Heteroleptic Tin(II) Initiators for the Ring-Opening (Co)Polymerization of Lactide and Trimethylene Carbonate: Mechanistic Insights from Experiments and Computations

Synergistic Empirical and Theoretical Study on the Stereoselective Mechanism for the Aluminum Salalen Complex Mediated Polymerization ofrac-Lactide

(2013) Ines dos Santos Vieira et al.   CHEMISTRY-A EUROPEAN JOURNAL

Discrete Divalent Rare-Earth Cationic ROP Catalysts: Ligand-Dependent Redox Behavior and Discrepancies with Alkaline-Earth Analogues in a Ligand-Assisted Activated Monomer Mechanism

(2013) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates

(2013) Samuel Dagorne et al.   COORDINATION CHEMISTRY REVIEWS

Macromolecular engineering via ring-opening polymerization (2): l-lactide/trimethylene carbonate copolymerization – kinetic and microstructural control via catalytic tuning

(2013) William Guerin et al.   Polymer Chemistry

Protic compound mediated living cross-chain-transfer polymerization of rac-lactide: synthesis of isotactic (crystalline)–heterotactic (amorphous) stereomultiblock polylactide

(2012) Wei Zhao et al.   CHEMICAL COMMUNICATIONS

Heteroleptic Silylamido Phenolate Complexes of Calcium and the Larger Alkaline Earth Metals: β-Agostic Ae⋅⋅⋅SiH Stabilization and Activity in the Ring-Opening Polymerization ofL-Lactide

(2012) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthetic and Mechanistic Aspects of the Immortal Ring-Opening Polymerization of Lactide and Trimethylene Carbonate with New Homo- and Heteroleptic Tin(II)-Phenolate Catalysts

(2012) Valentin Poirier et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of cyclic polylactide catalysed by bis(salicylaldiminato)tin(ii) complexes

(2012) Parichat Piromjitpong et al.   DALTON TRANSACTIONS

Yttrium Phosphasalen Initiators for rac-Lactide Polymerization: Excellent Rates and High Iso-Selectivities

(2012) Clare Bakewell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Roles of Monomer Binding and Alkoxide Nucleophilicity in Aluminum-Catalyzed Polymerization of ε-Caprolactone

(2012) Keying Ding et al.   MACROMOLECULES

Thermodynamics of the Carbon Dioxide–Epoxide Copolymerization and Kinetics of the Metal-Free Degradation: A Computational Study

(2012) Donald J. Darensbourg et al.   MACROMOLECULES

Recent advances in metallo/organo-catalyzed immortal ring-opening polymerization of cyclic carbonates

(2012) Sophie M. Guillaume et al.   Catalysis Science & Technology

Group 4 salalen complexes for the production and degradation of polylactide

(2011) Emma L. Whitelaw et al.   CHEMICAL COMMUNICATIONS

Mechanism of the Living Lactide Polymerization Mediated by Robust Zinc Guanidine Complexes

(2011) Janna Börner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Exploring Electronic versus Steric Effects in Stereoselective Ring-Opening Polymerization of Lactide and β-Butyrolactone with Amino-alkoxy-bis(phenolate)-Yttrium Complexes

(2011) Miloud Bouyahyi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Discrete, Solvent-Free Alkaline-Earth Metal Cations: Metal···Fluorine Interactions and ROP Catalytic Activity

(2011) Yann Sarazin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Aluminum-Catalyzed Ring-Opening Polymerization of Cyclic Carbonates, Lactones, and Lactides, Including a Unique Crystallographic Snapshot of an Intermediate

(2011) Jürgen Koller et al.   ORGANOMETALLICS

DFT investigations on the ring-opening polymerization of cyclic carbonates catalyzed by zinc-{β-diiminate} complexes

(2011) Iker del Rosal et al.   Polymer Chemistry

Cationic and charge-neutral calcium tetrahydroborate complexes and their use in the controlled ring-opening polymerisation of rac-lactide

(2010) Michael G. Cushion et al.   CHEMICAL COMMUNICATIONS

Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates

(2010) Noureddine Ajellal et al.   DALTON TRANSACTIONS

Synthesis of high-molecular-weight poly(ε-caprolactone) catalyzed by highly active bis(amidinate) tin(ii) complexes

(2010) Khamphee Phomphrai et al.   DALTON TRANSACTIONS

Zinc and magnesium complexes supported by bulky multidentate amino-ether phenolate ligands: potent pre-catalysts for the immortalring-opening polymerisation of cyclic esters

(2010) Valentin Poirier et al.   DALTON TRANSACTIONS

Random Copolymerization of ε-Caprolactone with Lactide Using a Homosalen−Al Complex

(2010) Nobuyoshi Nomura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Study of the Stereoselective Polymerization ofd,l-Lactide Using Indium(III) Halides

(2010) Agostino Pietrangelo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Active Magnesium Initiators for Ring-Opening Polymerization ofrac-Lactide

(2010) Liying Wang et al.   MACROMOLECULES

Single site catalysts for stereoselective ring-opening polymerization of lactides

(2010) Pieter Jelle Dijkstra et al.   Polymer Chemistry

Ring-Opening Polymerization of Cyclic Esters by an Enantiopure Heteroscorpionate Rare Earth Initiator

(2009) Antonio Otero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New facets of an old ligand: titanium and zirconium complexes of phenylenediamine bis(phenolate) in lactide polymerisation catalysis

(2009) Ayellet L. Zelikoff et al.   CHEMICAL COMMUNICATIONS

Stereocontrolled ring-opening polymerisation of lactide

(2009) Matthew J. Stanford et al.   CHEMICAL SOCIETY REVIEWS

Stereocontrolled ring-opening polymerization of cyclic esters: synthesis of new polyester microstructures

(2009) Christophe M. Thomas   CHEMICAL SOCIETY REVIEWS

Lactide Polymerisation with Air-Stable and Highly Active Zinc Complexes with Guanidine-Pyridine Hybrid Ligands

(2009) Janna Börner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bidentate salicylaldiminato tin(ii) complexes and their use as lactide polymerisation initiators

(2009) Nonsee Nimitsiriwat et al.   DALTON TRANSACTIONS

Complexes of Mg, Ca and Zn as homogeneous catalysts for lactide polymerization

(2009) Craig A. Wheaton et al.   DALTON TRANSACTIONS

Versatile catalytic systems based on complexes of zinc, magnesium and calcium supported by a bulky bis(morpholinomethyl)phenoxy ligand for the large-scale immortal ring-opening polymerisation of cyclic esters

(2009) Valentin Poirier et al.   DALTON TRANSACTIONS

Reverse orders of reactivities in the polymerization of cyclic esters using N2O2aluminium alkoxide complexes

(2009) Khamphee Phomphrai et al.   DALTON TRANSACTIONS

A Highly Active Chiral Indium Catalyst for Living Lactide Polymerization

(2008) Amy F. Douglas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ultraproductive, Zinc-Mediated, Immortal Ring-Opening Polymerization of Trimethylene Carbonate

(2008) Marion Helou et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Reversible Amination of Tin(II)-Ligated Imines: Latent Initiators for the Polymerization ofrac-Lactide

(2008) Nonsee Nimitsiriwat et al.   INORGANIC CHEMISTRY

Ring-Opening Polymerization of Cyclic Monomers by Complexes Derived from Biocompatible Metals. Production of Poly(lactide), Poly(trimethylene carbonate), and Their Copolymers

(2008) Donald J. Darensbourg et al.   MACROMOLECULES

Polymers from Renewable Resources: A Perspective for a Special Issue of Polymer Reviews

(2008) Charlotte Williams et al.   Polymer Reviews