Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 15, Issue 13, Pages 3198-3203Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200802326
Keywords
energetic salts; heats of formation; nitrogen; nitrogen heterocycles; tetrazoles
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The synthesis and detonation properties of high energy density materials with ethylene- and propylene bis(nitroiminotetrazolate) as the anions are reported; all salts were fully characterized by I R, and H-1, C-13, and N-15 NMR spectroscopy as well as elemental analyses. In addition, the heats of formation (Delta H-f) were calculated with the Gaussian 3.0 suite of programs. By using the experimental values for the densities of the nitroiminotetrazolate salts, the detonation pressures (P) and velocities (D) were calculated using Cheetah 5.0.
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