C(sp3)H Activation without a Directing Group: Regioselective Synthesis ofN-Ylide orN-Heterocyclic Carbene Complexes Controlled by the Choice of Metal and Ligand

Metal control of selectivity in acetate-assisted C–H bond activation: an experimental and computational study of heterocyclic, vinylic and phenylic C(sp2)–H bonds at Ir and Rh

(2014) Kevin J. T. Carr et al.   Chemical Science

Catalyst-Controlled Divergent C–H Functionalization of Unsymmetrical 2-Aryl Cyclic 1,3-Dicarbonyl Compounds with Alkynes and Alkenes

(2013) Johnathon D. Dooley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigation of Palladium-Catalyzed Allylic C–H Activation

(2013) Casper Engelin et al.   ACS Catalysis

Cp*IrIII-Catalyzed Oxidative Coupling of Benzoic Acids with Alkynes

(2013) Daniel A. Frasco et al.   ACS Catalysis

Fullerenes as Neutral Carbon-Based Lewis Acids

(2012) Javier Iglesias-Sigüenza et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple and versatile selective synthesis of neutral and cationic copper(i) N-heterocyclic carbene complexes using an electrochemical procedure

(2012) Benjamin R. M. Lake et al.   CHEMICAL COMMUNICATIONS

Nitrate as a redox co-catalyst for the aerobic Pd-catalyzed oxidation of unactivated sp3-C–H bonds

(2012) Kara J. Stowers et al.   Chemical Science

Copper-catalysed addition of α-alkyl azaarenes to ethyl glyoxylate via direct C(sp3)–H activation

(2012) Jia-Jia Jin et al.   RSC Advances

Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands

(2011) Alison N. Campbell et al.   CHEMICAL COMMUNICATIONS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Variable coordination of amine functionalised N-heterocyclic carbene ligands to Ru, Rh and Ir: C–H and N–H activation and catalytic transfer hydrogenation

(2011) Warren B. Cross et al.   DALTON TRANSACTIONS

Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes

(2011) Serge I. Gorelsky et al.   JOURNAL OF ORGANIC CHEMISTRY

Dehydrogenative [4 + 2] Cycloaddition of Formamides with Alkynes through Double C−H Activation

(2011) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Water Oxidation Catalyzed by Strong Carbene-Type Donor-Ligand Complexes of Iridium

(2010) Ralte Lalrempuia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed α-Arylation of Carbonyl and Related Molecules: Novel Trends in CC Bond Formation by CH Bond Functionalization

(2010) Carin C. C. Johansson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A computational study of solution equilibria of platinum-based ethylene hydroamination catalytic species including solvation and counterion effects: Proper treatment of the free energy of solvation☆

(2010) Pavel A. Dub et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Investigation of the Mechanism of C(sp3)−H Bond Cleavage in Pd(0)-Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and Sulfonamides

(2010) Sophie Rousseaux et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2and sp3Carbon−Hydrogen Bonds

(2010) Dmitry Shabashov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Benzylic Addition of 2-Methyl Azaarenes toN-Sulfonyl Aldimines via C−H Bond Activation

(2010) Bo Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyrrole Synthesis via Allylic sp3C−H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes

(2010) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III)

(2009) Qiao-Wen Chang et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A Csp3H Bond Activation α to the Trifluoromethyl Group

(2009) Yong Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides

(2009) Fabio Bellina et al.   CHEMICAL REVIEWS

Toward Efficient Palladium-Catalyzed Allylic CH Alkylation

(2009) Thomas Jensen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanisms of C–H bond activation: rich synergy between computation and experiment

(2009) Youcef Boutadla et al.   DALTON TRANSACTIONS

Pd(0)/PR3-Catalyzed Intermolecular Arylation of sp3C−H Bonds

(2009) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Programmed Synthesis of Tetraarylthiophenes through Sequential C−H Arylation

(2009) Shuichi Yanagisawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2(M = Ir, Rh): Regioselectivity, Kinetics, and Mechanism

(2009) Ling Li et al.   ORGANOMETALLICS

Site-Selective sp2and Benzylic sp3Palladium-Catalyzed Direct Arylation

(2008) Louis-Charles Campeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation and Crystal Structures of Both Enol and Keto Tautomer Intermediates in a Hydration of an Alkyne−Carboxylic Acid Ester Catalyzed by Iridium Complexes in Water

(2008) Hironobu Kanemitsu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Benzocyclobutenes by Palladium-Catalyzed C−H Activation of Methyl Groups: Method and Mechanistic Study

(2008) Manon Chaumontet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands

(2008) Sachiko Arita et al.   ORGANOMETALLICS