Journal
CHEMISTRY OF MATERIALS
Volume 24, Issue 6, Pages 975-980Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm2026812
Keywords
ALD; niobium oxide thin film; high-k; niobium imido-amido
Funding
- European Community [ENHANCE-23840]
Ask authors/readers for more resources
Atomic layer deposition (ALD) of Nb2O5 thin films was studied using three novel precursors, namely, (BuN)-Bu-t=Nb(NEt2)(3), (BuN)-Bu-t=Nb(NMeEt)(3), and (t)amylN=Nb((OBu)-Bu-t)(3). These precursors are liquid at room temperature, present good volatility, and are reactive toward both water and ozone as the oxygen sources. The deposition temperature was varied from 150 to 375 degrees C. ALD-type saturative growth modes were confirmed at 275 degrees C for (BuN)-Bu-t=Nb(NEt2)(3) and (BuN)-Bu-t=Nb(NMeEt)(3) together with both oxygen sources. Constant growth rate was observed between a temperature regions of 150 and 325 degrees C. By contrast, amylN=Nb((OBu)-Bu-t)(3) exhibited limited thermal stability and thus a saturative growth mode was not achieved. All films were amorphous in the as-deposited state and crystallized between 525-575 degrees C, regardless of the applied precursor and oxygen source. Time-of-flight elastic recoil detection analysis (TOF-ERDA) demonstrated the high purity of the films. Atomic force microscopy (AFM) revealed that the films were smooth and uniform. The films exhibited promising dielectric characteristics with permittivity values up to 60.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available