Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 19, Issue 30, Pages 9973-9978Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201301493
Keywords
asymmetric catalysis; aza-Michael reaction; enones; imides; synthetic methods
Categories
Funding
- Progetto di Ateneo
- Sapienza University of Roma
- Ottopermillevaldese (Chiesa Valdese Italiana)
- COST action [ORCA 0905]
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A challenging asymmetric reaction (aza-Michael addition of imides to enones) has been optimized through an integrated approach involving the synthesis of a family of organocatalysts, multiple catalysis (usage of additives), and finally with rational exploration of the chemical space by the application of the experiment design.
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