Article
Chemistry, Inorganic & Nuclear
Ying-Bo Wang, Xiu-Yuan Li, Hai-Yu Duan, Chaozheng He
Summary: A new porous MOF with a brick-shaped framework was synthesized successfully, and it showed high adsorption capacity for H2O and MeOH, while low adsorption capacity for EtOH, n-PrOH, and CH2Cl2. The adsorption selectivity and binding sites of the material were determined through simulation calculations.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Chemistry, Physical
Adrian Ruckhofer, Marco Sacchi, Anthony Payne, Andrew P. Jardine, Wolfgang E. Ernst, Nadav Avidor, Anton Tamtoegl
Summary: Utilizing helium atom scattering, the research discovered and controlled the growth of novel 2D h-BN nanoporous phases during the CVD process, revealing the formation of a metastable structure prior to h-BN formation and the emergence of a (3 x 4) structure.
NANOSCALE HORIZONS
(2022)
Article
Chemistry, Multidisciplinary
Chun Li, Zejun Zhang, Lars Heinke
Summary: The study demonstrates the use of smart and photoresponsive materials to remotely control their key properties. By embedding photochromic molecules in nanoporous metal-organic frameworks, the interaction between the host and guest molecules can be modified. The research shows for the first time that the adsorption and diffusion properties can be remotely controlled using a fulgide-based nanoporous material.
Article
Chemistry, Multidisciplinary
Banele Vatsha, Rowan Goliath, Giovanni Hearne
Summary: Pressurization of the 2D metal-organic framework compound Fe-2(azpy)(4)(NCS)(4) in isopropanol and ethanol results in metal-ion sites converting from high-spin to low-spin states under high pressure, driven by the uptake of guest molecules. The inclusion of different guest molecules leads to varying degrees of spin crossover progression, with higher pressure facilitating greater low-spin abundance at room temperature. This pressure-facilitated guest-specific triggering of spin crossover highlights interactions between guest molecules and the local coordination network of the Fe(II) core, increasing the ligand field.
Article
Chemistry, Physical
Xia Li, Debobroto Sensharma, Varvara I. Nikolayenko, Shaza Darwish, Andrey A. Bezrukov, Naveen Kumar, Wansheng Liu, Xiang-Jing Kong, Zhenjie Zhang, Michael J. Zaworotko
Summary: In this study, a new two-dimensional square lattice coordination network, sql-(azpy)(pdia)-Ni, was reported to exhibit guest-induced switching between closed and open phases. The structural transformations were enabled by the presence of a pendant phenyldiazenyl moiety on the pdia2- ligand. Various guests were accommodated through parallel slippage of layers and interlayer expansion. The network also exhibited elastic-like properties induced by adaptive guest binding.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ang Liu, Shimin Liu, Kai Wang
Summary: This study demonstrates the significant impact of coal-water interactions on the performance of coalbed methane reservoirs and coal utilizations. A mechanism-based isothermal model and analytical models for diffusion coefficients were proposed and validated. The contributions of different diffusion regimes to the total mass flow were discussed.
Article
Chemistry, Multidisciplinary
Ruiwen Luo, Huayan Fu, Yulin Li, Qinglei Xing, Guohong Liang, Peng Bai, Xianghai Guo, Jiafei Lyu, Michael Tsapatsis
Summary: A continuous Zr-MOF thin film with a thickness of approximately 180 nm has been fabricated via in situ recrystallization of MOF nanoparticles on a porous support under formic acid vapor. The MOF thin films exhibit excellent pervaporation performance in n-butanol dehydration and methanol/MTBE separation. This method of in situ recrystallization opens a new avenue for facile membrane fabrication of various MOF materials.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Wanbin Li, Yanshan Lin, Pengcheng Su
Summary: In this study, guest-host dual MOF@MOF heterosystems were designed and constructed using vapor linker processing. These heterosystems exhibited tailored dual pore geometries, enhanced affinities to gas molecules, and combined advantages of different MOFs. The MOF@MOF composites showed substantially improved compatibility toward polymers and could adjust membrane transport pathways for achieving outstanding carbon capture performance.
