Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 50, Pages 16574-16582Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403584
Keywords
donor-pi-acceptor-acceptor; dyes/pigments; indenothiophenes; intramolecular charge transfer; organic sensitizers; solar cells
Categories
Funding
- National Science Council of Taiwan [NSC 101-2113M-002-009-MY3]
Ask authors/readers for more resources
Two D-pi-A'-A regioisomers (A-IDT-D and D-IDT-A) featuring 4,4'-di-p-tolyl-4H-indeno[1,2-b]-thiophene as a pi linker (pi) between the diarylamino donor (D) and the pyrimidine-cyanoacrylic acid acceptor (A'-A) have been successfully synthesized and characterized as efficient sensitizers for the dye-sensitized solar cells (DSSCs). The different arrangements of the D and A'-A blocks on the unsymmetrical indenothiophene (IDT) core render the dipole of IDT being along (A-IDT-D) or opposite (D-IDT-A) to the direction of intramolecular (donor-to-acceptor) charge transfer, and thus induce variations in the physical properties. The experimental observations correlated well with the theoretical analyses, clearly revealing the trade-off between the molar extinction coefficient (epsilon) and the S-0 -> S-1 transition energy. As a result, a superior e value was observed for D-IDT-A, whereas a bathochromic shift in the absorption occurred in A-IDT-D. The larger e value of D-IDT-A together with its more favorable energy level relative to TiO2 led to a higher power conversion efficiency of 7.41% for the D-IDT-A-based DSSC, retaining approximately 95% of the N719-based DSSC efficiency. This work manifests the clear structure-property relationship for the case of donor and acceptor components being connected by an unsymmetrical pi linker and provides insights for molecular engineering of organic sensitizers.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available