4.3 Article

Rhodium-catalyzed Enantioselective [2+2+2] Cycloaddition of Tosylamide-linked 5-Allenal and 5-Allenone with Internal Alkynes

Journal

CHEMISTRY LETTERS
Volume 43, Issue 8, Pages 1260-1262

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.140448

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Funding

  1. ACT-C from Japan Science and Technology Agency (Japan)

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It has been established that a cationic rhodium(I) BINAP complex catalyzes the enantioselective [2 + 2 + 2] cycloaddition of a tosylamide-linked 5-allenal and 5-allenone with internal alkynes, leading to bicyclic oxygen heterocycles.

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