Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 17, Issue 16, Pages 4613-4618Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201002858
Keywords
detonation properties; energetic materials; heats of formation; nitrogen; thermodynamics
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Funding
- ONR [N00014-10-1-0097]
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Synthesis, characterization, and thermolysis studies of 1-amino-1-hydrazino-2,2-dinitroethene (2) and salts thereof are reported. These compounds have been fully characterized by IR and NMR spectroscopy, elemental analysis, differential scanning calorimetry (DSC), density, and impact sensitivity measurements. Compound 2 decomposes at 124.5 degrees C (DSC) and the salts decompose over the range 138.6-181.6 degrees C, thus showing higher thermostability. The calculated detonation pressures (P) for these salts range from 27.2 to 37.8 GPa, and detonation velocities (vD) fall between 8424 to 9482 m s(-1); these properties make them competitive energetic materials.
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