4.6 Article

Exploring the Synthesis of a New Group of Chiral Ammonium Salts with Specific Configurations at the Stereogenic Nitrogen Centers

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 12, Pages 3268-3272

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304433

Keywords

amines; chiral ammonium salts; chiral interfaces; chirality

Funding

  1. Cluster of Excellence RESOLV [EXC 1069]
  2. Deutsche Forschungsgemeinschaft

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A group of new chiral dications with a fixed, specific configuration at the stereogenic nitrogen center was created. Stereoselective synthesis and recrystallization give the diastereomerically and enantiomerically pure dications, including a chiral amphiphile with surface-active properties.

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