Combining the Power of TiIII-Mediated Processes for Easy Access to Hydroxylated Polycyclic Terpenoids: Synthesis of Sesterstatin 1 and C-D Rings of Aspergilloxide

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A straightforward and efficient synthetic access to biologically active marine sesterterpenoids, sesterstatins 4 and 5

(2011) Wen-Yuan Fan et al.   CHEMICAL COMMUNICATIONS

Bioinspired terpene synthesis: a radical approach

(2011) José Justicia et al.   CHEMICAL SOCIETY REVIEWS

Stictamides A−C, MMP12 Inhibitors Containing 4-Amino-3-hydroxy-5-phenylpentanoic Acid Subunits

(2011) Zhibin Liang et al.   JOURNAL OF ORGANIC CHEMISTRY

Diverting non-haem iron catalysed aliphatic C–H hydroxylations towards desaturations

(2011) Marinus A. Bigi et al.   Nature Chemistry

Total synthesis of novel D-ring-modified triptolide analogues: structure–cytotoxic activity relationship studies on the D-ring of triptolide

(2011) Bing Zhou et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Concise stereoselective synthesis of marine sesterterpene, 16-deacetoxy-12-epi-scalarafuran acetate and its 14-epimer via intramolecular Diels–Alder addition

(2011) Zheng-Lin Wang et al.   TETRAHEDRON

Titanocene(III)-Promoted Barbier-type Crotylation of Carbonyl Compounds

(2010) Iris Sancho-Sanz et al.   JOURNAL OF ORGANIC CHEMISTRY

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

(2010) M. S. Chen et al.   SCIENCE

Scalable synthesis of methyl ent-isocopalate and its derivatives

(2010) Si-Kai Hua et al.   TETRAHEDRON

Efficient Propargylation of Aldehydes and Ketones Catalyzed by Titanocene(III)

(2009) José Justicia et al.   ADVANCED SYNTHESIS & CATALYSIS

Strain Release in CH Bond Activation?

(2009) Ke Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

4-exoCyclizations by Template Catalysis

(2009) Andreas Gansäuer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ti-Catalyzed Barbier-Type Allylations and Related Reactions

(2009) Rosa E. Estévez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Scalarane Sesterterpenoids: Semisynthesis and Biological Activity

(2009) Haidy N. Kamel et al.   JOURNAL OF NATURAL PRODUCTS

Unexpected TiIII/Mn-Promoted Pinacol Coupling of Ketones

(2009) Miguel Paradas et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalysis via Homolytic Substitutions with C−O and Ti−O Bonds: Oxidative Additions and Reductive Eliminations in Single Electron Steps

(2009) Andreas Gansäuer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Novel Organometallic Gelators with Enhanced Amphiphilic Character: Structure−Property Correlations, Principles for Design, and Diversity of Gelation

(2009) Andreas Gansäuer et al.   ORGANOMETALLICS

Formal total synthesis of (±)-fragranol via template catalyzed 4-exo cyclization

(2009) Andreas Gansäuer et al.   TETRAHEDRON

The first synthesis of marine sesterterpene (+)-scalarolide

(2009) Xiang-Jian Meng et al.   TETRAHEDRON LETTERS

Titanium-Catalyzed Enantioselective Synthesis of α-Ambrinol

(2008) José Justicia et al.   ADVANCED SYNTHESIS & CATALYSIS

Carbonyl-Substituted Titanocenes: A Novel Class of Cytostatic Compounds with High Antitumor and Antileukemic Activity

(2008) Andreas Gansäuer et al.   CHEMISTRY-A EUROPEAN JOURNAL

TEMPO/NaIO4−SiO2: A Catalytic Oxidative Rearrangement of Tertiary Allylic Alcohols to β-Substituted α,β-Unsaturated Ketones

(2008) Masatoshi Shibuya et al.   ORGANIC LETTERS

Modular Synthesis of Functional Titanocenes

(2008) Andreas Gansäuer et al.   ORGANOMETALLICS