechanisms in Protic and Nonprotic Media

(2009) Gerald Hörner et al.   Journal of Physical Chemistry C

Oxaziridine-Mediated Intramolecular Amination of sp3-Hybridized C−H Bonds

(2009) Charles P. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total synthesis of eudesmane terpenes by site-selective C–H oxidations

(2009) Ke Chen et al.   NATURE

Synthesis of natural products containing spiroketals via intramolecular hydrogen abstraction

(2009) Jonathan Sperry et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct Construction of 1,3-Diaxial Diol Derivatives by C−H Hydroxylation

(2009) Satoshi Kasuya et al.   ORGANIC LETTERS

Asymmetric synthesis of β-lactams using chiral-memory effect on photochemical γ-hydrogen abstraction by thiocarbonyl group

(2008) Masami Sakamoto et al.   CHEMICAL COMMUNICATIONS

Photochemical Reactions as Key Steps in Organic Synthesis

(2008) Norbert Hoffmann   CHEMICAL REVIEWS

Intramolecular 1,8-Hydrogen-Atom Transfer Reactions in (1→4)-O-Disaccharide Systems: Conformational and Stereochemical Requirements

(2008) Cosme G. Francisco et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereoselective Radical Translocations

(2008) Philippe Renaud et al.   CHIMIA

Intramolecular 1,8-Hydrogen Atom Transfer. Stereoselectivity of the Hexopyranos-5′-yl Radical Reactions in Hexp-(1→4)-HexpDisaccharide Systems

(2008) Ángeles Martín et al.   JOURNAL OF ORGANIC CHEMISTRY

A Synthetic Approach to the Fusicoccane A−B Ring Fragment Based on a Pauson−Khand Cycloaddition/Norrish Type 1 Fragmentation

(2008) Gregory R. Dake et al.   JOURNAL OF ORGANIC CHEMISTRY

Rate Constants for 1,5- and 1,6-Hydrogen Atom Transfer Reactions of Mono-, Di-, and Tri-aryl-substituted Donors, Models for Hydrogen Atom Transfers in Polyunsaturated Fatty Acid Radicals

(2008) Christopher B. DeZutter et al.   JOURNAL OF PHYSICAL CHEMISTRY A

1,3-Diol Synthesis via Controlled, Radical-Mediated C−H Functionalization

(2008) Ke Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photogeneration of 2-Deoxyribonolactone in Benzophenone−Purine Dyads. Formation of Ketyl−C1′ Biradicals

(2008) Cecilia Paris et al.   ORGANIC LETTERS

Preparation of Five-Membered Rings via the Translocation-Cyclization of Vinyl Radicals

(2008) Fabrice Dénès et al.   SYNLETT

Stereoselective synthesis of C-ketosides by sequential intramolecular hydrogen atom transfer–intermolecular allylation reaction

(2008) Angeles Martín et al.   TETRAHEDRON LETTERS

Highly Efficient Photochemically Induced Thiyl Radical-Mediated Racemization of Aliphatic Amines at 30 °C

(2007) Lucie Routaboul et al.   JOURNAL OF ORGANIC CHEMISTRY