Ring Opening and Bidentate Coordination of Amidinate Germylenes and Silylenes on Carbonyl Dicobalt Complexes: The Importance of a Slight Difference in Ligand Volume

N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field

(2014) Burgert Blom et al.   Inorganic Chemistry Frontiers

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Application of a Bis(silylene) Nickel Complex as Precatalyst in C–C Bond Formation Reactions

(2013) Chika I. Someya et al.   CHEMISTRY LETTERS

Mixed valence η6-arene cobalt(i) and cobalt(ii) compound

(2013) Ramachandran Azhakar et al.   DALTON TRANSACTIONS

Five-Coordinate Silicon(II) Compounds with Si–M Bonds (M = Cr, Mo, W, Fe): Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II) as a Ligand in Transition-Metal Complexes

(2013) Konstantin Junold et al.   INORGANIC CHEMISTRY

Oxidative Addition Versus Substitution Reactions of Group 14 Dialkylamino Metalylenes with Pentafluoropyridine

(2013) Prinson P. Samuel et al.   INORGANIC CHEMISTRY

From a Zwitterionic Phosphasilene to Base Stabilized Silyliumylidene-Phosphide and Bis(silylene) Complexes

(2013) Nora C. Breit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction

(2013) Daniel Gallego et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron-Rich N-Heterocyclic Silylene (NHSi)–Iron Complexes: Synthesis, Structures, and Catalytic Ability of an Isolable Hydridosilylene–Iron Complex

(2013) Burgert Blom et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organic Amides as Suitable Precursors to Stabilize Stannylenes

(2013) Lucía Álvarez-Rodríguez et al.   ORGANOMETALLICS

Facile Access to Mono- and Dinuclear Heteroleptic N-Heterocyclic Silylene Copper Complexes

(2013) Gengwen Tan et al.   ORGANOMETALLICS

Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II): A Silicon(II) Compound with Both a Bidentate and a Monodentate Amidinato Ligand

(2012) Konstantin Junold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pushing the σ-Donor Strength in Iridium Pincer Complexes: Bis(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands

(2012) Andreas Brück et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Unexpected Coordination of a Silicon(II)-Based SiCSi Pincerlike Arene to Palladium

(2012) Wenyuan Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bis(silylenyl)- and Bis(germylenyl)-Substituted Ferrocenes: Synthesis, Structure, and Catalytic Applications of Bidentate Silicon(II)-Cobalt Complexes

(2012) Wenyuan Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile Access to Silicon-Functionalized Bis-Silylene Titanium(II) Complexes

(2012) Burgert Blom et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal Complexes of Tetrylones [(CO)5W-E(PPh3)2] and Tetrylenes [(CO)5W-NHE] (E=C-Pb): A Theoretical Study

(2012) Thi Ai Nhung Nguyen et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules

(2012) Burgert Blom et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand

(2012) Ramachandran Azhakar et al.   Chemistry-An Asian Journal

The group 7 metal carbonyl complexes from a stable heteroleptic silylene PhC(NtBu)2SiNPh2

(2012) Ramachandran Azhakar et al.   DALTON TRANSACTIONS

Expanding the coordination chemistry of donor-stabilized group-14 metalenes

(2012) Javier A. Cabeza et al.   DALTON TRANSACTIONS

Diaminogermylene and Diaminostannylene Derivatives of Gold(I): Novel AuM and AuM2 (M = Ge, Sn) Complexes

(2012) Javier A. Cabeza et al.   INORGANIC CHEMISTRY

Synthesis of Mixed Tin–Ruthenium and Tin–Germanium–Ruthenium Carbonyl Clusters from [Ru3(CO)12] and Diaminometalenes (M = Sn, Ge)

(2012) Javier A. Cabeza et al.   INORGANIC CHEMISTRY

Bis(amidinato)germylenerhodium Complexes: Synthesis, Structure, and Density Functional Theory Calculations

(2012) Dimitri Matioszek et al.   INORGANIC CHEMISTRY

Coordination Chemistry of Cyclic Disilylated Stannylenes and Plumbylenes to Group 4 Metallocenes

(2012) Henning Arp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)2SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)2, OtBu)

