Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 28, Pages 8566-8570Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402612
Keywords
cyclodextrin; nanoreactors; nanotubes; self-assembly; supramolecular catalysts
Categories
Funding
- 973 Program [2011CB932502]
- National Natural Science Foundation of China (NNSFC) [20932004, 91227107, 91027007, 21272125, 21102075]
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The extremely strong noncovalent complexation between the rigid host of phthalocyanine-bridged beta-cyclodextrins and the amphiphilic guest carboxylated porphyrin is employed to construct a hollow tubular structure as a supramolecular nanoreactor. A representative coupling reaction occurs in the hydrophobic interlayers of the tubular walls in pure water at room temperature, leading to an enhancement of ten times higher reaction rate without any adverse effect on catalytic activity and conversion.
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