APPLIED MATERIALS TODAY
(2022)
Article
Engineering, Chemical
Valerio Loianno, Antonio Baldanza, Giuseppe Scherillo, Rezvan Jamaledin, Pellegrino Musto, Giuseppe Mensitieri
Summary: A new hyphenated technique combining in situ FT-NIR spectroscopy and pressure-decay measurements has been implemented to study sorption in polymeric membranes. The method allows for accurate estimation of the molar absorptivity of analytical peaks by combining photometric data with quantitative information from pressure decay measurements. The experimental approach was validated by investigating CO2 sorption in polydimethylsiloxane and comparing the results with existing literature data.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
Bodo Felsner, Volodymyr Bon, Jack D. Evans, Friedrich Schwotzer, Ronny Grunker, Irena Senkovska, Stefan Kaskel
Summary: The switching mechanism of the flexible framework Zn4O(benztb)(1.5) (benztb=N,N,N',N'-benzidine tetrabenzoate), also known as DUT-13, was studied using advanced powder X-ray diffraction (PXRD) and gas physisorption techniques. In situ synchrotron PXRD experiments revealed guest-induced breathing in the MOF, which is based on the conformationally labile benztb ligand and results in a reduction in specific pore volume. The high temperature limit for adsorption-induced contraction of 170 K indicates that the DUT-13 framework is softer than other mesoporous MOFs, such as DUT-49, and does not support the formation of overloaded metastable states.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Review
Chemistry, Inorganic & Nuclear
Hilke Petersen, Claudia Weidenthaler
Summary: This review discusses the up-to-date in situ/operando methods for the comprehensive characterization of nanoporous materials, highlighting the growing variety of nanoporous materials and their potential applications. The evolution from ex situ examination to complex in situ or operando methods allows for establishing structure-property relationships and optimizing nanoporous materials for specific processes. Recent developments on both established and emerging methods are discussed for future applications.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Multidisciplinary
Shaheed Ullah, Michael L. Mckee, Alexander Samokhvalov
Summary: The study reveals the molecular-level interactions between advanced nanomaterial and volatile organic sulfur compounds. The material shows high adsorption capacity for diethyl sulfide and can be easily regenerated by heating. This research is important for environmental remediation and understanding of adsorption mechanisms.
Article
Chemistry, Analytical
Jinsheng Wu, Zhan Li, Hongxin Tan, Shaobo Du, Tianqi Liu, Yanli Yuan, Xiuhui Liu, Hongdeng Qiu
Summary: Rare earth elements are widely used in various devices, but achieving their selective separation and purification remains a challenge. Metal-organic frameworks (MOFs) have been utilized for selective separation of REEs, but most cannot be used for solid-state adsorption of REEs in strong acid. A new composite material was developed with the best separation performance for REEs.
ANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Corey L. Jones, Colan E. Hughes, Hamish H-M Yeung, Alison Paul, Kenneth D. M. Harris, Timothy L. Easun
Summary: In situ NMR studies on the formation of MFM-500(Ni) provide insights into the solution-phase processes and kinetics of crystallization, revealing activation energies for nucleation and growth. Complementary nanoscale information on rapid self-assembly prior to MOF crystallization is obtained through ex situ small-angle X-ray scattering, while in situ powder X-ray diffraction confirms the presence of phase-pure MFM-500(Ni) during the reaction. This work demonstrates the potential of in situ NMR experiments in shedding new light on MOF synthesis.
Article
Chemistry, Multidisciplinary
Georgia-Annicette Banga-Bothy, Alexander Samokhvalov
Summary: Metal-organic frameworks (MOFs) are nanostructured coordination polymers with high porosity. In this study, the sorption and desorption of n-pentane vapor by a specific MOF (Al-MOF-TCPPH2) were investigated using in-situ time-dependent attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy. The sorption kinetics followed the pseudo-first-order rate law, and the desorption process was also found to be reversible. This research shows that MOFs have potential applications in the separation of light hydrocarbons and chemo-sensing.