(2012) Ramachandran Azhakar et al.   ORGANOMETALLICS

Group 14 Hydrides with Low Valent Elements for Activation of Small Molecules

(2011) Swadhin K. Mandal et al.   ACCOUNTS OF CHEMICAL RESEARCH

Evaluation of ligand effects in the modified cobalt hydroformylation of 1-octene. Crystal structures of [Co(L)(CO)3]2 (L = PA–C5, PCy3 and PCyp3)

(2011) Peter N. Bungu et al.   DALTON TRANSACTIONS

Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene

(2011) Ramachandran Azhakar et al.   INORGANIC CHEMISTRY

Reactivity of Diaminogermylenes with Ruthenium Carbonyl: Ru3Ge3and RuGe2Derivatives

(2011) Javier A. Cabeza et al.   INORGANIC CHEMISTRY

Stabilization of Low Valent Silicon Fluorides in the Coordination Sphere of Transition Metals

(2011) Ramachandran Azhakar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

A Brief Survey of Our Contribution to Stable Carbene Chemistry

(2011) David Martin et al.   ORGANOMETALLICS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds

(2010) Mitsuo Kira   CHEMICAL COMMUNICATIONS

Interstellar molecules: guides for new chemistry

(2010) Swadhin K. Mandal et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Synthesis of Monomeric Divalent Tin(II) Compounds with Terminal Chloride, Amide, and Triflate Substituents

(2010) Sakya S. Sen et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Facile Syntheses of Silylene Nickel Carbonyl Complexes from Lewis Base Stabilized Chlorosilylenes†

(2010) Gašper Tavčar et al.   INORGANIC CHEMISTRY

Reactivity Studies of a GeI−GeICompound with and without Cleavage of the Ge−Ge Bond

(2010) Sakya S. Sen et al.   INORGANIC CHEMISTRY

An Isolable Bis-Silylene Oxide (“Disilylenoxane”) and Its Metal Coordination

(2010) Wenyuan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Triphenylphosphane-Modified Cobalt Catalysts for the Selective Carbonylation of Ethyl Diazoacetate

(2010) Neszta Ungvári et al.   ORGANOMETALLICS

Iridium−Germanium and −Tin Carbonyl Complexes

(2010) Richard D. Adams et al.   ORGANOMETALLICS

Halogermanium(II) Complexes Having Phenylamidinate As Supporting Ligands: Syntheses, Characterizations, and Reactivities

(2010) Dimitri Matioszek et al.   ORGANOMETALLICS

Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

(2009) Macarena Poyatos et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

A Base-Stabilized Silylene with a Tricoordinate Silicon Atom as a Ligand for a Metal Complex

(2009) Wei Yang et al.   INORGANIC CHEMISTRY

Germylene and stannylene (Me2NCH2CH2O)2E as strong σ-donor ligands for transition metal complexes [ML(CO)n] (E=Ge, Sn; M=Cr, Mo, W, n=4 or 5; M=Fe, n=4). Synthesis, spectroscopic and theoretical study

(2009) Ivan A. Portnyagin et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, characterisation and reactivity of germanium(ii) amidinate and guanidinate complexes

(2008) Cameron Jones et al.   DALTON TRANSACTIONS

Mono- and Bidentate Benzannulated N-Heterocyclic Germylenes, Stannylenes and Plumbylenes

(2008) Alexander V. Zabula et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ruthenium–tin complexes from the reaction of HSnPh3 with Ru3(CO)10(NCMe)2 and their reactions with bis(tri-t-butylphosphine)platinum

(2008) Richard D. Adams et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Trapping of Tin(II) and Lead(II) Homologues of Carbon Monoxide by a Benzannulated Lutidine-Bridged Bisstannylene

(2008) Alexander V. Zabula et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homoleptic Complexes of Bisstannylenes with Nickel(0): Synthesis, X-Ray Diffraction Studies, and119Sn NMR Investigations

(2008) Alexander V. Zabula et al.   ORGANOMETALLICS

The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)

(2008) Selvarajan Nagendran et al.   ORGANOMETALLICS

Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System

(2007) Roy A. Kelly III et al.   ORGANOMETALLICS