Article
Chemistry, Physical
Ashok S. Menon, Seda Ulusoy, Dickson O. Ojwang, Lars Riekehr, Christophe Didier, Vanessa K. Peterson, German Salazar-Alvarez, Peter Svedlindh, Kristina Edstrom, Cesar Pay Gomez, William R. Brant
Summary: Li- and Mn-rich layered oxides hold promise as electrode materials for future Li-ion batteries, but their crystallography remains inaccurately described, with the synthetic route having a direct impact on the crystal structure. Clarifying structural ambiguities is crucial for understanding electrochemical performance and anionic redox behavior.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Inorganic & Nuclear
Manan Ahmed, Katrina A. Zenere, Natasha F. Sciortino, Kasun S. A. Arachchige, Gemma F. Turner, Jace Cruddas, Carol Hua, Jason R. Price, Jack K. Clegg, Francisco Javier Valverde-Munoz, Jose A. Real, Guillaume Chastanet, Stephen A. Moggach, Cameron J. Kepert, Benjamin J. Powell, Suzanne M. Neville
Summary: This study investigates the effects of external stimuli on the Hofmann framework material, showing how manipulation of pore contents can regulate the balance between ferro- and antiferro-elastic interaction characters. The study highlights the complex mechanisms behind elastic interaction and the impact of external pressure and light-induced effects on the material properties.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Manan Ahmed, Kasun S. A. Arachchige, Zixi Xie, Jason R. Price, Jace Cruddas, Jack K. Clegg, Benjamin J. Powell, Cameron J. Kepert, Suzanne M. Neville
Summary: This study presents a detailed analysis of the structure and spin-crossover effects of a two-dimensional (2-D) Hofmann-like framework [Fe(furpy)(2)Pd(CN)(4)]center dot nG. The inclusion of guest modifications, particularly ethanol, affects the framework communication and local structure, leading to changes in the spin-state transition mechanism.
INORGANIC CHEMISTRY
(2022)
Article
Paleontology
Thomas H. Rich, Melissa Lowery, Michael Hall, Lesley Kool, Joseph Bevitt, Matt White, Patricia Vickers-Rich
Summary: Mesozoic mammals from the polar regions of Australian Gondwana are extremely rare. The discovery of a partial jaw from the australosphenid Ausktribosphenos nyktos in a new location along the Bass Coast of Victoria is significant because it comes from a sediment with abundant plant material that differs from previous findings, indicating a floodplain habitat far from local water bodies. The identification of a new Cretaceous mammal locality in Australia highlights the exciting prospects for future fossil discoveries.
Article
Materials Science, Multidisciplinary
Manohar H. Karigerasi, Kisung Kang, Jeffrey Huang, Vanessa K. Peterson, Kirrily C. Rule, Andrew J. Studer, Andre Schleife, Pinshane Y. Huang, Daniel P. Shoemaker
Summary: This study reveals the inhomogeneity and phase separation in copper manganese arsenic samples through diffraction patterns, and identifies two transitions through calorimetry and magnetometry measurements. These findings are important for understanding the properties and electronic switching behavior of copper manganese arsenic.
PHYSICAL REVIEW MATERIALS
(2022)
Article
Chemistry, Physical
Chih-Yu Chang, Natalia Majewska, Kuan-Chun Chen, Wen-Tse Huang, Tadeusz Lesniewski, Grzegorz Leniec, Slawomir M. Kaczmarek, Wei Kong Pang, Vanessa K. Peterson, Ding-Hua Cherng, Kuang-Mao Lu, Sebastian Mahlik, Ru-Shi Liu
Summary: In this work, the emission band of NIR phosphors is broadened by controlling crystal structure disorder through cation cosubstitution. The increased deviation of the cation radii leads to enhanced electron-phonon coupling, resulting in a wider emission spectrum and high internal quantum efficiency. Additionally, the application of high pressure can create a structure with ultra-broad-band emission.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Hamish McDougall, Monica Hibberd, Andrew Tong, Suzanne Neville, Vanessa Peterson, Christophe Didier
Summary: The study presents a precise and accurate methodology for quantitative phase analysis using X-ray diffraction of pyrite ore concentrate from the Thackaringa mine. The research explores sample preparation and optimization process, discussing the limitations of the method. The findings have significance in understanding the characteristics of pyrite ore from Thackaringa mine.
JOURNAL OF APPLIED CRYSTALLOGRAPHY
(2022)
Article
Multidisciplinary Sciences
Tea Maho, Joseph J. Bevitt, Robert R. Reisz
Summary: The discovery of articulated pelvic region and additional isolated material of Varanops brevirostris supports the existence of this large varanopid species at the Richards Spur locality. The presence of distinct anatomical features, such as blade-like neural spines and excavated pubis, confirms the autapomorphies previously suggested for this species. Histological analysis and neutron computed tomography indicate that the articulated specimen likely belonged to an adult individual.
Article
Multidisciplinary Sciences
Dylan C. T. Rowe, Joseph J. Bevitt, Robert R. Reisz
Summary: Through the use of neutron tomography, the detailed description of the holotype skeleton of Delorhynchus cifellii has provided important new information about the cranial and postcranial anatomy of this early Permian parareptile. Previously unknown features of the skull and the exposure of the stapes in three dimensions have been revealed. The discovery of postcranial material in articulation with the skull allows for the first detailed description of vertebrae, ribs, shoulder girdle, and humerus of an acleistorhinid parareptile, leading to a reevaluation of its phylogenetic relationships.
Article
Multidisciplinary Sciences
Yuguang Pu, Duncan Moseley, Zhen He, Krishna Chaitanya Pitike, Michael E. Manley, Jiaqiang Yan, Valentino R. Cooper, Valerie Mitchell, Vanessa K. Peterson, Bernt Johannessen, Raphael P. Hermann, Peng Cao
Summary: Researchers have developed a bottom-up method for synthesizing rocksalt high-entropy oxides (HEOs) containing Mn and Fe. They investigated the crystal structure and random cation-site occupancy of FeO-HEO, showing improved structural robustness and the viability of an oxygen sublattice as a buffer layer. Compositional analysis revealed the valence and spin state of the iron species, and the antiferromagnetic order of FeO-HEO below a transition temperature around 218 K was reported, along with predictions for the phase stability conditions of Mn and Fe-containing HEOs.
Article
Chemistry, Multidisciplinary
Daniel Risskov Sorensen, Andreas Ostergaard Drejer, Michael Heere, Anatoliy Senyshyn, Matthias Frontzek, Thomas Hansen, Christophe Didier, Vanessa K. Peterson, Dorthe Bomholdt Ravnsbaek, Mads Ry Vogel Jorgensen
Summary: In operando powder diffraction is a powerful tool for investigating battery electrode materials. While X-ray powder diffraction is routine, neutron powder diffraction is still less established. Researchers have developed a new electrochemical cell for in operando neutron powder diffraction that is easy to use and can cycle electrode materials under electrochemical conditions similar to standard laboratory cells.
Article
Chemistry, Multidisciplinary
Hunter J. Windsor, William Lewis, Suzanne M. Neville, Samuel G. Duyker, Deanna M. D'Alessandro, Cameron J. Kepert
Summary: A 3D Hofmann-like metal-organic framework with a 2,1,3-benzothiadiazole-based pillaring ligand has been synthesized. The encapsulation of a polycyclic aromatic hydrocarbon, chrysene, within the pore structure enables a new pathway to multi-step spin crossover behavior, where the observed two-step spin transition is attributed to the presence of multiple site environments and local guest positional effects within the host lattice.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Luonan Xu, Zixi Xie, Katrina A. Zenere, Jack K. Clegg, Elise Kenny, Nicole J. Rijs, Guy N. L. Jameson, Cameron J. Kepert, Benjamin J. Powell, Suzanne M. Neville
Summary: The inclusion of 4,2 ':6',4''-terpyridine (TPy) as an angular bridging ligand in a Hofmann-type framework results in the formation of an irregular network. This network consists of both six- and five-coordinate Fe-II species. The octahedral sites exhibit thermally-induced spin-crossover (SCO) while the rare five-coordinate Fe-II sites remain in a high-spin state.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Manan Ahmed, Helen E. A. Brand, Vanessa K. Peterson, Jack K. Clegg, Cameron J. Kepert, Jason R. Price, Benjamin J. Powell, Suzanne M. Neville
Summary: In this study, a nitro-functionalised 1,2,4-triazole ligand was used to induce lattice distortion in a 2-D Hofmann framework material through competing supramolecular interactions. The crystallographic analyses revealed substantial deviations from a regular Hofmann structure, showing an array of ligand conformations and Fe-II coordination environments. Temperature-dependent magnetic susceptibility measurements showed a two-step spin crossover transition, providing insight into the competition between elastic interactions and crystallographically driven order.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Multidisciplinary
Manan Ahmed, Zixi Xie, Shannon Thoonen, Carol Hua, Cameron J. Kepert, Jason R. Price, Suzanne M. Neville
Summary: A 3-D Fe-II Hofmann-type framework material with a rare Fe-II(py)3(N···)3 coordination environment has been prepared, showing for the first time to be conducive to spin crossover (SCO).
CHEMICAL COMMUNICATIONS
(2021)